Research output: Contribution to journal › Article › peer-review
Formation mechanism of MgO hollow nanospheres via calcination of C-MgO composite produced by electric arc spraying. / Smovzh, Dmitry V.; Sakhapov, Salavat Z.; Zaikovskii, Alexey V. et al.
In: Ceramics International, Vol. 45, No. 6, 15.04.2019, p. 7338-7343.Research output: Contribution to journal › Article › peer-review
}
TY - JOUR
T1 - Formation mechanism of MgO hollow nanospheres via calcination of C-MgO composite produced by electric arc spraying
AU - Smovzh, Dmitry V.
AU - Sakhapov, Salavat Z.
AU - Zaikovskii, Alexey V.
AU - Chernova, Svetlana A.
AU - Novopashin, Sergey A.
PY - 2019/4/15
Y1 - 2019/4/15
N2 - Spherical MgO nanoparticles were obtained using the method of electric arc spraying of the Mg-C composite electrode, followed by calcination in air. The composition and morphology of nanostructures, formed at spraying, were studied; kinetics of changes in the elemental composition of the carbon-magnesium composite was investigated at annealing in the range of up to 900 °C. It is shown that during arc spraying, core-shell nanoparticles are formed with a carbon core and shell enriched with magnesium nanoparticles, which are oxidized to MgO at contact with the atmosphere. When carbon-magnesium composites are annealed, carbon burns out; the morphology of magnesium oxide nanoparticles is a 250-nm sphere of magnesium crystals of 20–30 nm in size.
AB - Spherical MgO nanoparticles were obtained using the method of electric arc spraying of the Mg-C composite electrode, followed by calcination in air. The composition and morphology of nanostructures, formed at spraying, were studied; kinetics of changes in the elemental composition of the carbon-magnesium composite was investigated at annealing in the range of up to 900 °C. It is shown that during arc spraying, core-shell nanoparticles are formed with a carbon core and shell enriched with magnesium nanoparticles, which are oxidized to MgO at contact with the atmosphere. When carbon-magnesium composites are annealed, carbon burns out; the morphology of magnesium oxide nanoparticles is a 250-nm sphere of magnesium crystals of 20–30 nm in size.
KW - Arc discharge
KW - Calcination
KW - Condensation
KW - MgO
KW - Nanoceramics
KW - Nucleation
KW - Powders
KW - PERFORMANCE
KW - ADSORBENTS
KW - GRAPHENE
KW - NANOCRYSTALLINE MAGNESIUM-OXIDE
KW - NANOSTRUCTURES
KW - CO2 CAPTURE
KW - NANOPARTICLES
KW - REFRACTORIES
KW - RAPID SYNTHESIS
KW - MORPHOLOGY
UR - http://www.scopus.com/inward/record.url?scp=85060230697&partnerID=8YFLogxK
U2 - 10.1016/j.ceramint.2019.01.017
DO - 10.1016/j.ceramint.2019.01.017
M3 - Article
AN - SCOPUS:85060230697
VL - 45
SP - 7338
EP - 7343
JO - Ceramics International
JF - Ceramics International
SN - 0272-8842
IS - 6
ER -
ID: 18297402