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Green- and red-phosphorescent Mn(II) iodide complexes derived from 1,3-bis(diphenylphosphinyl)propane. / Davydova, Maria P.; Yu Bagryanskaya, Irina; Bauer, Irina A. et al.

In: Polyhedron, Vol. 188, 114706, 15.09.2020.

Research output: Contribution to journal › Article › peer-review

Harvard

Davydova, MP, Yu Bagryanskaya, I, Bauer, IA, Rakhmanova, MI, Morgalyuk, VP, Brel, VK & Artem'ev, AV 2020, 'Green- and red-phosphorescent Mn(II) iodide complexes derived from 1,3-bis(diphenylphosphinyl)propane', Polyhedron, vol. 188, 114706. https://doi.org/10.1016/j.poly.2020.114706

APA

Davydova, M. P., Yu Bagryanskaya, I., Bauer, I. A., Rakhmanova, M. I., Morgalyuk, V. P., Brel, V. K., & Artem'ev, A. V. (2020). Green- and red-phosphorescent Mn(II) iodide complexes derived from 1,3-bis(diphenylphosphinyl)propane. Polyhedron, 188, [114706]. https://doi.org/10.1016/j.poly.2020.114706

Vancouver

Davydova MP, Yu Bagryanskaya I, Bauer IA, Rakhmanova MI, Morgalyuk VP, Brel VK et al. Green- and red-phosphorescent Mn(II) iodide complexes derived from 1,3-bis(diphenylphosphinyl)propane. Polyhedron. 2020 Sept 15;188:114706. doi: 10.1016/j.poly.2020.114706

Author

Davydova, Maria P. ; Yu Bagryanskaya, Irina ; Bauer, Irina A. et al. / Green- and red-phosphorescent Mn(II) iodide complexes derived from 1,3-bis(diphenylphosphinyl)propane. In: Polyhedron. 2020 ; Vol. 188.

BibTeX

@article{6c6b4d0c1f0849a8a20cd13ae0c52b6d,
title = "Green- and red-phosphorescent Mn(II) iodide complexes derived from 1,3-bis(diphenylphosphinyl)propane",
abstract = "The reaction of 1,3-bis(diphenylphosphinyl)propane (dpppO2) with MnI2, depending on the reactants ratio, affords either 1D coordination polymer, [Mn(dpppO2)I2]n (1), or cage-like complex [Mn2(dpppO2)4I2]l2 (2). Polymer 1 contains Mn(II) ions in a tetrahedral [Mn@O2I2] arrangement, while the metal ions of 2 feature a square-pyramidal [Mn@O4I] geometry. At ambient temperature, 1 emits green phosphorescence (λmax = 530 nm) with unusually short lifetime being 50 µs, while 2 displays long-lived red phosphorescence with λmax = 660 nm and the lifetime of 1400 µs.",
keywords = "Coordination polymers, Luminescence, Mn(II) complexes, Phosphine oxide ligands, Phosphorescence, MANGANESE(II), OXIDE, PHOSPHORAMIDE, HALIDE, LUMINESCENCE, MN2+ IONS",
author = "Davydova, {Maria P.} and {Yu Bagryanskaya}, Irina and Bauer, {Irina A.} and Rakhmanova, {Mariana I.} and Morgalyuk, {Vasilii P.} and Brel, {Valery K.} and Artem'ev, {Alexander V.}",
note = "Funding Information: This research was supported by Russian Foundation for Basic Research (Project № 18-33-20079 ). Synthesis of the dpppO 2 ligand was performed with the financial support from Ministry of Science and Higher Education of the Russian Federation. The authors grateful to the Multi-Access Chemical Service Center SB RAS for sc-XRD analysis. Publisher Copyright: {\textcopyright} 2020 Elsevier Ltd Copyright: Copyright 2020 Elsevier B.V., All rights reserved.",
year = "2020",
month = sep,
day = "15",
doi = "10.1016/j.poly.2020.114706",
language = "English",
volume = "188",
journal = "Polyhedron",
issn = "0277-5387",
publisher = "Elsevier Science Publishing Company, Inc.",

}

RIS

TY - JOUR

T1 - Green- and red-phosphorescent Mn(II) iodide complexes derived from 1,3-bis(diphenylphosphinyl)propane

AU - Davydova, Maria P.

AU - Yu Bagryanskaya, Irina

AU - Bauer, Irina A.

AU - Rakhmanova, Mariana I.

AU - Morgalyuk, Vasilii P.

AU - Brel, Valery K.

AU - Artem'ev, Alexander V.

N1 - Funding Information: This research was supported by Russian Foundation for Basic Research (Project № 18-33-20079 ). Synthesis of the dpppO 2 ligand was performed with the financial support from Ministry of Science and Higher Education of the Russian Federation. The authors grateful to the Multi-Access Chemical Service Center SB RAS for sc-XRD analysis. Publisher Copyright: © 2020 Elsevier Ltd Copyright: Copyright 2020 Elsevier B.V., All rights reserved.

PY - 2020/9/15

Y1 - 2020/9/15

N2 - The reaction of 1,3-bis(diphenylphosphinyl)propane (dpppO2) with MnI2, depending on the reactants ratio, affords either 1D coordination polymer, [Mn(dpppO2)I2]n (1), or cage-like complex [Mn2(dpppO2)4I2]l2 (2). Polymer 1 contains Mn(II) ions in a tetrahedral [Mn@O2I2] arrangement, while the metal ions of 2 feature a square-pyramidal [Mn@O4I] geometry. At ambient temperature, 1 emits green phosphorescence (λmax = 530 nm) with unusually short lifetime being 50 µs, while 2 displays long-lived red phosphorescence with λmax = 660 nm and the lifetime of 1400 µs.

AB - The reaction of 1,3-bis(diphenylphosphinyl)propane (dpppO2) with MnI2, depending on the reactants ratio, affords either 1D coordination polymer, [Mn(dpppO2)I2]n (1), or cage-like complex [Mn2(dpppO2)4I2]l2 (2). Polymer 1 contains Mn(II) ions in a tetrahedral [Mn@O2I2] arrangement, while the metal ions of 2 feature a square-pyramidal [Mn@O4I] geometry. At ambient temperature, 1 emits green phosphorescence (λmax = 530 nm) with unusually short lifetime being 50 µs, while 2 displays long-lived red phosphorescence with λmax = 660 nm and the lifetime of 1400 µs.

KW - Coordination polymers

KW - Luminescence

KW - Mn(II) complexes

KW - Phosphine oxide ligands

KW - Phosphorescence

KW - MANGANESE(II)

KW - OXIDE

KW - PHOSPHORAMIDE

KW - HALIDE

KW - LUMINESCENCE

KW - MN2+ IONS

UR - http://www.scopus.com/inward/record.url?scp=85088822141&partnerID=8YFLogxK

U2 - 10.1016/j.poly.2020.114706

DO - 10.1016/j.poly.2020.114706

M3 - Article

AN - SCOPUS:85088822141

VL - 188

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

M1 - 114706

ER -

ID: 24869571