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Iminodiacetic acid synthesis over Cu/ZrO2 catalyst in a microchannel flow reactor. / Andreev, D. V.; Sergeev, E. E.; Gribovskii, A. G. et al.

In: Chemical Engineering Journal, Vol. 330, 15.12.2017, p. 899-905.

Research output: Contribution to journal › Article › peer-review

Harvard

Andreev, DV, Sergeev, EE, Gribovskii, AG, Makarshin, LL, Prikhod'ko, SA, Adonin, NY, Pai, ZP & Parmon, VN 2017, 'Iminodiacetic acid synthesis over Cu/ZrO2 catalyst in a microchannel flow reactor', Chemical Engineering Journal, vol. 330, pp. 899-905. https://doi.org/10.1016/j.cej.2017.08.028

APA

Andreev, D. V., Sergeev, E. E., Gribovskii, A. G., Makarshin, L. L., Prikhod'ko, S. A., Adonin, N. Y., Pai, Z. P., & Parmon, V. N. (2017). Iminodiacetic acid synthesis over Cu/ZrO2 catalyst in a microchannel flow reactor. Chemical Engineering Journal, 330, 899-905. https://doi.org/10.1016/j.cej.2017.08.028

Vancouver

Andreev DV, Sergeev EE, Gribovskii AG, Makarshin LL, Prikhod'ko SA, Adonin NY et al. Iminodiacetic acid synthesis over Cu/ZrO2 catalyst in a microchannel flow reactor. Chemical Engineering Journal. 2017 Dec 15;330:899-905. doi: 10.1016/j.cej.2017.08.028

Author

Andreev, D. V. ; Sergeev, E. E. ; Gribovskii, A. G. et al. / Iminodiacetic acid synthesis over Cu/ZrO2 catalyst in a microchannel flow reactor. In: Chemical Engineering Journal. 2017 ; Vol. 330. pp. 899-905.

BibTeX

@article{9a3ab26179ad4f6cb8b74c4408bd287d,
title = "Iminodiacetic acid synthesis over Cu/ZrO2 catalyst in a microchannel flow reactor",
abstract = "Flow microchannel reactor was used to study the synthesis of iminodiacetic acid (IDA) via the catalytic oxidative dehydrogenation of diethanolamine (DEA) over catalyst Cu/ZrO2 (containing copper in amount of 10 mass%) at various residence times, reaction temperature ranging within 160–190 °C. IDA was shown to form in the course of two consecutive reactions through intermediate compound N-(2-hydroxyethyl)glycine (HEG). DEA conversion and IDA yield were found to increase as residence time and reaction temperature grow, meanwhile HEG concentration maximum on kinetic curves shifts towards shorter residence times. Effective reaction rate constants were determined according to the suggested scheme of IDA synthesis. Calculated activation energies for two consecutive stages of IDA synthesis were found to be 73.7 and 67.2 kJ/mol, respectively.",
keywords = "Copper-zirconia catalyst, Effective reaction rate constant, Iminodiacetic acid, Microchannel flow reactor, Oxidative dehydrogenation of diethanolamine",
author = "Andreev, {D. V.} and Sergeev, {E. E.} and Gribovskii, {A. G.} and Makarshin, {L. L.} and Prikhod'ko, {S. A.} and Adonin, {N. Yu} and Pai, {Z. P.} and Parmon, {V. N.}",
year = "2017",
month = dec,
day = "15",
doi = "10.1016/j.cej.2017.08.028",
language = "English",
volume = "330",
pages = "899--905",
journal = "Chemical Engineering Journal",
issn = "1385-8947",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Iminodiacetic acid synthesis over Cu/ZrO2 catalyst in a microchannel flow reactor

AU - Andreev, D. V.

AU - Sergeev, E. E.

AU - Gribovskii, A. G.

AU - Makarshin, L. L.

AU - Prikhod'ko, S. A.

AU - Adonin, N. Yu

AU - Pai, Z. P.

AU - Parmon, V. N.

PY - 2017/12/15

Y1 - 2017/12/15

N2 - Flow microchannel reactor was used to study the synthesis of iminodiacetic acid (IDA) via the catalytic oxidative dehydrogenation of diethanolamine (DEA) over catalyst Cu/ZrO2 (containing copper in amount of 10 mass%) at various residence times, reaction temperature ranging within 160–190 °C. IDA was shown to form in the course of two consecutive reactions through intermediate compound N-(2-hydroxyethyl)glycine (HEG). DEA conversion and IDA yield were found to increase as residence time and reaction temperature grow, meanwhile HEG concentration maximum on kinetic curves shifts towards shorter residence times. Effective reaction rate constants were determined according to the suggested scheme of IDA synthesis. Calculated activation energies for two consecutive stages of IDA synthesis were found to be 73.7 and 67.2 kJ/mol, respectively.

AB - Flow microchannel reactor was used to study the synthesis of iminodiacetic acid (IDA) via the catalytic oxidative dehydrogenation of diethanolamine (DEA) over catalyst Cu/ZrO2 (containing copper in amount of 10 mass%) at various residence times, reaction temperature ranging within 160–190 °C. IDA was shown to form in the course of two consecutive reactions through intermediate compound N-(2-hydroxyethyl)glycine (HEG). DEA conversion and IDA yield were found to increase as residence time and reaction temperature grow, meanwhile HEG concentration maximum on kinetic curves shifts towards shorter residence times. Effective reaction rate constants were determined according to the suggested scheme of IDA synthesis. Calculated activation energies for two consecutive stages of IDA synthesis were found to be 73.7 and 67.2 kJ/mol, respectively.

KW - Copper-zirconia catalyst

KW - Effective reaction rate constant

KW - Iminodiacetic acid

KW - Microchannel flow reactor

KW - Oxidative dehydrogenation of diethanolamine

UR - http://www.scopus.com/inward/record.url?scp=85027342196&partnerID=8YFLogxK

U2 - 10.1016/j.cej.2017.08.028

DO - 10.1016/j.cej.2017.08.028

M3 - Article

AN - SCOPUS:85027342196

VL - 330

SP - 899

EP - 905

JO - Chemical Engineering Journal

JF - Chemical Engineering Journal

SN - 1385-8947

ER -

ID: 9400537