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Exploration of structural, thermal and spectroscopic properties of self-activated sulfate Eu2(SO4)3 with isolated SO4 groups. / Denisenko, Yu G.; Aleksandrovsky, A. S.; Atuchin, V. V. et al.

In: Journal of Industrial and Engineering Chemistry, Vol. 68, 25.12.2018, p. 109-116.

Research output: Contribution to journal › Article › peer-review

Harvard

Denisenko, YG, Aleksandrovsky, AS, Atuchin, VV, Krylov, AS, Molokeev, MS, Oreshonkov, AS, Shestakov, NP & Andreev, OV 2018, 'Exploration of structural, thermal and spectroscopic properties of self-activated sulfate Eu2(SO4)3 with isolated SO4 groups', Journal of Industrial and Engineering Chemistry, vol. 68, pp. 109-116. https://doi.org/10.1016/j.jiec.2018.07.034

APA

Denisenko, Y. G., Aleksandrovsky, A. S., Atuchin, V. V., Krylov, A. S., Molokeev, M. S., Oreshonkov, A. S., Shestakov, N. P., & Andreev, O. V. (2018). Exploration of structural, thermal and spectroscopic properties of self-activated sulfate Eu2(SO4)3 with isolated SO4 groups. Journal of Industrial and Engineering Chemistry, 68, 109-116. https://doi.org/10.1016/j.jiec.2018.07.034

Vancouver

Denisenko YG, Aleksandrovsky AS, Atuchin VV, Krylov AS, Molokeev MS, Oreshonkov AS et al. Exploration of structural, thermal and spectroscopic properties of self-activated sulfate Eu2(SO4)3 with isolated SO4 groups. Journal of Industrial and Engineering Chemistry. 2018 Dec 25;68:109-116. doi: 10.1016/j.jiec.2018.07.034

Author

Denisenko, Yu G. ; Aleksandrovsky, A. S. ; Atuchin, V. V. et al. / Exploration of structural, thermal and spectroscopic properties of self-activated sulfate Eu2(SO4)3 with isolated SO4 groups. In: Journal of Industrial and Engineering Chemistry. 2018 ; Vol. 68. pp. 109-116.

BibTeX

@article{98ed522c7f1340eeb5e3ea485876ec99,
title = "Exploration of structural, thermal and spectroscopic properties of self-activated sulfate Eu2(SO4)3 with isolated SO4 groups",
abstract = "Eu2(SO4)3 was synthesized by chemical precipitation method and the crystal structure was determined by Rietveld analysis. The compound crystallizes in monoclinic space group С2/с. In the air environment, Eu2(SO4)3 is stable up to 670 °C. The sample of Eu2(SO4)3 was examined by Raman, Fourier-transform infrared absorption and luminescence spectroscopy methods. The low site symmetry of SO4 tetrahedra results in the appearance of the IR inactive ν1 mode around 1000 cm−1 and ν2 modes below 500 cm−1. The band intensities redistribution in the luminescent spectra of Eu3+ ions is analyzed in terms of the peculiarities of its local environment.",
keywords = "Europium sulfate, Photoluminescence, Structure, Synthesis, Thermal analysis, UP-CONVERSION, CRYSTAL-STRUCTURE, DECOMPOSITION, LUMINESCENCE PROPERTIES, EUROPIUM, NANOPARTICLES, X-RAY, RARE-EARTH-ELEMENTS, RED PHOSPHOR, CHEMICAL-SYNTHESIS",
author = "Denisenko, {Yu G.} and Aleksandrovsky, {A. S.} and Atuchin, {V. V.} and Krylov, {A. S.} and Molokeev, {M. S.} and Oreshonkov, {A. S.} and Shestakov, {N. P.} and Andreev, {O. V.}",
note = "Publisher Copyright: {\textcopyright} 2018 The Korean Society of Industrial and Engineering Chemistry",
year = "2018",
month = dec,
day = "25",
doi = "10.1016/j.jiec.2018.07.034",
language = "English",
volume = "68",
pages = "109--116",
journal = "Journal of Industrial and Engineering Chemistry",
issn = "1226-086X",
publisher = "Korean Society of Industrial Engineering Chemistry",

}

RIS

TY - JOUR

T1 - Exploration of structural, thermal and spectroscopic properties of self-activated sulfate Eu2(SO4)3 with isolated SO4 groups

AU - Denisenko, Yu G.

AU - Aleksandrovsky, A. S.

AU - Atuchin, V. V.

AU - Krylov, A. S.

AU - Molokeev, M. S.

AU - Oreshonkov, A. S.

AU - Shestakov, N. P.

AU - Andreev, O. V.

N1 - Publisher Copyright: © 2018 The Korean Society of Industrial and Engineering Chemistry

PY - 2018/12/25

Y1 - 2018/12/25

N2 - Eu2(SO4)3 was synthesized by chemical precipitation method and the crystal structure was determined by Rietveld analysis. The compound crystallizes in monoclinic space group С2/с. In the air environment, Eu2(SO4)3 is stable up to 670 °C. The sample of Eu2(SO4)3 was examined by Raman, Fourier-transform infrared absorption and luminescence spectroscopy methods. The low site symmetry of SO4 tetrahedra results in the appearance of the IR inactive ν1 mode around 1000 cm−1 and ν2 modes below 500 cm−1. The band intensities redistribution in the luminescent spectra of Eu3+ ions is analyzed in terms of the peculiarities of its local environment.

AB - Eu2(SO4)3 was synthesized by chemical precipitation method and the crystal structure was determined by Rietveld analysis. The compound crystallizes in monoclinic space group С2/с. In the air environment, Eu2(SO4)3 is stable up to 670 °C. The sample of Eu2(SO4)3 was examined by Raman, Fourier-transform infrared absorption and luminescence spectroscopy methods. The low site symmetry of SO4 tetrahedra results in the appearance of the IR inactive ν1 mode around 1000 cm−1 and ν2 modes below 500 cm−1. The band intensities redistribution in the luminescent spectra of Eu3+ ions is analyzed in terms of the peculiarities of its local environment.

KW - Europium sulfate

KW - Photoluminescence

KW - Structure

KW - Synthesis

KW - Thermal analysis

KW - UP-CONVERSION

KW - CRYSTAL-STRUCTURE

KW - DECOMPOSITION

KW - LUMINESCENCE PROPERTIES

KW - EUROPIUM

KW - NANOPARTICLES

KW - X-RAY

KW - RARE-EARTH-ELEMENTS

KW - RED PHOSPHOR

KW - CHEMICAL-SYNTHESIS

UR - http://www.scopus.com/inward/record.url?scp=85051668274&partnerID=8YFLogxK

U2 - 10.1016/j.jiec.2018.07.034

DO - 10.1016/j.jiec.2018.07.034

M3 - Article

AN - SCOPUS:85051668274

VL - 68

SP - 109

EP - 116

JO - Journal of Industrial and Engineering Chemistry

JF - Journal of Industrial and Engineering Chemistry

SN - 1226-086X

ER -

ID: 16083509