Standard

Halogen-rich halorhenates(IV): (Me4N)2{[ReX6](X2)} (X = Cl, Br). / Korobeynikov, Nikita A.; Usoltsev, Andrey N.; Sukhikh, Taisiya S. et al.

In: Polyhedron, Vol. 221, 115876, 15.07.2022.

Research output: Contribution to journal › Article › peer-review

Harvard

Korobeynikov, NA, Usoltsev, AN, Sukhikh, TS, Novikov, AS, Korolkov, IV, Fedin, VP, Sokolov, MN & Adonin, SA 2022, 'Halogen-rich halorhenates(IV): (Me4N)2{[ReX6](X2)} (X = Cl, Br)', Polyhedron, vol. 221, 115876. https://doi.org/10.1016/j.poly.2022.115876

APA

Korobeynikov, N. A., Usoltsev, A. N., Sukhikh, T. S., Novikov, A. S., Korolkov, I. V., Fedin, V. P., Sokolov, M. N., & Adonin, S. A. (2022). Halogen-rich halorhenates(IV): (Me4N)2{[ReX6](X2)} (X = Cl, Br). Polyhedron, 221, [115876]. https://doi.org/10.1016/j.poly.2022.115876

Vancouver

Korobeynikov NA, Usoltsev AN, Sukhikh TS, Novikov AS, Korolkov IV, Fedin VP et al. Halogen-rich halorhenates(IV): (Me4N)2{[ReX6](X2)} (X = Cl, Br). Polyhedron. 2022 Jul 15;221:115876. doi: 10.1016/j.poly.2022.115876

Author

Korobeynikov, Nikita A. ; Usoltsev, Andrey N. ; Sukhikh, Taisiya S. et al. / Halogen-rich halorhenates(IV): (Me4N)2{[ReX6](X2)} (X = Cl, Br). In: Polyhedron. 2022 ; Vol. 221.

BibTeX

@article{7513e58c00004b6c93f75873c736f818,
title = "Halogen-rich halorhenates(IV): (Me4N)2{[ReX6](X2)} (X = Cl, Br)",
abstract = "Dihalogen - halorhenates(IV) (Me4N)2{[ReX6](X2)} (X = Cl (1), Br (2)) were prepared and structurally characterized, featuring the first examples of rhenium/dihalogen supramolecular complexes. 1 and 2 reveal pseudo-3D structure; both compounds demonstrate high thermal stability, releasing Cl2 or Br2 only at elevated temperatures (over 90 and 150 °C, respectively). The energies of halogen···halogen non-covalent interactions were estimated to be as high as 2.5 and 5.1 kcal/mol for 1 and 2, respectively. Hirshfeld surface analysis was performed for both structures, allowing estimation of contributions of different non-covalent interactions to crystal packing.",
keywords = "Bromine, Chlorine, Halogen bonding, Non-covalent interactions, Rhenium",
author = "Korobeynikov, {Nikita A.} and Usoltsev, {Andrey N.} and Sukhikh, {Taisiya S.} and Novikov, {Alexander S.} and Korolkov, {Ilya V.} and Fedin, {Vladimir P.} and Sokolov, {Maxim N.} and Adonin, {Sergey A.}",
note = "Funding Information: This work was supported by Russian Science Foundation (Grant No. 18-73-10040 ) and, in part, by the Ministry of Science and Higher Education of the Russian Federation (structural characterization of the samples, 121031700313-8 ). Publisher Copyright: {\textcopyright} 2022 Elsevier Ltd",
year = "2022",
month = jul,
day = "15",
doi = "10.1016/j.poly.2022.115876",
language = "English",
volume = "221",
journal = "Polyhedron",
issn = "0277-5387",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Halogen-rich halorhenates(IV): (Me4N)2{[ReX6](X2)} (X = Cl, Br)

AU - Korobeynikov, Nikita A.

AU - Usoltsev, Andrey N.

AU - Sukhikh, Taisiya S.

AU - Novikov, Alexander S.

AU - Korolkov, Ilya V.

AU - Fedin, Vladimir P.

AU - Sokolov, Maxim N.

AU - Adonin, Sergey A.

N1 - Funding Information: This work was supported by Russian Science Foundation (Grant No. 18-73-10040 ) and, in part, by the Ministry of Science and Higher Education of the Russian Federation (structural characterization of the samples, 121031700313-8 ). Publisher Copyright: © 2022 Elsevier Ltd

PY - 2022/7/15

Y1 - 2022/7/15

N2 - Dihalogen - halorhenates(IV) (Me4N)2{[ReX6](X2)} (X = Cl (1), Br (2)) were prepared and structurally characterized, featuring the first examples of rhenium/dihalogen supramolecular complexes. 1 and 2 reveal pseudo-3D structure; both compounds demonstrate high thermal stability, releasing Cl2 or Br2 only at elevated temperatures (over 90 and 150 °C, respectively). The energies of halogen···halogen non-covalent interactions were estimated to be as high as 2.5 and 5.1 kcal/mol for 1 and 2, respectively. Hirshfeld surface analysis was performed for both structures, allowing estimation of contributions of different non-covalent interactions to crystal packing.

AB - Dihalogen - halorhenates(IV) (Me4N)2{[ReX6](X2)} (X = Cl (1), Br (2)) were prepared and structurally characterized, featuring the first examples of rhenium/dihalogen supramolecular complexes. 1 and 2 reveal pseudo-3D structure; both compounds demonstrate high thermal stability, releasing Cl2 or Br2 only at elevated temperatures (over 90 and 150 °C, respectively). The energies of halogen···halogen non-covalent interactions were estimated to be as high as 2.5 and 5.1 kcal/mol for 1 and 2, respectively. Hirshfeld surface analysis was performed for both structures, allowing estimation of contributions of different non-covalent interactions to crystal packing.

KW - Bromine

KW - Chlorine

KW - Halogen bonding

KW - Non-covalent interactions

KW - Rhenium

UR - http://www.scopus.com/inward/record.url?scp=85129423345&partnerID=8YFLogxK

U2 - 10.1016/j.poly.2022.115876

DO - 10.1016/j.poly.2022.115876

M3 - Article

AN - SCOPUS:85129423345

VL - 221

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

M1 - 115876

ER -

ID: 36060682