Research output: Contribution to journal › Article › peer-review
Formation of Water-Bearing Defects in Olivine in the Presence of Water–Hydrocarbon Fluid at 6.3 GPa and 1200°C. / Sokol, A. G.; Kupriyanov, I. N.; Tomilenko, A. A. et al.
In: Doklady Earth Sciences, Vol. 483, No. 1, 01.12.2018, p. 1451-1453.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Formation of Water-Bearing Defects in Olivine in the Presence of Water–Hydrocarbon Fluid at 6.3 GPa and 1200°C
AU - Sokol, A. G.
AU - Kupriyanov, I. N.
AU - Tomilenko, A. A.
AU - Bul’bak, T. A.
AU - Palyanov, Yu N.
AU - Sobolev, N. V.
PY - 2018/12/1
Y1 - 2018/12/1
N2 - The main trends of water dissolution in Fe-bearing olivine have been investigated in the olivine–H2O–hydrocarbon fluid system in experiments at a pressure of 6.3 GPa, a temperature of 1200°C, and hydrogen fugacity (fH2) buffered by the Mo–MoO2 equilibrium. The content and contribution of ОH defects of different types in Fe-bearing olivines depend on the composition of reduced fluids in the system. As the fraction of hydrocarbons in the fluid increases, the H2O content in olivine crystals decreases from 900 to 160–180 ppm, while the ОН absorption peaks become lower at high frequencies and occupy a larger part of the infrared spectrum in the low-frequency region. According to the experimental results, even the deepest seated mantle olivines with OH defects were not equilibrated with a fluid rich in light alkanes or oxygenated hydrocarbons.
AB - The main trends of water dissolution in Fe-bearing olivine have been investigated in the olivine–H2O–hydrocarbon fluid system in experiments at a pressure of 6.3 GPa, a temperature of 1200°C, and hydrogen fugacity (fH2) buffered by the Mo–MoO2 equilibrium. The content and contribution of ОH defects of different types in Fe-bearing olivines depend on the composition of reduced fluids in the system. As the fraction of hydrocarbons in the fluid increases, the H2O content in olivine crystals decreases from 900 to 160–180 ppm, while the ОН absorption peaks become lower at high frequencies and occupy a larger part of the infrared spectrum in the low-frequency region. According to the experimental results, even the deepest seated mantle olivines with OH defects were not equilibrated with a fluid rich in light alkanes or oxygenated hydrocarbons.
KW - H2O STORAGE CAPACITY
KW - OXYGEN FUGACITY
KW - SILICA ACTIVITY
KW - TEMPERATURE
KW - FORSTERITE
KW - KIMBERLITE
KW - CARBON
KW - MANTLE
KW - IRON
UR - http://www.scopus.com/inward/record.url?scp=85058857228&partnerID=8YFLogxK
U2 - 10.1134/S1028334X18110156
DO - 10.1134/S1028334X18110156
M3 - Article
AN - SCOPUS:85058857228
VL - 483
SP - 1451
EP - 1453
JO - Doklady Earth Sciences
JF - Doklady Earth Sciences
SN - 1028-334X
IS - 1
ER -
ID: 17927091