Standard

Formation of Chiral Structures in UV-Initiated Formose Reaction. / Stovbun, S. V.; Skoblin, A. A.; Zanin, A. M. et al.

In: Doklady Physical Chemistry, Vol. 479, No. 1-2, 01.03.2018, p. 57-60.

Research output: Contribution to journal › Article › peer-review

Harvard

Stovbun, SV, Skoblin, AA, Zanin, AM, Tverdislov, VA, Taran, OP & Parmon, VN 2018, 'Formation of Chiral Structures in UV-Initiated Formose Reaction', Doklady Physical Chemistry, vol. 479, no. 1-2, pp. 57-60. https://doi.org/10.1134/S001250161803003X

APA

Stovbun, S. V., Skoblin, A. A., Zanin, A. M., Tverdislov, V. A., Taran, O. P., & Parmon, V. N. (2018). Formation of Chiral Structures in UV-Initiated Formose Reaction. Doklady Physical Chemistry, 479(1-2), 57-60. https://doi.org/10.1134/S001250161803003X

Vancouver

Stovbun SV, Skoblin AA, Zanin AM, Tverdislov VA, Taran OP, Parmon VN. Formation of Chiral Structures in UV-Initiated Formose Reaction. Doklady Physical Chemistry. 2018 Mar 1;479(1-2):57-60. doi: 10.1134/S001250161803003X

Author

Stovbun, S. V. ; Skoblin, A. A. ; Zanin, A. M. et al. / Formation of Chiral Structures in UV-Initiated Formose Reaction. In: Doklady Physical Chemistry. 2018 ; Vol. 479, No. 1-2. pp. 57-60.

BibTeX

@article{e24c55dd9f474a76a828948c6e90b156,
title = "Formation of Chiral Structures in UV-Initiated Formose Reaction",
abstract = "It has been found that the UV-initiated formose reaction in an extremely concentrated aqueous solution of formaldehyde gives sugars and other biologically significant chiral compounds with sp3-hybridized carbon atom. The reaction leads to an optically active condensed phase, which is a result of the spontaneous spatial separation of enantiomers in the racemate into the antipodes, similarly to the separation of enantiomers of different chirality sign in the famous Pasteur experiments. In our opinion, such a scenario is as close as possible to the actually realized de novo scenario of synthesis of chiral prebiotic molecules and matrices.",
author = "Stovbun, {S. V.} and Skoblin, {A. A.} and Zanin, {A. M.} and Tverdislov, {V. A.} and Taran, {O. P.} and Parmon, {V. N.}",
note = "Publisher Copyright: {\textcopyright} 2018, Pleiades Publishing, Ltd.",
year = "2018",
month = mar,
day = "1",
doi = "10.1134/S001250161803003X",
language = "English",
volume = "479",
pages = "57--60",
journal = "Doklady Physical Chemistry",
issn = "0012-5016",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "1-2",

}

RIS

TY - JOUR

T1 - Formation of Chiral Structures in UV-Initiated Formose Reaction

AU - Stovbun, S. V.

AU - Skoblin, A. A.

AU - Zanin, A. M.

AU - Tverdislov, V. A.

AU - Taran, O. P.

AU - Parmon, V. N.

N1 - Publisher Copyright: © 2018, Pleiades Publishing, Ltd.

PY - 2018/3/1

Y1 - 2018/3/1

N2 - It has been found that the UV-initiated formose reaction in an extremely concentrated aqueous solution of formaldehyde gives sugars and other biologically significant chiral compounds with sp3-hybridized carbon atom. The reaction leads to an optically active condensed phase, which is a result of the spontaneous spatial separation of enantiomers in the racemate into the antipodes, similarly to the separation of enantiomers of different chirality sign in the famous Pasteur experiments. In our opinion, such a scenario is as close as possible to the actually realized de novo scenario of synthesis of chiral prebiotic molecules and matrices.

AB - It has been found that the UV-initiated formose reaction in an extremely concentrated aqueous solution of formaldehyde gives sugars and other biologically significant chiral compounds with sp3-hybridized carbon atom. The reaction leads to an optically active condensed phase, which is a result of the spontaneous spatial separation of enantiomers in the racemate into the antipodes, similarly to the separation of enantiomers of different chirality sign in the famous Pasteur experiments. In our opinion, such a scenario is as close as possible to the actually realized de novo scenario of synthesis of chiral prebiotic molecules and matrices.

UR - http://www.scopus.com/inward/record.url?scp=85047245494&partnerID=8YFLogxK

U2 - 10.1134/S001250161803003X

DO - 10.1134/S001250161803003X

M3 - Article

AN - SCOPUS:85047245494

VL - 479

SP - 57

EP - 60

JO - Doklady Physical Chemistry

JF - Doklady Physical Chemistry

SN - 0012-5016

IS - 1-2

ER -

ID: 13488131