Standard

Hydrogen storage systems based on solid-state NaBH4/Co composite : Effect of catalyst precursor on hydrogen generation rate. / Netskina, O. V.; Tayban, E. S.; Prosvirin, I. P. et al.

In: Renewable Energy, Vol. 151, 05.2020, p. 278-285.

Research output: Contribution to journal › Article › peer-review

Harvard

Netskina, OV, Tayban, ES, Prosvirin, IP, Komova, OV & Simagina, VI 2020, 'Hydrogen storage systems based on solid-state NaBH4/Co composite: Effect of catalyst precursor on hydrogen generation rate', Renewable Energy, vol. 151, pp. 278-285. https://doi.org/10.1016/j.renene.2019.11.031

APA

Netskina, O. V., Tayban, E. S., Prosvirin, I. P., Komova, O. V., & Simagina, V. I. (2020). Hydrogen storage systems based on solid-state NaBH4/Co composite: Effect of catalyst precursor on hydrogen generation rate. Renewable Energy, 151, 278-285. https://doi.org/10.1016/j.renene.2019.11.031

Vancouver

Netskina OV, Tayban ES, Prosvirin IP, Komova OV, Simagina VI. Hydrogen storage systems based on solid-state NaBH4/Co composite: Effect of catalyst precursor on hydrogen generation rate. Renewable Energy. 2020 May;151:278-285. doi: 10.1016/j.renene.2019.11.031

Author

Netskina, O. V. ; Tayban, E. S. ; Prosvirin, I. P. et al. / Hydrogen storage systems based on solid-state NaBH4/Co composite : Effect of catalyst precursor on hydrogen generation rate. In: Renewable Energy. 2020 ; Vol. 151. pp. 278-285.

BibTeX

@article{fd0b88fc7fb548d2bfa8e60ec1ae0388,
title = "Hydrogen storage systems based on solid-state NaBH4/Co composite: Effect of catalyst precursor on hydrogen generation rate",
abstract = "Tablets on the basis of sodium borohydride and cobalt compounds (CoCl2·6H2O, Co(CH3COO)2·4H2O, Co3O4 and anhydrous CoSO4) have been studied as hydrogen generation materials. The kinetics of sodium borohydride hydrolysis upon contact of the tablets with water has been investigated. Adsorption and reaction constants have been determined for each of the catalysts using the Langmuir-Hinshelwood model which allowed us to estimate the contribution of BH4‾ adsorption to the overall rate of hydrogen generation. It was noted that the nature of the catalyst precursor has an influence not only on the specific surface area of the in situ forming catalytically active phase, the particle size of the catalyst, the degree of reduction of cobalt compounds by sodium borohydride but also on the adsorption of BH4‾ anions from the reaction medium on the catalyst surface.",
keywords = "Adsorption, Cobalt catalyst, Hydrogen, Hydrolysis, Langmuir-Hinshelwood model, Sodium borohydride",
author = "Netskina, {O. V.} and Tayban, {E. S.} and Prosvirin, {I. P.} and Komova, {O. V.} and Simagina, {V. I.}",
note = "Publisher Copyright: {\textcopyright} 2019 Elsevier Ltd",
year = "2020",
month = may,
doi = "10.1016/j.renene.2019.11.031",
language = "English",
volume = "151",
pages = "278--285",
journal = "Renewable Energy",
issn = "0960-1481",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Hydrogen storage systems based on solid-state NaBH4/Co composite

T2 - Effect of catalyst precursor on hydrogen generation rate

AU - Netskina, O. V.

AU - Tayban, E. S.

AU - Prosvirin, I. P.

AU - Komova, O. V.

AU - Simagina, V. I.

N1 - Publisher Copyright: © 2019 Elsevier Ltd

PY - 2020/5

Y1 - 2020/5

N2 - Tablets on the basis of sodium borohydride and cobalt compounds (CoCl2·6H2O, Co(CH3COO)2·4H2O, Co3O4 and anhydrous CoSO4) have been studied as hydrogen generation materials. The kinetics of sodium borohydride hydrolysis upon contact of the tablets with water has been investigated. Adsorption and reaction constants have been determined for each of the catalysts using the Langmuir-Hinshelwood model which allowed us to estimate the contribution of BH4‾ adsorption to the overall rate of hydrogen generation. It was noted that the nature of the catalyst precursor has an influence not only on the specific surface area of the in situ forming catalytically active phase, the particle size of the catalyst, the degree of reduction of cobalt compounds by sodium borohydride but also on the adsorption of BH4‾ anions from the reaction medium on the catalyst surface.

AB - Tablets on the basis of sodium borohydride and cobalt compounds (CoCl2·6H2O, Co(CH3COO)2·4H2O, Co3O4 and anhydrous CoSO4) have been studied as hydrogen generation materials. The kinetics of sodium borohydride hydrolysis upon contact of the tablets with water has been investigated. Adsorption and reaction constants have been determined for each of the catalysts using the Langmuir-Hinshelwood model which allowed us to estimate the contribution of BH4‾ adsorption to the overall rate of hydrogen generation. It was noted that the nature of the catalyst precursor has an influence not only on the specific surface area of the in situ forming catalytically active phase, the particle size of the catalyst, the degree of reduction of cobalt compounds by sodium borohydride but also on the adsorption of BH4‾ anions from the reaction medium on the catalyst surface.

KW - Adsorption

KW - Cobalt catalyst

KW - Hydrogen

KW - Hydrolysis

KW - Langmuir-Hinshelwood model

KW - Sodium borohydride

UR - http://www.scopus.com/inward/record.url?scp=85075454387&partnerID=8YFLogxK

U2 - 10.1016/j.renene.2019.11.031

DO - 10.1016/j.renene.2019.11.031

M3 - Article

AN - SCOPUS:85075454387

VL - 151

SP - 278

EP - 285

JO - Renewable Energy

JF - Renewable Energy

SN - 0960-1481

ER -

ID: 22402899