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Formation of methane hydrate from water sorbed by anthracite : An investgation by low-field NMR relaxation. / Turakhanov, A. H.; Shumskayte, M. Y.; Ildyakov, A. V. et al.

In: Fuel, Vol. 262, 116656, 15.02.2020.

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Turakhanov AH, Shumskayte MY, Ildyakov AV, Manakov AY, Smirnov VG, Glinskikh VN et al. Formation of methane hydrate from water sorbed by anthracite: An investgation by low-field NMR relaxation. Fuel. 2020 Feb 15;262:116656. doi: 10.1016/j.fuel.2019.116656

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Turakhanov, A. H. ; Shumskayte, M. Y. ; Ildyakov, A. V. et al. / Formation of methane hydrate from water sorbed by anthracite : An investgation by low-field NMR relaxation. In: Fuel. 2020 ; Vol. 262.

BibTeX

@article{7a42a2c9be7e4faaa503f2ed9e06e6d4,
title = "Formation of methane hydrate from water sorbed by anthracite: An investgation by low-field NMR relaxation",
abstract = "Transverse relaxation time spectra T2 were studied for the samples (a) of wet coal in which methane hydrate was obtained, (b) wet coal exposed under the pressure of methane without the formation of the hydrate, and (c) initial wet coal. In all these cases, the samples of wet coal contained only water adsorbed in the fine pores of the coal substance. It was demonstrated that hydrate formation and the competitive sorption of methane at the positions previously occupied by water causes replacement of a part of water from coal mesopores into larger pores. The data obtained confirm a previously proposed multistage model (Smirnov et al., 2018) of hydrate formation in natural coal, which includes the stages of replacement of a part of sorbed water from coal pores by gas, the formation of microscopic water fragments in larger coal pores, and the formation of hydrate from this water.",
keywords = "Coal, Gas hydrate, Methane, NMR, Spin-spin relaxation, Water adsorption, COAL, DECOMPOSITION, PARAMETERS",
author = "Turakhanov, {A. H.} and Shumskayte, {M. Y.} and Ildyakov, {A. V.} and Manakov, {A. Y.} and Smirnov, {V. G.} and Glinskikh, {V. N.} and Duchkov, {A. D.}",
note = "Publisher Copyright: {\textcopyright} 2019 Elsevier Ltd",
year = "2020",
month = feb,
day = "15",
doi = "10.1016/j.fuel.2019.116656",
language = "English",
volume = "262",
journal = "Fuel",
issn = "0016-2361",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Formation of methane hydrate from water sorbed by anthracite

T2 - An investgation by low-field NMR relaxation

AU - Turakhanov, A. H.

AU - Shumskayte, M. Y.

AU - Ildyakov, A. V.

AU - Manakov, A. Y.

AU - Smirnov, V. G.

AU - Glinskikh, V. N.

AU - Duchkov, A. D.

N1 - Publisher Copyright: © 2019 Elsevier Ltd

PY - 2020/2/15

Y1 - 2020/2/15

N2 - Transverse relaxation time spectra T2 were studied for the samples (a) of wet coal in which methane hydrate was obtained, (b) wet coal exposed under the pressure of methane without the formation of the hydrate, and (c) initial wet coal. In all these cases, the samples of wet coal contained only water adsorbed in the fine pores of the coal substance. It was demonstrated that hydrate formation and the competitive sorption of methane at the positions previously occupied by water causes replacement of a part of water from coal mesopores into larger pores. The data obtained confirm a previously proposed multistage model (Smirnov et al., 2018) of hydrate formation in natural coal, which includes the stages of replacement of a part of sorbed water from coal pores by gas, the formation of microscopic water fragments in larger coal pores, and the formation of hydrate from this water.

AB - Transverse relaxation time spectra T2 were studied for the samples (a) of wet coal in which methane hydrate was obtained, (b) wet coal exposed under the pressure of methane without the formation of the hydrate, and (c) initial wet coal. In all these cases, the samples of wet coal contained only water adsorbed in the fine pores of the coal substance. It was demonstrated that hydrate formation and the competitive sorption of methane at the positions previously occupied by water causes replacement of a part of water from coal mesopores into larger pores. The data obtained confirm a previously proposed multistage model (Smirnov et al., 2018) of hydrate formation in natural coal, which includes the stages of replacement of a part of sorbed water from coal pores by gas, the formation of microscopic water fragments in larger coal pores, and the formation of hydrate from this water.

KW - Coal

KW - Gas hydrate

KW - Methane

KW - NMR

KW - Spin-spin relaxation

KW - Water adsorption

KW - COAL

KW - DECOMPOSITION

KW - PARAMETERS

UR - http://www.scopus.com/inward/record.url?scp=85075719584&partnerID=8YFLogxK

U2 - 10.1016/j.fuel.2019.116656

DO - 10.1016/j.fuel.2019.116656

M3 - Article

AN - SCOPUS:85075719584

VL - 262

JO - Fuel

JF - Fuel

SN - 0016-2361

M1 - 116656

ER -

ID: 22500209