Research output: Contribution to journal › Article › peer-review
Experimental Studies and Mathematical Modeling of the Catalytic Conversion of Biodiesel Fuel to Synthesis Gas. / Shilov, V. a.; Zazhigalov, S. v.; Burmatova, M. a. et al.
In: Catalysis in Industry, Vol. 16, No. 4, 27.01.2025, p. 451-459.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Experimental Studies and Mathematical Modeling of the Catalytic Conversion of Biodiesel Fuel to Synthesis Gas
AU - Shilov, V. a.
AU - Zazhigalov, S. v.
AU - Burmatova, M. a.
AU - Zagoruiko, A. n.
AU - Snytnikov, P. v.
N1 - This work was supported by the Russian Science Foundation (project no. 19-19-00257, https://rscf.ru/project/19-19-00257).
PY - 2025/1/27
Y1 - 2025/1/27
N2 - The steam reforming and autothermal reforming of methyl oleate (model compound simulating biodiesel fuel) to synthesis gas in the presence of a structured Rh-containing catalyst have been studied. It has been shown that methyl oleate conversion occurs through a thermal cracking stage and the subsequent conversion of the resulting organic compounds with a shorter carbon skeleton. Based on test results, a mathematical model that takes into account the radial temperature gradient and represents an effective tool for the quantitative description and optimization of the biodiesel conversion process has been developed.
AB - The steam reforming and autothermal reforming of methyl oleate (model compound simulating biodiesel fuel) to synthesis gas in the presence of a structured Rh-containing catalyst have been studied. It has been shown that methyl oleate conversion occurs through a thermal cracking stage and the subsequent conversion of the resulting organic compounds with a shorter carbon skeleton. Based on test results, a mathematical model that takes into account the radial temperature gradient and represents an effective tool for the quantitative description and optimization of the biodiesel conversion process has been developed.
UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85217669177&origin=inward&txGid=b93102381984549aba4701cc87978755
U2 - 10.1134/S2070050424700296
DO - 10.1134/S2070050424700296
M3 - Article
VL - 16
SP - 451
EP - 459
JO - Catalysis in Industry
JF - Catalysis in Industry
SN - 2070-0504
IS - 4
ER -
ID: 64794510