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Formation of Chiral Structures in Photoinitiated Formose Reaction. / Stovbun, S. V.; Skoblin, A. A.; Zanin, A. M. et al.

In: High Energy Chemistry, Vol. 52, No. 2, 01.03.2018, p. 108-116.

Research output: Contribution to journal › Article › peer-review

Harvard

Stovbun, SV, Skoblin, AA, Zanin, AM, Tverdislov, VA, Taran, OP & Parmon, VN 2018, 'Formation of Chiral Structures in Photoinitiated Formose Reaction', High Energy Chemistry, vol. 52, no. 2, pp. 108-116. https://doi.org/10.1134/S0018143918020145

APA

Stovbun, S. V., Skoblin, A. A., Zanin, A. M., Tverdislov, V. A., Taran, O. P., & Parmon, V. N. (2018). Formation of Chiral Structures in Photoinitiated Formose Reaction. High Energy Chemistry, 52(2), 108-116. https://doi.org/10.1134/S0018143918020145

Vancouver

Stovbun SV, Skoblin AA, Zanin AM, Tverdislov VA, Taran OP, Parmon VN. Formation of Chiral Structures in Photoinitiated Formose Reaction. High Energy Chemistry. 2018 Mar 1;52(2):108-116. doi: 10.1134/S0018143918020145

Author

Stovbun, S. V. ; Skoblin, A. A. ; Zanin, A. M. et al. / Formation of Chiral Structures in Photoinitiated Formose Reaction. In: High Energy Chemistry. 2018 ; Vol. 52, No. 2. pp. 108-116.

BibTeX

@article{2df812965c6a4bf2a8ed12eba1c3123b,
title = "Formation of Chiral Structures in Photoinitiated Formose Reaction",
abstract = "The possibility to synthesize biologically important sugars and other chiral compounds without any initiators in the UV-initiated reaction of formaldehyde in aqueous solution has been shown for the first time. An optically active condensed phase due to an sp3-hybridized carbon atom has been detected. It has been shown that this phase is formed due to the spatial cleavage of antipodes in the racemate, similar to the cleavage of enantiomers following the sign of chirality in the known experiments of Pasteur. The results have been obtained under the conditions that correspond to modern ideas about the form and vector of prebiological evolution and, therefore, can be of fundamental importance for understanding the processes of biopoiesis.",
keywords = "biopoiesis, chirality, formaldehyde, formose reaction, photoionization",
author = "Stovbun, {S. V.} and Skoblin, {A. A.} and Zanin, {A. M.} and Tverdislov, {V. A.} and Taran, {O. P.} and Parmon, {V. N.}",
year = "2018",
month = mar,
day = "1",
doi = "10.1134/S0018143918020145",
language = "English",
volume = "52",
pages = "108--116",
journal = "High Energy Chemistry",
issn = "0018-1439",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "2",

}

RIS

TY - JOUR

T1 - Formation of Chiral Structures in Photoinitiated Formose Reaction

AU - Stovbun, S. V.

AU - Skoblin, A. A.

AU - Zanin, A. M.

AU - Tverdislov, V. A.

AU - Taran, O. P.

AU - Parmon, V. N.

PY - 2018/3/1

Y1 - 2018/3/1

N2 - The possibility to synthesize biologically important sugars and other chiral compounds without any initiators in the UV-initiated reaction of formaldehyde in aqueous solution has been shown for the first time. An optically active condensed phase due to an sp3-hybridized carbon atom has been detected. It has been shown that this phase is formed due to the spatial cleavage of antipodes in the racemate, similar to the cleavage of enantiomers following the sign of chirality in the known experiments of Pasteur. The results have been obtained under the conditions that correspond to modern ideas about the form and vector of prebiological evolution and, therefore, can be of fundamental importance for understanding the processes of biopoiesis.

AB - The possibility to synthesize biologically important sugars and other chiral compounds without any initiators in the UV-initiated reaction of formaldehyde in aqueous solution has been shown for the first time. An optically active condensed phase due to an sp3-hybridized carbon atom has been detected. It has been shown that this phase is formed due to the spatial cleavage of antipodes in the racemate, similar to the cleavage of enantiomers following the sign of chirality in the known experiments of Pasteur. The results have been obtained under the conditions that correspond to modern ideas about the form and vector of prebiological evolution and, therefore, can be of fundamental importance for understanding the processes of biopoiesis.

KW - biopoiesis

KW - chirality

KW - formaldehyde

KW - formose reaction

KW - photoionization

UR - http://www.scopus.com/inward/record.url?scp=85044787503&partnerID=8YFLogxK

U2 - 10.1134/S0018143918020145

DO - 10.1134/S0018143918020145

M3 - Article

AN - SCOPUS:85044787503

VL - 52

SP - 108

EP - 116

JO - High Energy Chemistry

JF - High Energy Chemistry

SN - 0018-1439

IS - 2

ER -

ID: 12299571