Standard

Fast destruction of singlet order in NMR experiments. / Rodin, Bogdan A.; Sheberstov, Kirill F.; Kiryutin, Alexey S. et al.

In: Journal of Chemical Physics, Vol. 151, No. 23, 234203, 21.12.2019.

Research output: Contribution to journal › Article › peer-review

Harvard

Rodin, BA, Sheberstov, KF, Kiryutin, AS, Brown, LJ, Brown, RCD, Sabba, M, Levitt, MH, Yurkovskaya, AV & Ivanov, KL 2019, 'Fast destruction of singlet order in NMR experiments', Journal of Chemical Physics, vol. 151, no. 23, 234203. https://doi.org/10.1063/1.5131730

APA

Rodin, B. A., Sheberstov, K. F., Kiryutin, A. S., Brown, L. J., Brown, R. C. D., Sabba, M., Levitt, M. H., Yurkovskaya, A. V., & Ivanov, K. L. (2019). Fast destruction of singlet order in NMR experiments. Journal of Chemical Physics, 151(23), [234203]. https://doi.org/10.1063/1.5131730

Vancouver

Rodin BA, Sheberstov KF, Kiryutin AS, Brown LJ, Brown RCD, Sabba M et al. Fast destruction of singlet order in NMR experiments. Journal of Chemical Physics. 2019 Dec 21;151(23):234203. doi: 10.1063/1.5131730

Author

Rodin, Bogdan A. ; Sheberstov, Kirill F. ; Kiryutin, Alexey S. et al. / Fast destruction of singlet order in NMR experiments. In: Journal of Chemical Physics. 2019 ; Vol. 151, No. 23.

BibTeX

@article{c0002478c69b477d8ba524a17b156988,
title = "Fast destruction of singlet order in NMR experiments",
abstract = "Some nuclear spin systems support long-lived states, which display greatly extended relaxation times relative to the relaxation time of nuclear spin magnetization. In spin-1/2 pairs, such a long-lived state is given by singlet order, representing the difference of the population of the nuclear singlet state and the mean population of the three triplets. In many cases, the experiments with long-lived singlet order are very time-consuming because of the need to wait for singlet order decay before the experiment can be repeated; otherwise, spin order remaining from a previous measurement may lead to experimental artifacts. Here, we propose techniques for fast and efficient singlet order destruction. These methods exploit coherent singlet-triplet conversion; in some cases, multiple conversion steps are introduced. We demonstrate that singlet order destruction enables a dramatic reduction of the waiting time between consecutive experiments and suggest to use this approach in singlet-state Nuclear Magnetic Resonance (NMR) experiments with nearly equivalent spins.",
keywords = "LONG-LIVED STATES, NUCLEAR-SPIN STATES, DIFFUSION-COEFFICIENTS, SLOW DIFFUSION, POLARIZATION, SPECTROSCOPY, MOLECULES, CONTRAST, HYDROGEN, FIELD",
author = "Rodin, {Bogdan A.} and Sheberstov, {Kirill F.} and Kiryutin, {Alexey S.} and Brown, {Lynda J.} and Brown, {Richard C.D.} and Mohamed Sabba and Levitt, {Malcolm H.} and Yurkovskaya, {Alexandra V.} and Ivanov, {Konstantin L.}",
year = "2019",
month = dec,
day = "21",
doi = "10.1063/1.5131730",
language = "English",
volume = "151",
journal = "Journal of Chemical Physics",
issn = "0021-9606",
publisher = "American Institute of Physics",
number = "23",

}

RIS

TY - JOUR

T1 - Fast destruction of singlet order in NMR experiments

AU - Rodin, Bogdan A.

AU - Sheberstov, Kirill F.

AU - Kiryutin, Alexey S.

AU - Brown, Lynda J.

AU - Brown, Richard C.D.

AU - Sabba, Mohamed

AU - Levitt, Malcolm H.

AU - Yurkovskaya, Alexandra V.

AU - Ivanov, Konstantin L.

PY - 2019/12/21

Y1 - 2019/12/21

N2 - Some nuclear spin systems support long-lived states, which display greatly extended relaxation times relative to the relaxation time of nuclear spin magnetization. In spin-1/2 pairs, such a long-lived state is given by singlet order, representing the difference of the population of the nuclear singlet state and the mean population of the three triplets. In many cases, the experiments with long-lived singlet order are very time-consuming because of the need to wait for singlet order decay before the experiment can be repeated; otherwise, spin order remaining from a previous measurement may lead to experimental artifacts. Here, we propose techniques for fast and efficient singlet order destruction. These methods exploit coherent singlet-triplet conversion; in some cases, multiple conversion steps are introduced. We demonstrate that singlet order destruction enables a dramatic reduction of the waiting time between consecutive experiments and suggest to use this approach in singlet-state Nuclear Magnetic Resonance (NMR) experiments with nearly equivalent spins.

AB - Some nuclear spin systems support long-lived states, which display greatly extended relaxation times relative to the relaxation time of nuclear spin magnetization. In spin-1/2 pairs, such a long-lived state is given by singlet order, representing the difference of the population of the nuclear singlet state and the mean population of the three triplets. In many cases, the experiments with long-lived singlet order are very time-consuming because of the need to wait for singlet order decay before the experiment can be repeated; otherwise, spin order remaining from a previous measurement may lead to experimental artifacts. Here, we propose techniques for fast and efficient singlet order destruction. These methods exploit coherent singlet-triplet conversion; in some cases, multiple conversion steps are introduced. We demonstrate that singlet order destruction enables a dramatic reduction of the waiting time between consecutive experiments and suggest to use this approach in singlet-state Nuclear Magnetic Resonance (NMR) experiments with nearly equivalent spins.

KW - LONG-LIVED STATES

KW - NUCLEAR-SPIN STATES

KW - DIFFUSION-COEFFICIENTS

KW - SLOW DIFFUSION

KW - POLARIZATION

KW - SPECTROSCOPY

KW - MOLECULES

KW - CONTRAST

KW - HYDROGEN

KW - FIELD

UR - http://www.scopus.com/inward/record.url?scp=85077014413&partnerID=8YFLogxK

U2 - 10.1063/1.5131730

DO - 10.1063/1.5131730

M3 - Article

C2 - 31864263

AN - SCOPUS:85077014413

VL - 151

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

SN - 0021-9606

IS - 23

M1 - 234203

ER -

ID: 22992901