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Fluorination of heterocyclic compounds accompanied by molecular rearrangements. / Borodkin, Gennady I.

In: Chemistry of Heterocyclic Compounds, Vol. 60, No. 7-8, 02.10.2024, p. 323-335.

Research output: Contribution to journal › Article › peer-review

Harvard

Borodkin, GI 2024, 'Fluorination of heterocyclic compounds accompanied by molecular rearrangements', Chemistry of Heterocyclic Compounds, vol. 60, no. 7-8, pp. 323-335. https://doi.org/10.1007/s10593-024-03340-0

APA

Borodkin, G. I. (2024). Fluorination of heterocyclic compounds accompanied by molecular rearrangements. Chemistry of Heterocyclic Compounds, 60(7-8), 323-335. https://doi.org/10.1007/s10593-024-03340-0

Vancouver

Borodkin GI. Fluorination of heterocyclic compounds accompanied by molecular rearrangements. Chemistry of Heterocyclic Compounds. 2024 Oct 2;60(7-8):323-335. doi: 10.1007/s10593-024-03340-0

Author

Borodkin, Gennady I. / Fluorination of heterocyclic compounds accompanied by molecular rearrangements. In: Chemistry of Heterocyclic Compounds. 2024 ; Vol. 60, No. 7-8. pp. 323-335.

BibTeX

@article{1510db9887ba407c901833e8c0f65eac,
title = "Fluorination of heterocyclic compounds accompanied by molecular rearrangements",
abstract = "(Figure presented.) Fluorination of heterocyclic compounds accompanied by molecular rearrangements is an area of synthesis experiencing rapid advances. One of the characteristics of electrophilic and oxidative fluorination is the involvement of carbocations, radicals, and radical ions which can undergo rearrangements. Such rearrangements expand the range of fluorinated products, which are sometimes difficult to access by direct fluorination of heterocyclic compounds. The purpose of this review is to systematize and analyze the literature data published over the past decade on fluorination of heterocyclic compounds accompanied by molecular rearrangements. Particular attention is paid to the analysis of reaction mechanisms and the problem of selectivity. ",
keywords = "fluorination, heterocyclic compounds, reaction mechanism, rearrangement, selectivity",
author = "Borodkin, {Gennady I.}",
year = "2024",
month = oct,
day = "2",
doi = "10.1007/s10593-024-03340-0",
language = "English",
volume = "60",
pages = "323--335",
journal = "Chemistry of Heterocyclic Compounds",
issn = "0009-3122",
publisher = "Springer New York",
number = "7-8",

}

RIS

TY - JOUR

T1 - Fluorination of heterocyclic compounds accompanied by molecular rearrangements

AU - Borodkin, Gennady I.

PY - 2024/10/2

Y1 - 2024/10/2

N2 - (Figure presented.) Fluorination of heterocyclic compounds accompanied by molecular rearrangements is an area of synthesis experiencing rapid advances. One of the characteristics of electrophilic and oxidative fluorination is the involvement of carbocations, radicals, and radical ions which can undergo rearrangements. Such rearrangements expand the range of fluorinated products, which are sometimes difficult to access by direct fluorination of heterocyclic compounds. The purpose of this review is to systematize and analyze the literature data published over the past decade on fluorination of heterocyclic compounds accompanied by molecular rearrangements. Particular attention is paid to the analysis of reaction mechanisms and the problem of selectivity.

AB - (Figure presented.) Fluorination of heterocyclic compounds accompanied by molecular rearrangements is an area of synthesis experiencing rapid advances. One of the characteristics of electrophilic and oxidative fluorination is the involvement of carbocations, radicals, and radical ions which can undergo rearrangements. Such rearrangements expand the range of fluorinated products, which are sometimes difficult to access by direct fluorination of heterocyclic compounds. The purpose of this review is to systematize and analyze the literature data published over the past decade on fluorination of heterocyclic compounds accompanied by molecular rearrangements. Particular attention is paid to the analysis of reaction mechanisms and the problem of selectivity.

KW - fluorination

KW - heterocyclic compounds

KW - reaction mechanism

KW - rearrangement

KW - selectivity

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85205337370&origin=inward&txGid=e994963d4bdd7931a00a9517fd2afeb7

UR - https://www.mendeley.com/catalogue/53be97ba-dbdb-33f1-af3f-651dd50dbbf1/

U2 - 10.1007/s10593-024-03340-0

DO - 10.1007/s10593-024-03340-0

M3 - Article

VL - 60

SP - 323

EP - 335

JO - Chemistry of Heterocyclic Compounds

JF - Chemistry of Heterocyclic Compounds

SN - 0009-3122

IS - 7-8

ER -

ID: 60817871