Research output: Contribution to journal › Article › peer-review
Highly conductive porous coatings based on gold organosols stabilized with the non-ionic biodegradable surfactant Ecosurf SA4. / Popovetskiy, Pavel S.; Chubar, Victoria S.; Sulyaeva, Veronica S.
In: Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 726, No. 3, 138109, 05.12.2025.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Highly conductive porous coatings based on gold organosols stabilized with the non-ionic biodegradable surfactant Ecosurf SA4
AU - Popovetskiy, Pavel S.
AU - Chubar, Victoria S.
AU - Sulyaeva, Veronica S.
N1 - The work was financially supported by the Ministry of Science and Higher Education of the Russian Federation, Project code 125021302133-1. Highly conductive porous coatings based on gold organosols stabilized with the non-ionic biodegradable surfactant Ecosurf SA4 / Pavel S. Popovetskiy, Victoria S. Chubar, Veronica S. Sulyaeva // Colloids and Surfaces A: Physicochemical and Engineering Aspects. – 2025. – Vol. 726, No. Part 3. – P. 138109. – DOI 10.1016/j.colsurfa.2025.138109
PY - 2025/12/5
Y1 - 2025/12/5
N2 - This work investigates the impact of the volume ratio of the aqueous and organic phases in reverse microemulsions on the hydrodynamic diameter and electrokinetic potential of gold nanoparticles obtained using such systems. Nonionic biodegradable ethoxylated surfactant Ecosurf SA4 was used as stabilizer. It has been determined that the destruction of micromulsions occurs under the influence of an electric field, accompanied by the separation of the aqueous phase, without coagulation of the nanoparticles. The influence of water on the electrophoretic concentration process was investigated. Different methods for its removal from the organosol were compared. Thermal treatment of pre-dehydrated and concentrated organosols resulted in porous coatings 4–8 μm thick with a metal content of approximately 90 % by mass and an extremely low surface resistivity of less than 100 nOhm per square.
AB - This work investigates the impact of the volume ratio of the aqueous and organic phases in reverse microemulsions on the hydrodynamic diameter and electrokinetic potential of gold nanoparticles obtained using such systems. Nonionic biodegradable ethoxylated surfactant Ecosurf SA4 was used as stabilizer. It has been determined that the destruction of micromulsions occurs under the influence of an electric field, accompanied by the separation of the aqueous phase, without coagulation of the nanoparticles. The influence of water on the electrophoretic concentration process was investigated. Different methods for its removal from the organosol were compared. Thermal treatment of pre-dehydrated and concentrated organosols resulted in porous coatings 4–8 μm thick with a metal content of approximately 90 % by mass and an extremely low surface resistivity of less than 100 nOhm per square.
KW - Atomic force microscopy
KW - Conductive films
KW - Nanoparticles
KW - Nonaqueous electrophoresis
KW - Scanning electron microscopy
KW - Surfactants
UR - https://www.mendeley.com/catalogue/6ca76867-eeb4-34c2-8eb0-ff388730bdbd/
UR - https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=105013841925&origin=inward
U2 - 10.1016/j.colsurfa.2025.138109
DO - 10.1016/j.colsurfa.2025.138109
M3 - Article
VL - 726
JO - Colloids and Surfaces A: Physicochemical and Engineering Aspects
JF - Colloids and Surfaces A: Physicochemical and Engineering Aspects
SN - 0927-7757
IS - 3
M1 - 138109
ER -
ID: 68881166