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Heterometallic Catecholates of Zirconium and Alkali Metals. / Filippova, Elizaveta A.; Sukhikh, Taisiya S.; Tychinina, Anna A. et al.

In: Crystals, Vol. 16, No. 1, 12, 2026.

Research output: Contribution to journal › Article › peer-review

Harvard

Filippova, EA, Sukhikh, TS, Tychinina, AA, Eltsov, IV, Novikov, AS, Yambulatov, DS & Petrov, PA 2026, 'Heterometallic Catecholates of Zirconium and Alkali Metals', Crystals, vol. 16, no. 1, 12. https://doi.org/10.3390/cryst16010012

APA

Filippova, E. A., Sukhikh, T. S., Tychinina, A. A., Eltsov, I. V., Novikov, A. S., Yambulatov, D. S., & Petrov, P. A. (2026). Heterometallic Catecholates of Zirconium and Alkali Metals. Crystals, 16(1), [12]. https://doi.org/10.3390/cryst16010012

Vancouver

Filippova EA, Sukhikh TS, Tychinina AA, Eltsov IV, Novikov AS, Yambulatov DS et al. Heterometallic Catecholates of Zirconium and Alkali Metals. Crystals. 2026;16(1):12. doi: 10.3390/cryst16010012

Author

Filippova, Elizaveta A. ; Sukhikh, Taisiya S. ; Tychinina, Anna A. et al. / Heterometallic Catecholates of Zirconium and Alkali Metals. In: Crystals. 2026 ; Vol. 16, No. 1.

BibTeX

@article{47eda031139d442bbf63d9c581ae751a,
title = "Heterometallic Catecholates of Zirconium and Alkali Metals",
abstract = "Reaction of [Zr(η5-Cp{\textquoteright})2Cl2] (Cp{\textquoteright} = tBuC5H4) and Na2Cat36 (Cat36 = 3,6-di-tert-butylcatecholate) leads to the formation of the complexes [Na2Zr(Cat36)3(THF)2(C7H8)] (1) and [Zr(η5-Cp{\textquoteright})2(η1-Cp{\textquoteright})2] (2). Complex 1 along with its congeners [K2Zr(Cat36)3(THF)2] (3), [Li(THF)4][LiZr(Cat36)3] (4) and [Li4Zr(Cat36)4(dme)2] (5) were synthesized by the reaction of [ZrCl4(THF)2] and corresponding alkali metal catecholate M2Cat36. The complexes obtained were characterized by means of single-crystal X-ray diffraction and solution NMR spectroscopy (1H, 7Li, 13C). Relatively short Li···H contacts are present in the structures of complexes 4 and 5; nevertheless, DFT calculations have shown no covalent contribution to these interactions.",
author = "Filippova, {Elizaveta A.} and Sukhikh, {Taisiya S.} and Tychinina, {Anna A.} and Eltsov, {Ilia V.} and Novikov, {Alexander S.} and Yambulatov, {Dmitriy S.} and Petrov, {Pavel A.}",
note = "This research was financially supported by the Russian Science Foundation (project 25-73-10021), https://rscf.ru/en/project/25-73-10021/ (accessed on 7 December 2025).",
year = "2026",
doi = "10.3390/cryst16010012",
language = "English",
volume = "16",
journal = "Crystals",
issn = "2073-4352",
publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",
number = "1",

}

RIS

TY - JOUR

T1 - Heterometallic Catecholates of Zirconium and Alkali Metals

AU - Filippova, Elizaveta A.

AU - Sukhikh, Taisiya S.

AU - Tychinina, Anna A.

AU - Eltsov, Ilia V.

AU - Novikov, Alexander S.

AU - Yambulatov, Dmitriy S.

AU - Petrov, Pavel A.

N1 - This research was financially supported by the Russian Science Foundation (project 25-73-10021), https://rscf.ru/en/project/25-73-10021/ (accessed on 7 December 2025).

PY - 2026

Y1 - 2026

N2 - Reaction of [Zr(η5-Cp’)2Cl2] (Cp’ = tBuC5H4) and Na2Cat36 (Cat36 = 3,6-di-tert-butylcatecholate) leads to the formation of the complexes [Na2Zr(Cat36)3(THF)2(C7H8)] (1) and [Zr(η5-Cp’)2(η1-Cp’)2] (2). Complex 1 along with its congeners [K2Zr(Cat36)3(THF)2] (3), [Li(THF)4][LiZr(Cat36)3] (4) and [Li4Zr(Cat36)4(dme)2] (5) were synthesized by the reaction of [ZrCl4(THF)2] and corresponding alkali metal catecholate M2Cat36. The complexes obtained were characterized by means of single-crystal X-ray diffraction and solution NMR spectroscopy (1H, 7Li, 13C). Relatively short Li···H contacts are present in the structures of complexes 4 and 5; nevertheless, DFT calculations have shown no covalent contribution to these interactions.

AB - Reaction of [Zr(η5-Cp’)2Cl2] (Cp’ = tBuC5H4) and Na2Cat36 (Cat36 = 3,6-di-tert-butylcatecholate) leads to the formation of the complexes [Na2Zr(Cat36)3(THF)2(C7H8)] (1) and [Zr(η5-Cp’)2(η1-Cp’)2] (2). Complex 1 along with its congeners [K2Zr(Cat36)3(THF)2] (3), [Li(THF)4][LiZr(Cat36)3] (4) and [Li4Zr(Cat36)4(dme)2] (5) were synthesized by the reaction of [ZrCl4(THF)2] and corresponding alkali metal catecholate M2Cat36. The complexes obtained were characterized by means of single-crystal X-ray diffraction and solution NMR spectroscopy (1H, 7Li, 13C). Relatively short Li···H contacts are present in the structures of complexes 4 and 5; nevertheless, DFT calculations have shown no covalent contribution to these interactions.

UR - https://www.scopus.com/pages/publications/105028650674

UR - https://www.mendeley.com/catalogue/f125aaa7-7565-32b3-9c19-730ff03ed482/

U2 - 10.3390/cryst16010012

DO - 10.3390/cryst16010012

M3 - Article

VL - 16

JO - Crystals

JF - Crystals

SN - 2073-4352

IS - 1

M1 - 12

ER -

ID: 74323404