Standard

Eu-Doped layered yttrium hydroxides sensitized by a series of benzenedicarboxylate and sulphobenzoate anions. / Yapryntsev, Alexey; Abdusatorov, Bakhodur; Yakushev, Ilya et al.

In: Dalton Transactions, Vol. 48, No. 18, 2019, p. 6111-6122.

Research output: Contribution to journalArticlepeer-review

Harvard

Yapryntsev, A, Abdusatorov, B, Yakushev, I, Svetogorov, R, Gavrikov, A, Rodina, A, Fatyushina, Y, Baranchikov, A, Zubavichus, Y & Ivanov, V 2019, 'Eu-Doped layered yttrium hydroxides sensitized by a series of benzenedicarboxylate and sulphobenzoate anions', Dalton Transactions, vol. 48, no. 18, pp. 6111-6122. https://doi.org/10.1039/c9dt00390h

APA

Yapryntsev, A., Abdusatorov, B., Yakushev, I., Svetogorov, R., Gavrikov, A., Rodina, A., Fatyushina, Y., Baranchikov, A., Zubavichus, Y., & Ivanov, V. (2019). Eu-Doped layered yttrium hydroxides sensitized by a series of benzenedicarboxylate and sulphobenzoate anions. Dalton Transactions, 48(18), 6111-6122. https://doi.org/10.1039/c9dt00390h

Vancouver

Yapryntsev A, Abdusatorov B, Yakushev I, Svetogorov R, Gavrikov A, Rodina A et al. Eu-Doped layered yttrium hydroxides sensitized by a series of benzenedicarboxylate and sulphobenzoate anions. Dalton Transactions. 2019;48(18):6111-6122. doi: 10.1039/c9dt00390h

Author

Yapryntsev, Alexey ; Abdusatorov, Bakhodur ; Yakushev, Ilya et al. / Eu-Doped layered yttrium hydroxides sensitized by a series of benzenedicarboxylate and sulphobenzoate anions. In: Dalton Transactions. 2019 ; Vol. 48, No. 18. pp. 6111-6122.

BibTeX

@article{b9df98706d6c4d6eb866899cfb2c7a34,
title = "Eu-Doped layered yttrium hydroxides sensitized by a series of benzenedicarboxylate and sulphobenzoate anions",
abstract = "A number of Eu-doped layered yttrium hydroxides intercalated with various benzenedicarboxylate (phthalate, isophthalate and terephthalate) and sulphobenzoate (2-, 3- and 4-sulphobenzoate) anions were obtained using hydrothermal microwave (HTMW) treatment. For the first time, phthalate, isophthalate and sulphobenzoate anions were intercalated into layered rare-earth hydroxides (LRHs). Two approaches for the synthesis of intercalated layered yttrium hydroxides were used: ion exchange reactions and homogeneous hydrolysis of rare-earth cations in the presence of intercalated anions. Ion-exchange reactions between layered rare-earth hydroxides and a series of benzenedicarboxylic and sulphobenzoic acid salts were performed under the conditions of HTMW treatment, which significantly increased the rate of intercalation. The structure of the first representative of layered rare-earth hydroxides intercalated with sulphobenzoate-type anions, namely layered yttrium hydroxide intercalated with 4-sulphobenzoate of the composition Y3(OH)7(C7H4O5S)·H2O, was solved. Intercalation of benzenedicarboxylate and sulphobenzoate anions into Eu-doped layered yttrium hydroxides led to a substantial sensitization of Eu3+ luminescence. The local symmetry of Eu3+ was greatly decreased by intercalation of benzenedicarboxylate and sulphobenzoate anions.",
keywords = "RARE-EARTH HYDROXIDES, ENHANCED LUMINESCENCE, HYDROTHERMAL SYNTHESIS, EUROPIUM HYDROXIDE, EXCHANGE REACTIONS, CRYSTAL-STRUCTURE, WHITE-LIGHT, PHOTOLUMINESCENCE, INTERCALATION, FAMILY",
author = "Alexey Yapryntsev and Bakhodur Abdusatorov and Ilya Yakushev and Roman Svetogorov and Andrey Gavrikov and Anfisa Rodina and Yelena Fatyushina and Alexander Baranchikov and Yan Zubavichus and Vladimir Ivanov",
year = "2019",
doi = "10.1039/c9dt00390h",
language = "English",
volume = "48",
pages = "6111--6122",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "18",

