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High-Temperature Spin Crossover in Complexes of Iron(II) closo-Borates with 2,6-Bis(benzimidazol-2-yl)pyridine. / Ivanova, A. D.; Lavrenova, L. G.; Korotaev, E. V. et al.

In: Russian Journal of Inorganic Chemistry, Vol. 65, No. 11, 11.2020, p. 1687-1694.

Research output: Contribution to journal › Article › peer-review

Harvard

Ivanova, AD, Lavrenova, LG, Korotaev, EV, Trubina, SV, Sheludyakova, LA, Petrov, SA, Zhizhin, KY & Kuznetsov, NT 2020, 'High-Temperature Spin Crossover in Complexes of Iron(II) closo-Borates with 2,6-Bis(benzimidazol-2-yl)pyridine', Russian Journal of Inorganic Chemistry, vol. 65, no. 11, pp. 1687-1694. https://doi.org/10.1134/S0036023620110078

APA

Ivanova, A. D., Lavrenova, L. G., Korotaev, E. V., Trubina, S. V., Sheludyakova, L. A., Petrov, S. A., Zhizhin, K. Y., & Kuznetsov, N. T. (2020). High-Temperature Spin Crossover in Complexes of Iron(II) closo-Borates with 2,6-Bis(benzimidazol-2-yl)pyridine. Russian Journal of Inorganic Chemistry, 65(11), 1687-1694. https://doi.org/10.1134/S0036023620110078

Vancouver

Ivanova AD, Lavrenova LG, Korotaev EV, Trubina SV, Sheludyakova LA, Petrov SA et al. High-Temperature Spin Crossover in Complexes of Iron(II) closo-Borates with 2,6-Bis(benzimidazol-2-yl)pyridine. Russian Journal of Inorganic Chemistry. 2020 Nov;65(11):1687-1694. doi: 10.1134/S0036023620110078

Author

Ivanova, A. D. ; Lavrenova, L. G. ; Korotaev, E. V. et al. / High-Temperature Spin Crossover in Complexes of Iron(II) closo-Borates with 2,6-Bis(benzimidazol-2-yl)pyridine. In: Russian Journal of Inorganic Chemistry. 2020 ; Vol. 65, No. 11. pp. 1687-1694.

BibTeX

@article{ce80111333d74079a03e82b5cf739ab7,
title = "High-Temperature Spin Crossover in Complexes of Iron(II) closo-Borates with 2,6-Bis(benzimidazol-2-yl)pyridine",
abstract = "New iron(II) complexes with 2,6-bis(benzimidazol-2-yl)pyridine (L) and closo-borate(2–) anions—[FeL2][B10H10] ⋅ 2H2O and [FeL2][B12H12] ⋅ H2O—have been synthesized. The complexes have been characterized by static magnetic susceptibility measurements, electronic (diffuse reflectance spectra), IR, and EXAFS spectroscopy, and X-ray diffraction analysis. A study of the μeff(T) dependence in the temperature range 80–500 K has shown that the complexes exhibit a high-temperature spin crossover 1А1 ⇔ 5Т2.",
keywords = "2,6-bis(benzimidazol-2-yl)pyridine, and EXAFS spectroscopy, cluster boron anions, complexes, electronic, IR, iron(II), spin crossover, synthesis, XRD, TRANSITION MOLECULAR MATERIALS, BORON CLUSTER ANIONS, 2, 6-bis(benzimidazol-2-yl)pyridine, CHEMISTRY",
author = "Ivanova, {A. D.} and Lavrenova, {L. G.} and Korotaev, {E. V.} and Trubina, {S. V.} and Sheludyakova, {L. A.} and Petrov, {S. A.} and Zhizhin, {K. Yu} and Kuznetsov, {N. T.}",
note = "Funding Information: The work was partially supported by the Russian Science Foundation (project no. 20-63-46026). Publisher Copyright: {\textcopyright} 2020, Pleiades Publishing, Ltd. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.",
year = "2020",
month = nov,
doi = "10.1134/S0036023620110078",
language = "English",
volume = "65",
pages = "1687--1694",
journal = "Russian Journal of Inorganic Chemistry",
issn = "0036-0236",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "11",

}

RIS

TY - JOUR

T1 - High-Temperature Spin Crossover in Complexes of Iron(II) closo-Borates with 2,6-Bis(benzimidazol-2-yl)pyridine

AU - Ivanova, A. D.

AU - Lavrenova, L. G.

AU - Korotaev, E. V.

AU - Trubina, S. V.

AU - Sheludyakova, L. A.

AU - Petrov, S. A.

AU - Zhizhin, K. Yu

AU - Kuznetsov, N. T.

N1 - Funding Information: The work was partially supported by the Russian Science Foundation (project no. 20-63-46026). Publisher Copyright: © 2020, Pleiades Publishing, Ltd. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.

PY - 2020/11

Y1 - 2020/11

N2 - New iron(II) complexes with 2,6-bis(benzimidazol-2-yl)pyridine (L) and closo-borate(2–) anions—[FeL2][B10H10] ⋅ 2H2O and [FeL2][B12H12] ⋅ H2O—have been synthesized. The complexes have been characterized by static magnetic susceptibility measurements, electronic (diffuse reflectance spectra), IR, and EXAFS spectroscopy, and X-ray diffraction analysis. A study of the μeff(T) dependence in the temperature range 80–500 K has shown that the complexes exhibit a high-temperature spin crossover 1А1 ⇔ 5Т2.

AB - New iron(II) complexes with 2,6-bis(benzimidazol-2-yl)pyridine (L) and closo-borate(2–) anions—[FeL2][B10H10] ⋅ 2H2O and [FeL2][B12H12] ⋅ H2O—have been synthesized. The complexes have been characterized by static magnetic susceptibility measurements, electronic (diffuse reflectance spectra), IR, and EXAFS spectroscopy, and X-ray diffraction analysis. A study of the μeff(T) dependence in the temperature range 80–500 K has shown that the complexes exhibit a high-temperature spin crossover 1А1 ⇔ 5Т2.

KW - 2,6-bis(benzimidazol-2-yl)pyridine

KW - and EXAFS spectroscopy

KW - cluster boron anions

KW - complexes

KW - electronic

KW - IR

KW - iron(II)

KW - spin crossover

KW - synthesis

KW - XRD

KW - TRANSITION MOLECULAR MATERIALS

KW - BORON CLUSTER ANIONS

KW - 2

KW - 6-bis(benzimidazol-2-yl)pyridine

KW - CHEMISTRY

UR - http://www.scopus.com/inward/record.url?scp=85096235525&partnerID=8YFLogxK

U2 - 10.1134/S0036023620110078

DO - 10.1134/S0036023620110078

M3 - Article

AN - SCOPUS:85096235525

VL - 65

SP - 1687

EP - 1694

JO - Russian Journal of Inorganic Chemistry

JF - Russian Journal of Inorganic Chemistry

SN - 0036-0236

IS - 11

ER -

ID: 26028400