High resolution laser diode spectroscopy of the hot bands of C2HD in the first overtone region of C-H stretching. / Plastinina, D. M.; Lipskaya, A. S.; Chesnokov, E. N.
In: Journal of Molecular Spectroscopy, Vol. 406, 111955, 01.11.2024.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - High resolution laser diode spectroscopy of the hot bands of C2HD in the first overtone region of C-H stretching
AU - Plastinina, D. M.
AU - Lipskaya, A. S.
AU - Chesnokov, E. N.
PY - 2024/11/1
Y1 - 2024/11/1
N2 - The frequencies of C2HD hot bands ro-vibrational lines of the first overtone of C-H stretching were measured using tunable diode lasers. To expand the measuring range to the region of the large rotational numbers, a heated gas cell was used. Measurements were made in the range R1–R36 and P2–P14 for the transition (2,0,0,1,0) ← (0,0,0,1,0), and in the range R1–R18 for the transition (2,0,0,0,1) ← (0,0,0,0,1). The rotational parameters of the upper and lower states for the band (2,0,0,1,0) ← (0,0,0,1,0) were determined. The doublet structure of ro-vibrational lines was studied. For the transition (2,0,0,1,0) ← (0,0,0,1,0), a sharp increase in the splitting value was detected at J > 25.
AB - The frequencies of C2HD hot bands ro-vibrational lines of the first overtone of C-H stretching were measured using tunable diode lasers. To expand the measuring range to the region of the large rotational numbers, a heated gas cell was used. Measurements were made in the range R1–R36 and P2–P14 for the transition (2,0,0,1,0) ← (0,0,0,1,0), and in the range R1–R18 for the transition (2,0,0,0,1) ← (0,0,0,0,1). The rotational parameters of the upper and lower states for the band (2,0,0,1,0) ← (0,0,0,1,0) were determined. The doublet structure of ro-vibrational lines was studied. For the transition (2,0,0,1,0) ← (0,0,0,1,0), a sharp increase in the splitting value was detected at J > 25.
KW - First overtone
KW - Hot bands
KW - Laser diode spectroscopy
KW - Mono-deuterated acetylene
KW - Ro-vibrational lines
KW - l – doubling
UR - https://www.mendeley.com/catalogue/d841e6fc-3289-3f5b-9749-3ca86b64dd44/
U2 - 10.1016/j.jms.2024.111955
DO - 10.1016/j.jms.2024.111955
M3 - Article
VL - 406
JO - Journal of Molecular Spectroscopy
JF - Journal of Molecular Spectroscopy
SN - 1096-083X
M1 - 111955
ER -
ID: 60779310