}

RIS

TY - JOUR

T1 - Eu-Doped layered yttrium hydroxides sensitized by a series of benzenedicarboxylate and sulphobenzoate anions

AU - Yapryntsev, Alexey

AU - Abdusatorov, Bakhodur

AU - Yakushev, Ilya

AU - Svetogorov, Roman

AU - Gavrikov, Andrey

AU - Rodina, Anfisa

AU - Fatyushina, Yelena

AU - Baranchikov, Alexander

AU - Zubavichus, Yan

AU - Ivanov, Vladimir

PY - 2019

Y1 - 2019

N2 - A number of Eu-doped layered yttrium hydroxides intercalated with various benzenedicarboxylate (phthalate, isophthalate and terephthalate) and sulphobenzoate (2-, 3- and 4-sulphobenzoate) anions were obtained using hydrothermal microwave (HTMW) treatment. For the first time, phthalate, isophthalate and sulphobenzoate anions were intercalated into layered rare-earth hydroxides (LRHs). Two approaches for the synthesis of intercalated layered yttrium hydroxides were used: ion exchange reactions and homogeneous hydrolysis of rare-earth cations in the presence of intercalated anions. Ion-exchange reactions between layered rare-earth hydroxides and a series of benzenedicarboxylic and sulphobenzoic acid salts were performed under the conditions of HTMW treatment, which significantly increased the rate of intercalation. The structure of the first representative of layered rare-earth hydroxides intercalated with sulphobenzoate-type anions, namely layered yttrium hydroxide intercalated with 4-sulphobenzoate of the composition Y3(OH)7(C7H4O5S)·H2O, was solved. Intercalation of benzenedicarboxylate and sulphobenzoate anions into Eu-doped layered yttrium hydroxides led to a substantial sensitization of Eu3+ luminescence. The local symmetry of Eu3+ was greatly decreased by intercalation of benzenedicarboxylate and sulphobenzoate anions.

AB - A number of Eu-doped layered yttrium hydroxides intercalated with various benzenedicarboxylate (phthalate, isophthalate and terephthalate) and sulphobenzoate (2-, 3- and 4-sulphobenzoate) anions were obtained using hydrothermal microwave (HTMW) treatment. For the first time, phthalate, isophthalate and sulphobenzoate anions were intercalated into layered rare-earth hydroxides (LRHs). Two approaches for the synthesis of intercalated layered yttrium hydroxides were used: ion exchange reactions and homogeneous hydrolysis of rare-earth cations in the presence of intercalated anions. Ion-exchange reactions between layered rare-earth hydroxides and a series of benzenedicarboxylic and sulphobenzoic acid salts were performed under the conditions of HTMW treatment, which significantly increased the rate of intercalation. The structure of the first representative of layered rare-earth hydroxides intercalated with sulphobenzoate-type anions, namely layered yttrium hydroxide intercalated with 4-sulphobenzoate of the composition Y3(OH)7(C7H4O5S)·H2O, was solved. Intercalation of benzenedicarboxylate and sulphobenzoate anions into Eu-doped layered yttrium hydroxides led to a substantial sensitization of Eu3+ luminescence. The local symmetry of Eu3+ was greatly decreased by intercalation of benzenedicarboxylate and sulphobenzoate anions.

KW - RARE-EARTH HYDROXIDES

KW - ENHANCED LUMINESCENCE

KW - HYDROTHERMAL SYNTHESIS

KW - EUROPIUM HYDROXIDE

KW - EXCHANGE REACTIONS

KW - CRYSTAL-STRUCTURE

KW - WHITE-LIGHT

KW - PHOTOLUMINESCENCE

KW - INTERCALATION

KW - FAMILY

UR - http://www.scopus.com/inward/record.url?scp=85065524843&partnerID=8YFLogxK

U2 - 10.1039/c9dt00390h

DO - 10.1039/c9dt00390h

M3 - Article

C2 - 30821305

AN - SCOPUS:85065524843

VL - 48

SP - 6111

EP - 6122

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 18

ER -

ID: 25465026