Research output: Contribution to journal › Article › peer-review
Gas-phase oxidation of propylene into acetone on a V2O5/TiO2 catalyst : Effect of pressure and role of water. / Chernov, A. N.; Sobolev, V. I.; Koltunov, K. Yu.
In: Russian Journal of Applied Chemistry, Vol. 90, No. 9, 01.09.2017, p. 1439-1442.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Gas-phase oxidation of propylene into acetone on a V2O5/TiO2 catalyst
T2 - Effect of pressure and role of water
AU - Chernov, A. N.
AU - Sobolev, V. I.
AU - Koltunov, K. Yu
PY - 2017/9/1
Y1 - 2017/9/1
N2 - The effect of pressure and role of water on gas-phase oxidation of propylene into acetone on a V2O5/TiO2 catalyst were investigated. A positive effect of increasing the pressure and water content in the reaction mixture in the oxidative conversion of propylene into acetone on a V2O5/TiO2 catalyst was observed. The results showed that the reaction occurred via intermediate formation of isopropanol, which was produced in situ as a result of the acid-catalyzed hydration of propylene and, under certain conditions, may be the main product.
AB - The effect of pressure and role of water on gas-phase oxidation of propylene into acetone on a V2O5/TiO2 catalyst were investigated. A positive effect of increasing the pressure and water content in the reaction mixture in the oxidative conversion of propylene into acetone on a V2O5/TiO2 catalyst was observed. The results showed that the reaction occurred via intermediate formation of isopropanol, which was produced in situ as a result of the acid-catalyzed hydration of propylene and, under certain conditions, may be the main product.
KW - SELECTIVE OXIDATION
KW - ACID CATALYSTS
KW - CONVERSION
KW - ETHANE
UR - http://www.scopus.com/inward/record.url?scp=85040107364&partnerID=8YFLogxK
U2 - 10.1134/S1070427217090105
DO - 10.1134/S1070427217090105
M3 - Article
AN - SCOPUS:85040107364
VL - 90
SP - 1439
EP - 1442
JO - Russian Journal of Applied Chemistry
JF - Russian Journal of Applied Chemistry
SN - 1070-4272
IS - 9
ER -
ID: 9642350