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Fingerprints of Critical Phenomena in a Quantum Paraelectric Ensemble of Nanoconfined Water Molecules. / Belyanchikov, Mikhail A.; Savinov, Maxim; Proschek, Petr et al.

In: Nano Letters, Vol. 22, No. 8, 27.04.2022, p. 3380-3384.

Research output: Contribution to journal › Article › peer-review

Harvard

Belyanchikov, MA, Savinov, M, Proschek, P, Prokleška, J, Zhukova, ES, Thomas, VG, Bedran, ZV, Kadlec, F, Kamba, S, Dressel, M & Gorshunov, BP 2022, 'Fingerprints of Critical Phenomena in a Quantum Paraelectric Ensemble of Nanoconfined Water Molecules', Nano Letters, vol. 22, no. 8, pp. 3380-3384. https://doi.org/10.1021/acs.nanolett.2c00638

APA

Belyanchikov, M. A., Savinov, M., Proschek, P., Prokleška, J., Zhukova, E. S., Thomas, V. G., Bedran, Z. V., Kadlec, F., Kamba, S., Dressel, M., & Gorshunov, B. P. (2022). Fingerprints of Critical Phenomena in a Quantum Paraelectric Ensemble of Nanoconfined Water Molecules. Nano Letters, 22(8), 3380-3384. https://doi.org/10.1021/acs.nanolett.2c00638

Vancouver

Belyanchikov MA, Savinov M, Proschek P, Prokleška J, Zhukova ES, Thomas VG et al. Fingerprints of Critical Phenomena in a Quantum Paraelectric Ensemble of Nanoconfined Water Molecules. Nano Letters. 2022 Apr 27;22(8):3380-3384. Epub 2022 Apr 7. doi: 10.1021/acs.nanolett.2c00638

Author

Belyanchikov, Mikhail A. ; Savinov, Maxim ; Proschek, Petr et al. / Fingerprints of Critical Phenomena in a Quantum Paraelectric Ensemble of Nanoconfined Water Molecules. In: Nano Letters. 2022 ; Vol. 22, No. 8. pp. 3380-3384.

BibTeX

@article{8ce066c3a754498aa16deca5874cab55,
title = "Fingerprints of Critical Phenomena in a Quantum Paraelectric Ensemble of Nanoconfined Water Molecules",
abstract = "We have studied the radio frequency dielectric response of a system consisting of separate polar water molecules periodically arranged in nanocages formed by the crystal lattice of the gemstone beryl. Below T = 20-30 K, quantum effects start to dominate the properties of the electric dipolar system as manifested by a crossover between the Curie-Weiss and the Barrett regimes in the temperature-dependent real dielectric permittivity ϵ′(T). When analyzing in detail the temperature evolution of the reciprocal permittivity (ϵ′)-1 down to T ≈ 0.3 K and comparing it with the data obtained for conventional quantum paraelectrics, like SrTiO3, KTaO3, we discovered clear signatures of a quantum-critical behavior of the interacting water molecular dipoles: Between T = 6 and 14 K, the reciprocal permittivity follows a quadratic temperature dependence and displays a shallow minimum below 3 K. This is the first observation of {"}dielectric fingerprints{"}of quantum-critical phenomena in a paraelectric system of coupled point electric dipoles. ",
keywords = "nanoconfined water, quantum criticality, quantum paraelectric, spectroscopy",
author = "Belyanchikov, {Mikhail A.} and Maxim Savinov and Petr Proschek and Jan Prokle{\v s}ka and Zhukova, {Elena S.} and Thomas, {Victor G.} and Bedran, {Zakhar V.} and Filip Kadlec and Stanislav Kamba and Martin Dressel and Gorshunov, {Boris P.}",
note = "Funding Information: The work was supported by the Russian Science Foundation, Grant 22-22-00091. We are grateful to A. Loidl and P. Lunkenheimer for fruitful discussions. Publisher Copyright: {\textcopyright} 2022 American Chemical Society.",
year = "2022",
month = apr,
day = "27",
doi = "10.1021/acs.nanolett.2c00638",
language = "English",
volume = "22",
pages = "3380--3384",
journal = "Nano Letters",
issn = "1530-6984",
publisher = "American Chemical Society",
number = "8",

}

RIS

TY - JOUR

T1 - Fingerprints of Critical Phenomena in a Quantum Paraelectric Ensemble of Nanoconfined Water Molecules

AU - Belyanchikov, Mikhail A.

AU - Savinov, Maxim

AU - Proschek, Petr

AU - Prokleška, Jan

AU - Zhukova, Elena S.

AU - Thomas, Victor G.

AU - Bedran, Zakhar V.

AU - Kadlec, Filip

AU - Kamba, Stanislav

AU - Dressel, Martin

AU - Gorshunov, Boris P.

N1 - Funding Information: The work was supported by the Russian Science Foundation, Grant 22-22-00091. We are grateful to A. Loidl and P. Lunkenheimer for fruitful discussions. Publisher Copyright: © 2022 American Chemical Society.

PY - 2022/4/27

Y1 - 2022/4/27

N2 - We have studied the radio frequency dielectric response of a system consisting of separate polar water molecules periodically arranged in nanocages formed by the crystal lattice of the gemstone beryl. Below T = 20-30 K, quantum effects start to dominate the properties of the electric dipolar system as manifested by a crossover between the Curie-Weiss and the Barrett regimes in the temperature-dependent real dielectric permittivity ϵ′(T). When analyzing in detail the temperature evolution of the reciprocal permittivity (ϵ′)-1 down to T ≈ 0.3 K and comparing it with the data obtained for conventional quantum paraelectrics, like SrTiO3, KTaO3, we discovered clear signatures of a quantum-critical behavior of the interacting water molecular dipoles: Between T = 6 and 14 K, the reciprocal permittivity follows a quadratic temperature dependence and displays a shallow minimum below 3 K. This is the first observation of "dielectric fingerprints"of quantum-critical phenomena in a paraelectric system of coupled point electric dipoles.

AB - We have studied the radio frequency dielectric response of a system consisting of separate polar water molecules periodically arranged in nanocages formed by the crystal lattice of the gemstone beryl. Below T = 20-30 K, quantum effects start to dominate the properties of the electric dipolar system as manifested by a crossover between the Curie-Weiss and the Barrett regimes in the temperature-dependent real dielectric permittivity ϵ′(T). When analyzing in detail the temperature evolution of the reciprocal permittivity (ϵ′)-1 down to T ≈ 0.3 K and comparing it with the data obtained for conventional quantum paraelectrics, like SrTiO3, KTaO3, we discovered clear signatures of a quantum-critical behavior of the interacting water molecular dipoles: Between T = 6 and 14 K, the reciprocal permittivity follows a quadratic temperature dependence and displays a shallow minimum below 3 K. This is the first observation of "dielectric fingerprints"of quantum-critical phenomena in a paraelectric system of coupled point electric dipoles.

KW - nanoconfined water

KW - quantum criticality

KW - quantum paraelectric

KW - spectroscopy

UR - http://www.scopus.com/inward/record.url?scp=85128583142&partnerID=8YFLogxK

U2 - 10.1021/acs.nanolett.2c00638

DO - 10.1021/acs.nanolett.2c00638

M3 - Article

C2 - 35389652

AN - SCOPUS:85128583142

VL - 22

SP - 3380

EP - 3384

JO - Nano Letters

JF - Nano Letters

SN - 1530-6984

IS - 8

ER -

ID: 35992265