Estimation of electrical properties of composite solid electrolytes of different morphologies

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Estimation of electrical properties of composite solid electrolytes of different morphologies. / Uvarov, Nikolai F.

In: Solid State Ionics, Vol. 302, 01.04.2017, p. 19-24.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{efa5ca5dcc924878992b1d64f4ddc05a,

title = "Estimation of electrical properties of composite solid electrolytes of different morphologies",

abstract = "A generalized mixing rule was applied to calculation of electric properties (conductivity and dielectric permittivity) as a function of concentration and ac frequency for composites of different morphologies. Morphologies of three types were considered: (i) statistical mixture of ionic salt MX and oxide A with the same grains size of the components; (ii) composites in which A phase spreads along grain boundaries of MX and (iii) composites formed by filling the porous matrix of A with the ionic salt MX. Theoretical dependences were analyzed and compared to experimental results obtained earlier by authors or taken from the literature.",

keywords = "Mixing rules, Conductivity, Composite solid electrolytes, DISPERSED IONIC CONDUCTORS, PERCOLATION MODEL, AGI-AL2O3 COMPOSITES, CONDUCTIVITY, INTERFACE, TRANSPORT, PARTICLES, CONSTANTS, INSULATOR, IODIDE",

author = "Uvarov, {Nikolai F.}",

year = "2017",

month = apr,

day = "1",

doi = "10.1016/j.ssi.2016.11.021",

language = "English",

volume = "302",

pages = "19--24",

journal = "Solid State Ionics",

issn = "0167-2738",

publisher = "Elsevier Science B.V.",

note = "12th International Symposium on Systems with Fast Ionic Transport (ISSFIT) ; Conference date: 03-07-2016 Through 07-07-2016",

}

RIS

TY - JOUR

T1 - Estimation of electrical properties of composite solid electrolytes of different morphologies

AU - Uvarov, Nikolai F.

PY - 2017/4/1

Y1 - 2017/4/1

N2 - A generalized mixing rule was applied to calculation of electric properties (conductivity and dielectric permittivity) as a function of concentration and ac frequency for composites of different morphologies. Morphologies of three types were considered: (i) statistical mixture of ionic salt MX and oxide A with the same grains size of the components; (ii) composites in which A phase spreads along grain boundaries of MX and (iii) composites formed by filling the porous matrix of A with the ionic salt MX. Theoretical dependences were analyzed and compared to experimental results obtained earlier by authors or taken from the literature.

AB - A generalized mixing rule was applied to calculation of electric properties (conductivity and dielectric permittivity) as a function of concentration and ac frequency for composites of different morphologies. Morphologies of three types were considered: (i) statistical mixture of ionic salt MX and oxide A with the same grains size of the components; (ii) composites in which A phase spreads along grain boundaries of MX and (iii) composites formed by filling the porous matrix of A with the ionic salt MX. Theoretical dependences were analyzed and compared to experimental results obtained earlier by authors or taken from the literature.

KW - Mixing rules

KW - Conductivity

KW - Composite solid electrolytes

KW - DISPERSED IONIC CONDUCTORS

KW - PERCOLATION MODEL

KW - AGI-AL2O3 COMPOSITES

KW - CONDUCTIVITY

KW - INTERFACE

KW - TRANSPORT

KW - PARTICLES

KW - CONSTANTS

KW - INSULATOR

KW - IODIDE

UR - http://www.scopus.com/inward/record.url?scp=85007339400&partnerID=8YFLogxK

U2 - 10.1016/j.ssi.2016.11.021

DO - 10.1016/j.ssi.2016.11.021

M3 - Article

VL - 302

SP - 19

EP - 24

JO - Solid State Ionics

JF - Solid State Ionics

SN - 0167-2738

T2 - 12th International Symposium on Systems with Fast Ionic Transport (ISSFIT)

Y2 - 3 July 2016 through 7 July 2016

ER -

ID: 18735819