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Ferrocenyl-substituted nitronyl nitroxide in the design of one dimensional magnets. / Maryunina, Kseniya; Nigomedyanova, Daria; Morozov, Vitaliy A et al.

In: Dalton Transactions, Vol. 53, No. 4, 23.01.2024, p. 1714-1721.

Research output: Contribution to journal › Article › peer-review

Harvard

Maryunina, K, Nigomedyanova, D, Morozov, VA, Smirnova, K, Letyagin, G, Romanenko, G, Efimov, NN, Bogomyakov, A & Ovcharenko, V 2024, 'Ferrocenyl-substituted nitronyl nitroxide in the design of one dimensional magnets', Dalton Transactions, vol. 53, no. 4, pp. 1714-1721. https://doi.org/10.1039/d3dt03858k

APA

Maryunina, K., Nigomedyanova, D., Morozov, V. A., Smirnova, K., Letyagin, G., Romanenko, G., Efimov, N. N., Bogomyakov, A., & Ovcharenko, V. (2024). Ferrocenyl-substituted nitronyl nitroxide in the design of one dimensional magnets. Dalton Transactions, 53(4), 1714-1721. https://doi.org/10.1039/d3dt03858k

Vancouver

Maryunina K, Nigomedyanova D, Morozov VA, Smirnova K, Letyagin G, Romanenko G et al. Ferrocenyl-substituted nitronyl nitroxide in the design of one dimensional magnets. Dalton Transactions. 2024 Jan 23;53(4):1714-1721. Epub 2023 Dec 19. doi: 10.1039/d3dt03858k

Author

Maryunina, Kseniya ; Nigomedyanova, Daria ; Morozov, Vitaliy A et al. / Ferrocenyl-substituted nitronyl nitroxide in the design of one dimensional magnets. In: Dalton Transactions. 2024 ; Vol. 53, No. 4. pp. 1714-1721.

BibTeX

@article{d1c247aa0ad44eaaaba7c8fe0efe1827,
title = "Ferrocenyl-substituted nitronyl nitroxide in the design of one dimensional magnets",
abstract = "By the reaction of M(hfac) 2 (M = Mn(II), Co(II), Cu(II), and Zn(II); hfac is the hexafluoroacetylacetonate anion) and ferrocenyl-substituted nitronyl nitroxide (L), we succeeded in the synthesis of stable heterospin complexes: mononuclear [Zn(hfac) 2L], trinuclear {[Cu(hfac) 2] 3L 2} and chain polymer [Mn(hfac) 2L] n and [Co(hfac) 2L] n . The specific steric bulkiness of the ferrocenyl substituent leads to the formation of trans-type coordination polyhedra in the [Mn(hfac) 2L] n and [Co(hfac) 2L] n chains. The introduction of the ferrocene substituent leads to an effective weakening of intermolecular or interchain magnetic exchange coupling. Ferrimagnetic ordering was observed for one-dimensional complexes [M(hfac) 2L] n (M = Mn(II), Co(II)). [Co(hfac) 2L] n exhibits features of single-chain magnet behaviour: slow relaxation of magnetization below 13 K is associated with a high coercive field (54 kOe at 2 K). ",
author = "Kseniya Maryunina and Daria Nigomedyanova and Morozov, {Vitaliy A} and Kristina Smirnova and Gleb Letyagin and Galina Romanenko and Efimov, {N. N.} and Artem Bogomyakov and Victor Ovcharenko",
note = "We thank the Ministry of Science and Higher Education of the Russian Federation (Grant No. 075-15-2020-779).",
year = "2024",
month = jan,
day = "23",
doi = "10.1039/d3dt03858k",
language = "English",
volume = "53",
pages = "1714--1721",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "4",

}

RIS

TY - JOUR

T1 - Ferrocenyl-substituted nitronyl nitroxide in the design of one dimensional magnets

AU - Maryunina, Kseniya

AU - Nigomedyanova, Daria

AU - Morozov, Vitaliy A

AU - Smirnova, Kristina

AU - Letyagin, Gleb

AU - Romanenko, Galina

AU - Efimov, N. N.

AU - Bogomyakov, Artem

AU - Ovcharenko, Victor

N1 - We thank the Ministry of Science and Higher Education of the Russian Federation (Grant No. 075-15-2020-779).

PY - 2024/1/23

Y1 - 2024/1/23

N2 - By the reaction of M(hfac) 2 (M = Mn(II), Co(II), Cu(II), and Zn(II); hfac is the hexafluoroacetylacetonate anion) and ferrocenyl-substituted nitronyl nitroxide (L), we succeeded in the synthesis of stable heterospin complexes: mononuclear [Zn(hfac) 2L], trinuclear {[Cu(hfac) 2] 3L 2} and chain polymer [Mn(hfac) 2L] n and [Co(hfac) 2L] n . The specific steric bulkiness of the ferrocenyl substituent leads to the formation of trans-type coordination polyhedra in the [Mn(hfac) 2L] n and [Co(hfac) 2L] n chains. The introduction of the ferrocene substituent leads to an effective weakening of intermolecular or interchain magnetic exchange coupling. Ferrimagnetic ordering was observed for one-dimensional complexes [M(hfac) 2L] n (M = Mn(II), Co(II)). [Co(hfac) 2L] n exhibits features of single-chain magnet behaviour: slow relaxation of magnetization below 13 K is associated with a high coercive field (54 kOe at 2 K).

AB - By the reaction of M(hfac) 2 (M = Mn(II), Co(II), Cu(II), and Zn(II); hfac is the hexafluoroacetylacetonate anion) and ferrocenyl-substituted nitronyl nitroxide (L), we succeeded in the synthesis of stable heterospin complexes: mononuclear [Zn(hfac) 2L], trinuclear {[Cu(hfac) 2] 3L 2} and chain polymer [Mn(hfac) 2L] n and [Co(hfac) 2L] n . The specific steric bulkiness of the ferrocenyl substituent leads to the formation of trans-type coordination polyhedra in the [Mn(hfac) 2L] n and [Co(hfac) 2L] n chains. The introduction of the ferrocene substituent leads to an effective weakening of intermolecular or interchain magnetic exchange coupling. Ferrimagnetic ordering was observed for one-dimensional complexes [M(hfac) 2L] n (M = Mn(II), Co(II)). [Co(hfac) 2L] n exhibits features of single-chain magnet behaviour: slow relaxation of magnetization below 13 K is associated with a high coercive field (54 kOe at 2 K).

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85181830730&origin=inward&txGid=9193e3f3acaec97d310b6e59e57bdaa3

UR - https://www.mendeley.com/catalogue/fa0a4290-3d5c-35f0-af65-6ed9951d4cb9/

U2 - 10.1039/d3dt03858k

DO - 10.1039/d3dt03858k

M3 - Article

C2 - 38167942

VL - 53

SP - 1714

EP - 1721

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 4

ER -

ID: 59714415