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Generation of a hetero spin complex from iron(Ii) iodide with redox active acenaphthene-1,2-diimine. / Yambulatov, Dmitriy S.; Nikolaevskii, Stanislav A.; Kiskin, Mikhail A. et al.

In: Molecules, Vol. 26, No. 10, 2998, 18.05.2021.

Research output: Contribution to journal › Article › peer-review

Harvard

Yambulatov, DS, Nikolaevskii, SA, Kiskin, MA, Kholin, KV, Khrizanforov, MN, Budnikova, YG, Babeshkin, KA, Efimov, NN, Goloveshkin, AS, Imshennik, VK, Maksimov, YV, Kadilenko, EM, Gritsan, NP & Eremenko, IL 2021, 'Generation of a hetero spin complex from iron(Ii) iodide with redox active acenaphthene-1,2-diimine', Molecules, vol. 26, no. 10, 2998. https://doi.org/10.3390/molecules26102998

APA

Yambulatov, D. S., Nikolaevskii, S. A., Kiskin, M. A., Kholin, K. V., Khrizanforov, M. N., Budnikova, Y. G., Babeshkin, K. A., Efimov, N. N., Goloveshkin, A. S., Imshennik, V. K., Maksimov, Y. V., Kadilenko, E. M., Gritsan, N. P., & Eremenko, I. L. (2021). Generation of a hetero spin complex from iron(Ii) iodide with redox active acenaphthene-1,2-diimine. Molecules, 26(10), [2998]. https://doi.org/10.3390/molecules26102998

Vancouver

Yambulatov DS, Nikolaevskii SA, Kiskin MA, Kholin KV, Khrizanforov MN, Budnikova YG et al. Generation of a hetero spin complex from iron(Ii) iodide with redox active acenaphthene-1,2-diimine. Molecules. 2021 May 18;26(10):2998. doi: 10.3390/molecules26102998

Author

Yambulatov, Dmitriy S. ; Nikolaevskii, Stanislav A. ; Kiskin, Mikhail A. et al. / Generation of a hetero spin complex from iron(Ii) iodide with redox active acenaphthene-1,2-diimine. In: Molecules. 2021 ; Vol. 26, No. 10.

BibTeX

@article{ff9eb9e64d5f442aadde802e31b1c7da,
title = "Generation of a hetero spin complex from iron(Ii) iodide with redox active acenaphthene-1,2-diimine",
abstract = "The reaction of the redox active 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene (dppBIAN) and iron(II) iodide in acetonitrile led to a new complex [(dpp-BIAN)FeII I2 ] (1). Molecular structure of 1 was determined by the single crystal X-ray diffraction analysis. The spin state of the iron cation in complex 1 at room temperature and the magnetic behavior of 1 in the temperature range of 2–300 K were studied using Mossbauer spectroscopy and magnetic susceptibility measurements, respectively. The neutral character of dpp-BIAN in 1 was confirmed by IR and UV spectroscopy. The electrochemistry of 1 was studied in solution and solid state using cyclic voltammetry. The generation of the radical anion form of the dpp-BIAN ligand upon reduction of 1 in a CH2 Cl2 solution was monitored by EPR spectroscopy.",
keywords = "BIAN, Cyclic voltammetry, Iron(II) complex, Magnetic measurements, Molecular structure, α-diimine",
author = "Yambulatov, {Dmitriy S.} and Nikolaevskii, {Stanislav A.} and Kiskin, {Mikhail A.} and Kholin, {Kirill V.} and Khrizanforov, {Mikhail N.} and Budnikova, {Yulia G.} and Babeshkin, {Konstantin A.} and Efimov, {Nikolay N.} and Goloveshkin, {Alexander S.} and Imshennik, {Vladimir K.} and Maksimov, {Yurii V.} and Kadilenko, {Evgeny M.} and Gritsan, {Nina P.} and Eremenko, {Igor L.}",
note = "Funding Information: This research (synthesis of 1, X-ray crystallography, IR, and UV spectroscopy, magnetochemistry) was financially supported by the Russian Science Foundation (project 19-13-00436). E.M.K. acknowledges RFBR (grant 20-33-90104) for the financial support of the computational part of this paper and the Supercomputer Centre of Novosibirsk State University for computational resources. Publisher Copyright: {\textcopyright} 2021 by the authors. Licensee MDPI, Basel, Switzerland. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.",
year = "2021",
month = may,
day = "18",
doi = "10.3390/molecules26102998",
language = "English",
volume = "26",
journal = "Molecules",
issn = "1420-3049",
publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",
number = "10",

