Research output: Contribution to journal › Article › peer-review
Flux growth and optical properties of K7CaY2(B5O10)3 nonlinear crystal. / Kuznetsov, A. B.; Ezhov, D. M.; Kokh, K. A. et al.
In: Materials Research Bulletin, Vol. 107, 01.11.2018, p. 333-338.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Flux growth and optical properties of K7CaY2(B5O10)3 nonlinear crystal
AU - Kuznetsov, A. B.
AU - Ezhov, D. M.
AU - Kokh, K. A.
AU - Kononova, N. G.
AU - Shevchenko, V. S.
AU - Rashchenko, S. V.
AU - Pestryakov, E. V.
AU - Svetlichnyi, V. A.
AU - Lapin, I. N.
AU - Kokh, A. E.
PY - 2018/11/1
Y1 - 2018/11/1
N2 - Non-centrosymmetric borates K7CaY2(B5O10)3 have been synthesized by solid state reaction and the crystals were successfully grown by the top seeded solution growth method using K2O-B2O3-CaF2 flux. According to the single X-ray diffraction, the structure belongs to the R32 space group with lattice parameters a = 13.2516(2) Å and c = 14.9679(3) Å. IR, Raman, absorption spectra as well as data on melting temperature were obtained for the crystal. The short edge of UV absorption and SHG intensity comparable with KH2PO4 (KDP) suggests that this crystal is a promising nonlinear-optical material.
AB - Non-centrosymmetric borates K7CaY2(B5O10)3 have been synthesized by solid state reaction and the crystals were successfully grown by the top seeded solution growth method using K2O-B2O3-CaF2 flux. According to the single X-ray diffraction, the structure belongs to the R32 space group with lattice parameters a = 13.2516(2) Å and c = 14.9679(3) Å. IR, Raman, absorption spectra as well as data on melting temperature were obtained for the crystal. The short edge of UV absorption and SHG intensity comparable with KH2PO4 (KDP) suggests that this crystal is a promising nonlinear-optical material.
KW - Borates
KW - Crystal structure
KW - Growth from high temperature solutions
KW - Nonlinear optical
KW - Nonlinear optics materials
KW - DESIGN
KW - FIELD
KW - MORPHOLOGY
UR - http://www.scopus.com/inward/record.url?scp=85051127046&partnerID=8YFLogxK
U2 - 10.1016/j.materresbull.2018.07.037
DO - 10.1016/j.materresbull.2018.07.037
M3 - Article
AN - SCOPUS:85051127046
VL - 107
SP - 333
EP - 338
JO - Materials Research Bulletin
JF - Materials Research Bulletin
SN - 0025-5408
ER -
ID: 16083941