Genesis of volatiles in suprasubduction basaltic melts from Tolbachik Volcano, Kamchatka. / Dobretsov, N. L.; Simonov, V. A.; Kotlyarov, A. V. et al.
In: Russian Geology and Geophysics, Vol. 58, No. 8, 01.08.2017, p. 869-886.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Genesis of volatiles in suprasubduction basaltic melts from Tolbachik Volcano, Kamchatka
AU - Dobretsov, N. L.
AU - Simonov, V. A.
AU - Kotlyarov, A. V.
AU - Stupakov, S. I.
PY - 2017/8/1
Y1 - 2017/8/1
N2 - Vitreous basalts and plagioclase lapilli from Tolbachik Volcano studied by high-temperature gas chromatography reveal features of a fluid regime uncommon to suprasubduction melts. Prominent depletion in volatiles confirms the anomalous behavior of the Tolbachik fluid systems. Vitreous basalts contain minor amounts of water (0.16-0.27 wt.%) and carbon dioxide (95-440 ppm). New data on volatiles in the Tolbachik plagioclase lapilli show very low contents of CO2 and total gas (exclusive of H2O) and enrichment in reduced fluids (CO and CH4) relative to the basalts. In general, analysis of basalts and plagioclase lapilli from different eruptions trace a progressive increase in reduced fluids (CO and CH4) and decrease in CO2 and total gas from past to present events. The concentrations of CO2 decrease, while those of CO and CH4 in basalts and plagioclase lapilli increase systematically with an increase in FeO/MgO ratios and K2O contents in the lavas and in anorthite component in plagioclase.
AB - Vitreous basalts and plagioclase lapilli from Tolbachik Volcano studied by high-temperature gas chromatography reveal features of a fluid regime uncommon to suprasubduction melts. Prominent depletion in volatiles confirms the anomalous behavior of the Tolbachik fluid systems. Vitreous basalts contain minor amounts of water (0.16-0.27 wt.%) and carbon dioxide (95-440 ppm). New data on volatiles in the Tolbachik plagioclase lapilli show very low contents of CO2 and total gas (exclusive of H2O) and enrichment in reduced fluids (CO and CH4) relative to the basalts. In general, analysis of basalts and plagioclase lapilli from different eruptions trace a progressive increase in reduced fluids (CO and CH4) and decrease in CO2 and total gas from past to present events. The concentrations of CO2 decrease, while those of CO and CH4 in basalts and plagioclase lapilli increase systematically with an increase in FeO/MgO ratios and K2O contents in the lavas and in anorthite component in plagioclase.
KW - high-temperature gas chromatography
KW - Kamchatka
KW - suprasubduction basaltic melt
KW - Tolbachik Volcano
KW - volatiles
KW - LAVA
KW - INCLUSIONS
KW - H2O
KW - COMPONENTS
KW - TRACE-ELEMENTS
KW - ARC
KW - MAGMAS
KW - ERUPTION
KW - PETROLOGY
KW - RUSSIA
UR - http://www.scopus.com/inward/record.url?scp=85026871291&partnerID=8YFLogxK
U2 - 10.1016/j.rgg.2016.09.033
DO - 10.1016/j.rgg.2016.09.033
M3 - Article
AN - SCOPUS:85026871291
VL - 58
SP - 869
EP - 886
JO - Russian Geology and Geophysics
JF - Russian Geology and Geophysics
SN - 1068-7971
IS - 8
ER -
ID: 9966001