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Effects arising from the replacement of aprotic dipolar solvents with ionic liquids in the nickel-catalyzed reduction of aryl chlorides. / Prikhod'ko, S. A.; Popov, A. G.; Adonin, N. Yu.

In: Molecular Catalysis, Vol. 461, 01.12.2018, p. 19-25.

Research output: Contribution to journal › Article › peer-review

Harvard

Prikhod'ko, SA, Popov, AG & Adonin, NY 2018, 'Effects arising from the replacement of aprotic dipolar solvents with ionic liquids in the nickel-catalyzed reduction of aryl chlorides', Molecular Catalysis, vol. 461, pp. 19-25. https://doi.org/10.1016/j.mcat.2018.09.022

APA

Prikhod'ko, S. A., Popov, A. G., & Adonin, N. Y. (2018). Effects arising from the replacement of aprotic dipolar solvents with ionic liquids in the nickel-catalyzed reduction of aryl chlorides. Molecular Catalysis, 461, 19-25. https://doi.org/10.1016/j.mcat.2018.09.022

Vancouver

Prikhod'ko SA, Popov AG, Adonin NY. Effects arising from the replacement of aprotic dipolar solvents with ionic liquids in the nickel-catalyzed reduction of aryl chlorides. Molecular Catalysis. 2018 Dec 1;461:19-25. doi: 10.1016/j.mcat.2018.09.022

Author

Prikhod'ko, S. A. ; Popov, A. G. ; Adonin, N. Yu. / Effects arising from the replacement of aprotic dipolar solvents with ionic liquids in the nickel-catalyzed reduction of aryl chlorides. In: Molecular Catalysis. 2018 ; Vol. 461. pp. 19-25.

BibTeX

@article{70b0290c946d4b719f7fe143ea93aa97,
title = "Effects arising from the replacement of aprotic dipolar solvents with ionic liquids in the nickel-catalyzed reduction of aryl chlorides",
abstract = "In the work on the example of liquid-phase catalytic processes of the aromatic C–Cl bonds activation occurring in the presence of nickel complexes under reducing conditions the main effects arising from the replacement of aprotic dipolar solvents with ionic liquids are analyzed. The features of the nickel-catalyzed reaction of aryl chlorides, related to the nature of the anion and cation of the ionic liquid, were observed. It was shown that a high concentration of cations and anions in the ionic liquid affects the process of reduction of the nickel complex to the catalytically active state. In addition, the presence of a reactive hydrogen atom in the imidazolium cation of ionic liquid causes the process of hydrodechlorination of aryl chlorides.",
keywords = "Aryl chlorides, Homocoupling, Hydrodehalogenation, Ionic liquid, Nickel complexes, Zinc",
author = "Prikhod'ko, {S. A.} and Popov, {A. G.} and Adonin, {N. Yu}",
year = "2018",
month = dec,
day = "1",
doi = "10.1016/j.mcat.2018.09.022",
language = "English",
volume = "461",
pages = "19--25",
journal = "Molecular Catalysis",
issn = "2468-8231",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Effects arising from the replacement of aprotic dipolar solvents with ionic liquids in the nickel-catalyzed reduction of aryl chlorides

AU - Prikhod'ko, S. A.

AU - Popov, A. G.

AU - Adonin, N. Yu

PY - 2018/12/1

Y1 - 2018/12/1

N2 - In the work on the example of liquid-phase catalytic processes of the aromatic C–Cl bonds activation occurring in the presence of nickel complexes under reducing conditions the main effects arising from the replacement of aprotic dipolar solvents with ionic liquids are analyzed. The features of the nickel-catalyzed reaction of aryl chlorides, related to the nature of the anion and cation of the ionic liquid, were observed. It was shown that a high concentration of cations and anions in the ionic liquid affects the process of reduction of the nickel complex to the catalytically active state. In addition, the presence of a reactive hydrogen atom in the imidazolium cation of ionic liquid causes the process of hydrodechlorination of aryl chlorides.

AB - In the work on the example of liquid-phase catalytic processes of the aromatic C–Cl bonds activation occurring in the presence of nickel complexes under reducing conditions the main effects arising from the replacement of aprotic dipolar solvents with ionic liquids are analyzed. The features of the nickel-catalyzed reaction of aryl chlorides, related to the nature of the anion and cation of the ionic liquid, were observed. It was shown that a high concentration of cations and anions in the ionic liquid affects the process of reduction of the nickel complex to the catalytically active state. In addition, the presence of a reactive hydrogen atom in the imidazolium cation of ionic liquid causes the process of hydrodechlorination of aryl chlorides.

KW - Aryl chlorides

KW - Homocoupling

KW - Hydrodehalogenation

KW - Ionic liquid

KW - Nickel complexes

KW - Zinc

UR - http://www.scopus.com/inward/record.url?scp=85054458060&partnerID=8YFLogxK

U2 - 10.1016/j.mcat.2018.09.022

DO - 10.1016/j.mcat.2018.09.022

M3 - Article

AN - SCOPUS:85054458060

VL - 461

SP - 19

EP - 25

JO - Molecular Catalysis

JF - Molecular Catalysis

SN - 2468-8231

ER -

ID: 17039159