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Generation of Perfluoro- and 1-Chloroperfluoro-Indanyl and -Benzocyclobutenyl Cations with Perfluoroalkyl Groups in the Aliphatic Ring. / Mezhenkova, T. V.; Karpov, V. M.; Zonov, Ya V. et al.

In: Russian Journal of Organic Chemistry, Vol. 55, No. 2, 01.02.2019, p. 193-201.

Research output: Contribution to journal › Article › peer-review

Harvard

Mezhenkova, TV, Karpov, VM, Zonov, YV & Chuikov, IP 2019, 'Generation of Perfluoro- and 1-Chloroperfluoro-Indanyl and -Benzocyclobutenyl Cations with Perfluoroalkyl Groups in the Aliphatic Ring', Russian Journal of Organic Chemistry, vol. 55, no. 2, pp. 193-201. https://doi.org/10.1134/S1070428019020118

APA

Mezhenkova, T. V., Karpov, V. M., Zonov, Y. V., & Chuikov, I. P. (2019). Generation of Perfluoro- and 1-Chloroperfluoro-Indanyl and -Benzocyclobutenyl Cations with Perfluoroalkyl Groups in the Aliphatic Ring. Russian Journal of Organic Chemistry, 55(2), 193-201. https://doi.org/10.1134/S1070428019020118

Vancouver

Mezhenkova TV, Karpov VM, Zonov YV, Chuikov IP. Generation of Perfluoro- and 1-Chloroperfluoro-Indanyl and -Benzocyclobutenyl Cations with Perfluoroalkyl Groups in the Aliphatic Ring. Russian Journal of Organic Chemistry. 2019 Feb 1;55(2):193-201. doi: 10.1134/S1070428019020118

Author

Mezhenkova, T. V. ; Karpov, V. M. ; Zonov, Ya V. et al. / Generation of Perfluoro- and 1-Chloroperfluoro-Indanyl and -Benzocyclobutenyl Cations with Perfluoroalkyl Groups in the Aliphatic Ring. In: Russian Journal of Organic Chemistry. 2019 ; Vol. 55, No. 2. pp. 193-201.

BibTeX

@article{79ecd0b5553b4fabb4cf9f6c67afdf04,
title = "Generation of Perfluoro- and 1-Chloroperfluoro-Indanyl and -Benzocyclobutenyl Cations with Perfluoroalkyl Groups in the Aliphatic Ring",
abstract = " Perfluoro(alkylbenzocycloalken-1-yl) cations were generated in a SbF 5 −SO 2 ClF medium from perfluorinated indane and benzocyclobutene derivatives containing perfluoroalkyl groups in the alicyclic fragment. The cations exist in equilibrium with their precursors. Adding SO 2 Cl 2 to the system led to the formation of polyfluoroalkylbenzocycloalken-1-yl cations with a chlorine substituent at the cationic center. The structures of the cations were determined by 19 F and 13 C NMR spectroscopy and confirmed by the structures of perfluoroketones formed on their hydrolysis. ",
keywords = "benzocyclobutene, cation, chlorine, fluorinated, indane, perfluoroalkyl group, REARRANGEMENTS, FLUORINE-CONTAINING CARBOCATIONS",
author = "Mezhenkova, {T. V.} and Karpov, {V. M.} and Zonov, {Ya V.} and Chuikov, {I. P.}",
year = "2019",
month = feb,
day = "1",
doi = "10.1134/S1070428019020118",
language = "English",
volume = "55",
pages = "193--201",
journal = "Russian Journal of Organic Chemistry",
issn = "1070-4280",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "2",

}

RIS

TY - JOUR

T1 - Generation of Perfluoro- and 1-Chloroperfluoro-Indanyl and -Benzocyclobutenyl Cations with Perfluoroalkyl Groups in the Aliphatic Ring

AU - Mezhenkova, T. V.

AU - Karpov, V. M.

AU - Zonov, Ya V.

AU - Chuikov, I. P.

PY - 2019/2/1

Y1 - 2019/2/1

N2 - Perfluoro(alkylbenzocycloalken-1-yl) cations were generated in a SbF 5 −SO 2 ClF medium from perfluorinated indane and benzocyclobutene derivatives containing perfluoroalkyl groups in the alicyclic fragment. The cations exist in equilibrium with their precursors. Adding SO 2 Cl 2 to the system led to the formation of polyfluoroalkylbenzocycloalken-1-yl cations with a chlorine substituent at the cationic center. The structures of the cations were determined by 19 F and 13 C NMR spectroscopy and confirmed by the structures of perfluoroketones formed on their hydrolysis.

AB - Perfluoro(alkylbenzocycloalken-1-yl) cations were generated in a SbF 5 −SO 2 ClF medium from perfluorinated indane and benzocyclobutene derivatives containing perfluoroalkyl groups in the alicyclic fragment. The cations exist in equilibrium with their precursors. Adding SO 2 Cl 2 to the system led to the formation of polyfluoroalkylbenzocycloalken-1-yl cations with a chlorine substituent at the cationic center. The structures of the cations were determined by 19 F and 13 C NMR spectroscopy and confirmed by the structures of perfluoroketones formed on their hydrolysis.

KW - benzocyclobutene

KW - cation

KW - chlorine

KW - fluorinated

KW - indane

KW - perfluoroalkyl group

KW - REARRANGEMENTS

KW - FLUORINE-CONTAINING CARBOCATIONS

UR - http://www.scopus.com/inward/record.url?scp=85064818900&partnerID=8YFLogxK

U2 - 10.1134/S1070428019020118

DO - 10.1134/S1070428019020118

M3 - Article

AN - SCOPUS:85064818900

VL - 55

SP - 193

EP - 201

JO - Russian Journal of Organic Chemistry

JF - Russian Journal of Organic Chemistry

SN - 1070-4280

IS - 2

ER -

ID: 19649497