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Exploring the Frontiers of Heterometallic Systems: the {FeW5} Octahedral Cluster Complex. / Kozyreva, Anastasia I.; Yudin, Vasiliy N.; Gaifulin, Yakov M. et al.

In: Inorganic Chemistry, Vol. 63, No. 35, 02.09.2024, p. 16128-16133.

Research output: Contribution to journal › Article › peer-review

Harvard

Kozyreva, AI, Yudin, VN, Gaifulin, YM, Ivanov, AA, Yanshole, VV, Shestopalov, MA, Asanov, IP, Evtushok, VY & Evtushok, DV 2024, 'Exploring the Frontiers of Heterometallic Systems: the {FeW5} Octahedral Cluster Complex', Inorganic Chemistry, vol. 63, no. 35, pp. 16128-16133. https://doi.org/10.1021/acs.inorgchem.4c02594

APA

Kozyreva, A. I., Yudin, V. N., Gaifulin, Y. M., Ivanov, A. A., Yanshole, V. V., Shestopalov, M. A., Asanov, I. P., Evtushok, V. Y., & Evtushok, D. V. (2024). Exploring the Frontiers of Heterometallic Systems: the {FeW5} Octahedral Cluster Complex. Inorganic Chemistry, 63(35), 16128-16133. https://doi.org/10.1021/acs.inorgchem.4c02594

Vancouver

Kozyreva AI, Yudin VN, Gaifulin YM, Ivanov AA, Yanshole VV, Shestopalov MA et al. Exploring the Frontiers of Heterometallic Systems: the {FeW5} Octahedral Cluster Complex. Inorganic Chemistry. 2024 Sept 2;63(35):16128-16133. doi: 10.1021/acs.inorgchem.4c02594

Author

Kozyreva, Anastasia I. ; Yudin, Vasiliy N. ; Gaifulin, Yakov M. et al. / Exploring the Frontiers of Heterometallic Systems: the {FeW5} Octahedral Cluster Complex. In: Inorganic Chemistry. 2024 ; Vol. 63, No. 35. pp. 16128-16133.

BibTeX

@article{cb455db6fedf4886ab04d780498e6b2f,
title = "Exploring the Frontiers of Heterometallic Systems: the {FeW5} Octahedral Cluster Complex",
abstract = "This research presents the first examples of heterometallic octahedral cluster complexes incorporating both 5d and 3d metals, specifically, tungsten and iron. The key compound, (TBA)2[FeW5Br14] (TBA = tetrabutylammonium), exhibits selective ligand substitution reactions at the iron site when exposed to various solvents. Several {FeW5}-type anions, namely, [FeW5Br14]2-, [FeW5Br13(L)]− (L = H2O, DMSO, CH3CN), and [(FeW5Br13)2O]4-, were revealed and characterized by single-crystal X-ray diffraction analysis. The redox properties of [FeW5Br14]2- were studied and compared with those of [W6Br14]2-. Density functional theory calculations demonstrated that the bonding between Fe and W atoms is fundamentally different from the bonding between 4d (Mo-Mo) or 5d (W-W) metals in isotypic {M6} clusters.",
author = "Kozyreva, {Anastasia I.} and Yudin, {Vasiliy N.} and Gaifulin, {Yakov M.} and Ivanov, {Anton A.} and Yanshole, {Vadim V.} and Shestopalov, {Michael A.} and Asanov, {Igor P.} and Evtushok, {Vasilii Yu} and Evtushok, {Darya V.}",
note = "The authors gratefully acknowledge financial support from the Ministry of Science and Higher Education of the Russian Federation (Nos. 121031700321-2, 121031700321-3, and 121012290043-3). The authors thank the Collective Center of NIIC, SB RAS ( http://www.niic.nsc.ru/institute/tskp ). The authors thank the XRD Facility of NIIC, SB RAS, and personally thank L. V. Zargarova for the data collection. The authors thank A. D. Fedorenko for recording the XPS spectra.",
year = "2024",
month = sep,
day = "2",
doi = "10.1021/acs.inorgchem.4c02594",
language = "English",
volume = "63",
pages = "16128--16133",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "35",

}

RIS

TY - JOUR

T1 - Exploring the Frontiers of Heterometallic Systems: the {FeW5} Octahedral Cluster Complex

AU - Kozyreva, Anastasia I.

AU - Yudin, Vasiliy N.

AU - Gaifulin, Yakov M.

AU - Ivanov, Anton A.

AU - Yanshole, Vadim V.

AU - Shestopalov, Michael A.

AU - Asanov, Igor P.

AU - Evtushok, Vasilii Yu

AU - Evtushok, Darya V.

N1 - The authors gratefully acknowledge financial support from the Ministry of Science and Higher Education of the Russian Federation (Nos. 121031700321-2, 121031700321-3, and 121012290043-3). The authors thank the Collective Center of NIIC, SB RAS ( http://www.niic.nsc.ru/institute/tskp ). The authors thank the XRD Facility of NIIC, SB RAS, and personally thank L. V. Zargarova for the data collection. The authors thank A. D. Fedorenko for recording the XPS spectra.

PY - 2024/9/2

Y1 - 2024/9/2

N2 - This research presents the first examples of heterometallic octahedral cluster complexes incorporating both 5d and 3d metals, specifically, tungsten and iron. The key compound, (TBA)2[FeW5Br14] (TBA = tetrabutylammonium), exhibits selective ligand substitution reactions at the iron site when exposed to various solvents. Several {FeW5}-type anions, namely, [FeW5Br14]2-, [FeW5Br13(L)]− (L = H2O, DMSO, CH3CN), and [(FeW5Br13)2O]4-, were revealed and characterized by single-crystal X-ray diffraction analysis. The redox properties of [FeW5Br14]2- were studied and compared with those of [W6Br14]2-. Density functional theory calculations demonstrated that the bonding between Fe and W atoms is fundamentally different from the bonding between 4d (Mo-Mo) or 5d (W-W) metals in isotypic {M6} clusters.

AB - This research presents the first examples of heterometallic octahedral cluster complexes incorporating both 5d and 3d metals, specifically, tungsten and iron. The key compound, (TBA)2[FeW5Br14] (TBA = tetrabutylammonium), exhibits selective ligand substitution reactions at the iron site when exposed to various solvents. Several {FeW5}-type anions, namely, [FeW5Br14]2-, [FeW5Br13(L)]− (L = H2O, DMSO, CH3CN), and [(FeW5Br13)2O]4-, were revealed and characterized by single-crystal X-ray diffraction analysis. The redox properties of [FeW5Br14]2- were studied and compared with those of [W6Br14]2-. Density functional theory calculations demonstrated that the bonding between Fe and W atoms is fundamentally different from the bonding between 4d (Mo-Mo) or 5d (W-W) metals in isotypic {M6} clusters.

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85201864920&origin=inward&txGid=d7372ac9e38e74425e9bce2a163b36a3

UR - https://www.mendeley.com/catalogue/07eed313-e7e7-3c4f-a04c-5f7b51fbb5b8/

U2 - 10.1021/acs.inorgchem.4c02594

DO - 10.1021/acs.inorgchem.4c02594

M3 - Article

C2 - 39171697

VL - 63

SP - 16128

EP - 16133

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 35

ER -

ID: 60815094