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Graphene-polymer composite conductivity in air and water. / Andryushchenko, Vladimir; Sorokin, Dmitry; Morozova, Marina et al.

In: Applied Surface Science, Vol. 567, 150843, 30.11.2021.

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Andryushchenko V, Sorokin D, Morozova M, Solnyshkina O, Smovzh D. Graphene-polymer composite conductivity in air and water. Applied Surface Science. 2021 Nov 30;567:150843. doi: 10.1016/j.apsusc.2021.150843

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Andryushchenko, Vladimir ; Sorokin, Dmitry ; Morozova, Marina et al. / Graphene-polymer composite conductivity in air and water. In: Applied Surface Science. 2021 ; Vol. 567.

BibTeX

@article{562fdfcafafa453198c53515405a8d03,
title = "Graphene-polymer composite conductivity in air and water",
abstract = "An experimental study of the graphene conductivity in an aqueous environment is carried out in this study. The presence of a time dependence of the graphene resistivity in water is established. In addition, the characteristic relaxation times of resistivity are determined when graphene is immersed in water and then dried. The resistivity temperature dependence is used to estimate the values of the band gap arising in graphene due to water contact. Based on the analysis of molecular dynamics modeling data, a possible mechanism responsible for the opening of the band gap in graphene is proposed. This mechanism is associated with the inhomogeneous tangential electric field appearance in the plane of the graphene flake, caused by water molecules structured near the graphene surface.",
keywords = "Band gap, Graphene conductivity, Molecular dynamics, Water structuring",
author = "Vladimir Andryushchenko and Dmitry Sorokin and Marina Morozova and Olga Solnyshkina and Dmitry Smovzh",
note = "Funding Information: The theoretical calculation was financially supported by IT SB RAS (AAAA-A19-119061490008-3), experimental investigation was financially supported by RFBR / Russian Foundation for Basic Research (Project No. 18-29-19099). Publisher Copyright: {\textcopyright} 2021",
year = "2021",
month = nov,
day = "30",
doi = "10.1016/j.apsusc.2021.150843",
language = "English",
volume = "567",
journal = "Applied Surface Science",
issn = "0169-4332",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Graphene-polymer composite conductivity in air and water

AU - Andryushchenko, Vladimir

AU - Sorokin, Dmitry

AU - Morozova, Marina

AU - Solnyshkina, Olga

AU - Smovzh, Dmitry

N1 - Funding Information: The theoretical calculation was financially supported by IT SB RAS (AAAA-A19-119061490008-3), experimental investigation was financially supported by RFBR / Russian Foundation for Basic Research (Project No. 18-29-19099). Publisher Copyright: © 2021

PY - 2021/11/30

Y1 - 2021/11/30

N2 - An experimental study of the graphene conductivity in an aqueous environment is carried out in this study. The presence of a time dependence of the graphene resistivity in water is established. In addition, the characteristic relaxation times of resistivity are determined when graphene is immersed in water and then dried. The resistivity temperature dependence is used to estimate the values of the band gap arising in graphene due to water contact. Based on the analysis of molecular dynamics modeling data, a possible mechanism responsible for the opening of the band gap in graphene is proposed. This mechanism is associated with the inhomogeneous tangential electric field appearance in the plane of the graphene flake, caused by water molecules structured near the graphene surface.

AB - An experimental study of the graphene conductivity in an aqueous environment is carried out in this study. The presence of a time dependence of the graphene resistivity in water is established. In addition, the characteristic relaxation times of resistivity are determined when graphene is immersed in water and then dried. The resistivity temperature dependence is used to estimate the values of the band gap arising in graphene due to water contact. Based on the analysis of molecular dynamics modeling data, a possible mechanism responsible for the opening of the band gap in graphene is proposed. This mechanism is associated with the inhomogeneous tangential electric field appearance in the plane of the graphene flake, caused by water molecules structured near the graphene surface.

KW - Band gap

KW - Graphene conductivity

KW - Molecular dynamics

KW - Water structuring

UR - http://www.scopus.com/inward/record.url?scp=85111959270&partnerID=8YFLogxK

U2 - 10.1016/j.apsusc.2021.150843

DO - 10.1016/j.apsusc.2021.150843

M3 - Article

AN - SCOPUS:85111959270

VL - 567

JO - Applied Surface Science

JF - Applied Surface Science

SN - 0169-4332

M1 - 150843

ER -

ID: 29279031