Research output: Contribution to journal › Article › peer-review
High-Conductive CsH2PO4 Membranes with PVDF-Based Polymers Additives. / Bagryantseva, Irina; Ponomareva, Valentina; Kungurtsev, Yuri.
In: Membranes, Vol. 13, No. 7, 617, 22.06.2023.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - High-Conductive CsH2PO4 Membranes with PVDF-Based Polymers Additives
AU - Bagryantseva, Irina
AU - Ponomareva, Valentina
AU - Kungurtsev, Yuri
N1 - Funding: This work was supported by the Russian Science Foundation grant No. 21-73-00298.
PY - 2023/6/22
Y1 - 2023/6/22
N2 - The study is devoted to one of the important problems of hydrogen energy-the comparative analysis and creation of novel highly conductive and durable medium-temperature proton membranes based on cesium dihydrogen phosphate and fluoropolymers. The proton conductivity, structural characteristics and mechanical properties of (1 - x)CsH2PO4-x fluoropolymer electrolytes (x-mass fraction, x = 0-0.3) have been investigated and analyzed. UPTFE and PVDF-based polymers (F2M, F42, and SKF26) with high thermal stability and mechanical properties have been chosen as polymer additives. The used fluoropolymers are shown to be chemical inert matrices for CsH2PO4. According to the XRD data, a monoclinic CsH2PO4 (P21/m) phase was retained in all of the polymer electrolytes studied. Highly conductive and mechanically strong composite membranes with thicknesses of ~50-100 μm were obtained for the soluble fluoropolymers (F2M, F42, and SKF26). The size and shape of CsH2PO4 particles and their distribution have been shown to significantly affect proton conductivity and the mechanical properties of the membranes. The thin-film polymer systems with uniform distributions of salt particles (up to ~300 nm) were produced via the use of different methods. The best results were achieved via the pretreatment of the suspension in a bead mill. The ability of the membranes to resist plastic deformation increases with the growth of the polymer content in comparison with the pure CsH2PO4, and the values of the mechanical strength characteristics are comparable to the best low-temperature polymer membranes. The proton-conducting membranes (1 - x)CsH2PO4-x fluoropolymer with the optimal combination of the conductivity and mechanical and hydrophobic properties are promising for use in solid acid fuel cells and other medium-temperature electrochemical devices.
AB - The study is devoted to one of the important problems of hydrogen energy-the comparative analysis and creation of novel highly conductive and durable medium-temperature proton membranes based on cesium dihydrogen phosphate and fluoropolymers. The proton conductivity, structural characteristics and mechanical properties of (1 - x)CsH2PO4-x fluoropolymer electrolytes (x-mass fraction, x = 0-0.3) have been investigated and analyzed. UPTFE and PVDF-based polymers (F2M, F42, and SKF26) with high thermal stability and mechanical properties have been chosen as polymer additives. The used fluoropolymers are shown to be chemical inert matrices for CsH2PO4. According to the XRD data, a monoclinic CsH2PO4 (P21/m) phase was retained in all of the polymer electrolytes studied. Highly conductive and mechanically strong composite membranes with thicknesses of ~50-100 μm were obtained for the soluble fluoropolymers (F2M, F42, and SKF26). The size and shape of CsH2PO4 particles and their distribution have been shown to significantly affect proton conductivity and the mechanical properties of the membranes. The thin-film polymer systems with uniform distributions of salt particles (up to ~300 nm) were produced via the use of different methods. The best results were achieved via the pretreatment of the suspension in a bead mill. The ability of the membranes to resist plastic deformation increases with the growth of the polymer content in comparison with the pure CsH2PO4, and the values of the mechanical strength characteristics are comparable to the best low-temperature polymer membranes. The proton-conducting membranes (1 - x)CsH2PO4-x fluoropolymer with the optimal combination of the conductivity and mechanical and hydrophobic properties are promising for use in solid acid fuel cells and other medium-temperature electrochemical devices.
UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85166340240&origin=inward&txGid=d5fd03259710769199ce29a12917ce2c
UR - https://www.mendeley.com/catalogue/c9d3a9f0-81fc-3265-8309-4dc40c31c006/
U2 - 10.3390/membranes13070617
DO - 10.3390/membranes13070617
M3 - Article
C2 - 37504983
VL - 13
JO - Membranes
JF - Membranes
SN - 2077-0375
IS - 7
M1 - 617
ER -
ID: 53250921