Research output: Contribution to journal › Article › peer-review
Heavy oil cracking in the presence of steam and nanodispersed catalysts based on different metals. / Yeletsky, Petr M.; Zaikina, Olesya O.; Sosnin, Gleb A. et al.
In: Fuel Processing Technology, Vol. 199, 106239, 01.03.2020.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Heavy oil cracking in the presence of steam and nanodispersed catalysts based on different metals
AU - Yeletsky, Petr M.
AU - Zaikina, Olesya O.
AU - Sosnin, Gleb A.
AU - Kukushkin, Roman G.
AU - Yakovlev, Vadim A.
PY - 2020/3/1
Y1 - 2020/3/1
N2 - Catalytic steam cracking (CSC) of Tatar heavy oil has been studied using nanodispersed catalysts forming in situ based on K, Fe, Ni, Mo as well as several Mo-based catalysts promoted by Ni-, Co-, and Al-based additives. The upgrading was carried out at 425 °C, catalyst content of 2 wt%, water to heavy oil wt. ratio of 0.3:1, and 1 h of residence time using a batch reactor. The highest upgrading efficacy was found in the case of non-promoted Mo-based catalyst: at a low coke yield the upgraded oil had the lowest S content as well as the highest H:С ratio. The participation of water in the case of Mo- and Ni-dispersed catalysts was confirmed by comparison with the water-free cracking experiments at the same conditions. XRD and TEM characterization have shown that the active components were in a form of oxides and/or sulfides.
AB - Catalytic steam cracking (CSC) of Tatar heavy oil has been studied using nanodispersed catalysts forming in situ based on K, Fe, Ni, Mo as well as several Mo-based catalysts promoted by Ni-, Co-, and Al-based additives. The upgrading was carried out at 425 °C, catalyst content of 2 wt%, water to heavy oil wt. ratio of 0.3:1, and 1 h of residence time using a batch reactor. The highest upgrading efficacy was found in the case of non-promoted Mo-based catalyst: at a low coke yield the upgraded oil had the lowest S content as well as the highest H:С ratio. The participation of water in the case of Mo- and Ni-dispersed catalysts was confirmed by comparison with the water-free cracking experiments at the same conditions. XRD and TEM characterization have shown that the active components were in a form of oxides and/or sulfides.
KW - Catalytic steam cracking
KW - Dispersed catalysts
KW - Heavy oil feedstocks
KW - Heavy oil upgrading
KW - Water-based upgrading
KW - VACUUM RESIDUE
KW - UNSATURATED ALIPHATICS HYDROGENATION
KW - SUPERCRITICAL WATER
KW - CRUDE-OIL
KW - AROMATIC-COMPOUNDS
KW - FLARE GASES
KW - OXIDE NANOPARTICLES
KW - PETROLEUM RESIDUE
KW - LABORATORY EXPERIMENTS
KW - IN-SITU
UR - http://www.scopus.com/inward/record.url?scp=85074584039&partnerID=8YFLogxK
U2 - 10.1016/j.fuproc.2019.106239
DO - 10.1016/j.fuproc.2019.106239
M3 - Article
AN - SCOPUS:85074584039
VL - 199
JO - Fuel Processing Technology
JF - Fuel Processing Technology
SN - 0378-3820
M1 - 106239
ER -
ID: 22403952