}

RIS

TY - JOUR

T1 - Generation of a hetero spin complex from iron(Ii) iodide with redox active acenaphthene-1,2-diimine

AU - Yambulatov, Dmitriy S.

AU - Nikolaevskii, Stanislav A.

AU - Kiskin, Mikhail A.

AU - Kholin, Kirill V.

AU - Khrizanforov, Mikhail N.

AU - Budnikova, Yulia G.

AU - Babeshkin, Konstantin A.

AU - Efimov, Nikolay N.

AU - Goloveshkin, Alexander S.

AU - Imshennik, Vladimir K.

AU - Maksimov, Yurii V.

AU - Kadilenko, Evgeny M.

AU - Gritsan, Nina P.

AU - Eremenko, Igor L.

N1 - Funding Information: This research (synthesis of 1, X-ray crystallography, IR, and UV spectroscopy, magnetochemistry) was financially supported by the Russian Science Foundation (project 19-13-00436). E.M.K. acknowledges RFBR (grant 20-33-90104) for the financial support of the computational part of this paper and the Supercomputer Centre of Novosibirsk State University for computational resources. Publisher Copyright: © 2021 by the authors. Licensee MDPI, Basel, Switzerland. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.

PY - 2021/5/18

Y1 - 2021/5/18

N2 - The reaction of the redox active 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene (dppBIAN) and iron(II) iodide in acetonitrile led to a new complex [(dpp-BIAN)FeII I2 ] (1). Molecular structure of 1 was determined by the single crystal X-ray diffraction analysis. The spin state of the iron cation in complex 1 at room temperature and the magnetic behavior of 1 in the temperature range of 2–300 K were studied using Mossbauer spectroscopy and magnetic susceptibility measurements, respectively. The neutral character of dpp-BIAN in 1 was confirmed by IR and UV spectroscopy. The electrochemistry of 1 was studied in solution and solid state using cyclic voltammetry. The generation of the radical anion form of the dpp-BIAN ligand upon reduction of 1 in a CH2 Cl2 solution was monitored by EPR spectroscopy.

AB - The reaction of the redox active 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene (dppBIAN) and iron(II) iodide in acetonitrile led to a new complex [(dpp-BIAN)FeII I2 ] (1). Molecular structure of 1 was determined by the single crystal X-ray diffraction analysis. The spin state of the iron cation in complex 1 at room temperature and the magnetic behavior of 1 in the temperature range of 2–300 K were studied using Mossbauer spectroscopy and magnetic susceptibility measurements, respectively. The neutral character of dpp-BIAN in 1 was confirmed by IR and UV spectroscopy. The electrochemistry of 1 was studied in solution and solid state using cyclic voltammetry. The generation of the radical anion form of the dpp-BIAN ligand upon reduction of 1 in a CH2 Cl2 solution was monitored by EPR spectroscopy.

KW - BIAN

KW - Cyclic voltammetry

KW - Iron(II) complex

KW - Magnetic measurements

KW - Molecular structure

KW - α-diimine

UR - http://www.scopus.com/inward/record.url?scp=85106918554&partnerID=8YFLogxK

U2 - 10.3390/molecules26102998

DO - 10.3390/molecules26102998

M3 - Article

C2 - 34070061

AN - SCOPUS:85106918554

VL - 26

JO - Molecules

JF - Molecules

SN - 1420-3049

IS - 10

M1 - 2998

ER -

ID: 28750478