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Homo- and heterometallic iodobismuthates(III) with 1,3,5-trimethylpyridinium cation: Preparation and features of optical behavior. / Shentseva, Irina A.; Usoltsev, Andrey N.; Abramov, Pavel A. et al.

In: Polyhedron, Vol. 216, 115720, 01.04.2022.

Research output: Contribution to journal › Article › peer-review

Harvard

Shentseva, IA, Usoltsev, AN, Abramov, PA, Shayapov, VR, Plyusnin, PE, Korolkov, IV, Sokolov, MN & Adonin, SA 2022, 'Homo- and heterometallic iodobismuthates(III) with 1,3,5-trimethylpyridinium cation: Preparation and features of optical behavior', Polyhedron, vol. 216, 115720. https://doi.org/10.1016/j.poly.2022.115720

APA

Shentseva, I. A., Usoltsev, A. N., Abramov, P. A., Shayapov, V. R., Plyusnin, P. E., Korolkov, I. V., Sokolov, M. N., & Adonin, S. A. (2022). Homo- and heterometallic iodobismuthates(III) with 1,3,5-trimethylpyridinium cation: Preparation and features of optical behavior. Polyhedron, 216, [115720]. https://doi.org/10.1016/j.poly.2022.115720

Vancouver

Shentseva IA, Usoltsev AN, Abramov PA, Shayapov VR, Plyusnin PE, Korolkov IV et al. Homo- and heterometallic iodobismuthates(III) with 1,3,5-trimethylpyridinium cation: Preparation and features of optical behavior. Polyhedron. 2022 Apr 1;216:115720. doi: 10.1016/j.poly.2022.115720

Author

Shentseva, Irina A. ; Usoltsev, Andrey N. ; Abramov, Pavel A. et al. / Homo- and heterometallic iodobismuthates(III) with 1,3,5-trimethylpyridinium cation: Preparation and features of optical behavior. In: Polyhedron. 2022 ; Vol. 216.

BibTeX

@article{e76600502b624e9ea16844e649c8b232,
title = "Homo- and heterometallic iodobismuthates(III) with 1,3,5-trimethylpyridinium cation: Preparation and features of optical behavior",
abstract = "The outcomes of reactions between bismuth triiodide, 1,3,5-trimethylpyridinium iodide (1,3,5-MePyI), copper(I) or silver(I) iodides depend on the nature of solvents used in preparation. From acetone/acetonitrile mixture, there crystallizes only binuclear (1,3,5-MePy)3[Bi2I9] (1), while addition of ethanol allows isolation of homometallic (1,3,5-MePy)11.8[Cu(CH3CN)4]0.2[Bi6I22][Bi5I19]2 (2) or heterometallic polymeric (1,3,5-MePy)2{[Bi2Cu2I10]} (3) and (1,3,5-MePy)2{[Bi2Ag2I10]} (4). For all complexes, optical band gaps were estimated via diffuse reflectance spectroscopy (2.06, 1.88, 1.84 and 1.92 eV, respectively). 1–4 reveal relatively high thermal stability.",
keywords = "Bismuth, Halide complexes, Halometalates, Heterometallic complexes, Semiconductors",
author = "Shentseva, {Irina A.} and Usoltsev, {Andrey N.} and Abramov, {Pavel A.} and Shayapov, {Vladimir R.} and Plyusnin, {Pavel E.} and Korolkov, {Ilya V.} and Sokolov, {Maxim N.} and Adonin, {Sergey A.}",
note = "Funding Information: This work was supported by Russian Science Foundation (Grant No. 21-73-00192) and, in part, by Ministry of Science and Higher Education of the Russian Federation (structural characterization of the samples, 121031700313-8). Publisher Copyright: {\textcopyright} 2022 Elsevier Ltd",
year = "2022",
month = apr,
day = "1",
doi = "10.1016/j.poly.2022.115720",
language = "English",
volume = "216",
journal = "Polyhedron",
issn = "0277-5387",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Homo- and heterometallic iodobismuthates(III) with 1,3,5-trimethylpyridinium cation: Preparation and features of optical behavior

AU - Shentseva, Irina A.

AU - Usoltsev, Andrey N.

AU - Abramov, Pavel A.

AU - Shayapov, Vladimir R.

AU - Plyusnin, Pavel E.

AU - Korolkov, Ilya V.

AU - Sokolov, Maxim N.

AU - Adonin, Sergey A.

N1 - Funding Information: This work was supported by Russian Science Foundation (Grant No. 21-73-00192) and, in part, by Ministry of Science and Higher Education of the Russian Federation (structural characterization of the samples, 121031700313-8). Publisher Copyright: © 2022 Elsevier Ltd

PY - 2022/4/1

Y1 - 2022/4/1

N2 - The outcomes of reactions between bismuth triiodide, 1,3,5-trimethylpyridinium iodide (1,3,5-MePyI), copper(I) or silver(I) iodides depend on the nature of solvents used in preparation. From acetone/acetonitrile mixture, there crystallizes only binuclear (1,3,5-MePy)3[Bi2I9] (1), while addition of ethanol allows isolation of homometallic (1,3,5-MePy)11.8[Cu(CH3CN)4]0.2[Bi6I22][Bi5I19]2 (2) or heterometallic polymeric (1,3,5-MePy)2{[Bi2Cu2I10]} (3) and (1,3,5-MePy)2{[Bi2Ag2I10]} (4). For all complexes, optical band gaps were estimated via diffuse reflectance spectroscopy (2.06, 1.88, 1.84 and 1.92 eV, respectively). 1–4 reveal relatively high thermal stability.

AB - The outcomes of reactions between bismuth triiodide, 1,3,5-trimethylpyridinium iodide (1,3,5-MePyI), copper(I) or silver(I) iodides depend on the nature of solvents used in preparation. From acetone/acetonitrile mixture, there crystallizes only binuclear (1,3,5-MePy)3[Bi2I9] (1), while addition of ethanol allows isolation of homometallic (1,3,5-MePy)11.8[Cu(CH3CN)4]0.2[Bi6I22][Bi5I19]2 (2) or heterometallic polymeric (1,3,5-MePy)2{[Bi2Cu2I10]} (3) and (1,3,5-MePy)2{[Bi2Ag2I10]} (4). For all complexes, optical band gaps were estimated via diffuse reflectance spectroscopy (2.06, 1.88, 1.84 and 1.92 eV, respectively). 1–4 reveal relatively high thermal stability.

KW - Bismuth

KW - Halide complexes

KW - Halometalates

KW - Heterometallic complexes

KW - Semiconductors

UR - http://www.scopus.com/inward/record.url?scp=85124589224&partnerID=8YFLogxK

U2 - 10.1016/j.poly.2022.115720

DO - 10.1016/j.poly.2022.115720

M3 - Article

AN - SCOPUS:85124589224

VL - 216

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

M1 - 115720

ER -

ID: 35537902