Research output: Contribution to journal › Article › peer-review
Hybrid Nanocomposite Solid Electrolytes (n-C4H9)4NBF4-MgO. / Mateyshina, Yulia; Stebnitskii, Ivan; Shivtsov, Danil et al.
In: International Journal of Molecular Sciences, Vol. 24, No. 13, 10949, 30.06.2023.Research output: Contribution to journal › Article › peer-review
}
TY - JOUR
T1 - Hybrid Nanocomposite Solid Electrolytes (n-C4H9)4NBF4-MgO
AU - Mateyshina, Yulia
AU - Stebnitskii, Ivan
AU - Shivtsov, Danil
AU - Ilyina, Ekaterina
AU - Ulihin, Artem
AU - Bukhtiyarov, Andrey
AU - Uvarov, Nikolai
N1 - Funding: This research was funded by the Russian Science Foundation, project 20-13-00302-p.
PY - 2023/6/30
Y1 - 2023/6/30
N2 - Hybrid nanocomposite materials Bu4NBF4-MgO were obtained using a nanocrystalline MgO with a specific surface area of 324 m2/g and the grains size of 5.1 nm. As a result of the strong adhesion, the salt transforms into an interface-stabilized amorphous state within the thin layer near the interface. The analysis of the DSC data allowed one to estimate the concentration and the thickness of this amorphous layer as 4.8 nm. The amorphous interface phase has an enhanced ionic conductivity. As a result, conductivity of the nanocomposite increases with the concentration of the amorphous phase and reaches 1.1 × 10-3 S/cm at 150 °C at a concentration of the MgO additive x = 0.90 corresponding to the maximum content of the amorphous phase. The conductivity of the nanocomposite is by three orders of magnitude higher than the conductivity of pure Bu4NBF4. The nanocomposites are electrochemically stable up to 2.5 V. At high concentrations of MgO when the total volume of the salt is small the composites become nano- and mesoporous.
AB - Hybrid nanocomposite materials Bu4NBF4-MgO were obtained using a nanocrystalline MgO with a specific surface area of 324 m2/g and the grains size of 5.1 nm. As a result of the strong adhesion, the salt transforms into an interface-stabilized amorphous state within the thin layer near the interface. The analysis of the DSC data allowed one to estimate the concentration and the thickness of this amorphous layer as 4.8 nm. The amorphous interface phase has an enhanced ionic conductivity. As a result, conductivity of the nanocomposite increases with the concentration of the amorphous phase and reaches 1.1 × 10-3 S/cm at 150 °C at a concentration of the MgO additive x = 0.90 corresponding to the maximum content of the amorphous phase. The conductivity of the nanocomposite is by three orders of magnitude higher than the conductivity of pure Bu4NBF4. The nanocomposites are electrochemically stable up to 2.5 V. At high concentrations of MgO when the total volume of the salt is small the composites become nano- and mesoporous.
UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85164845584&origin=inward&txGid=2392c3c2fdc474a0b44e098483cea59c
UR - https://www.mendeley.com/catalogue/afda79b3-e09f-3c14-ab1d-7ae2fc392467/
U2 - 10.3390/ijms241310949
DO - 10.3390/ijms241310949
M3 - Article
C2 - 37446124
VL - 24
JO - International Journal of Molecular Sciences
JF - International Journal of Molecular Sciences
SN - 1661-6596
IS - 13
M1 - 10949
ER -
ID: 52658110