Research output: Contribution to journal › Article › peer-review
Effect of increasing pressure on the structure and temperature-induced changes in magnetic properties of heterospin complexes. / Romanenko, G. V.; Letyagin, G. A.; Maryunina, K. Yu et al.
In: Russian Chemical Bulletin, Vol. 69, No. 8, 01.08.2020, p. 1530-1536.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Effect of increasing pressure on the structure and temperature-induced changes in magnetic properties of heterospin complexes
AU - Romanenko, G. V.
AU - Letyagin, G. A.
AU - Maryunina, K. Yu
AU - Bogomyakov, A. S.
AU - Nishihara, S.
AU - Inoue, K.
AU - Ovcharenko, V. I.
PY - 2020/8/1
Y1 - 2020/8/1
N2 - The study is concerned with structural rearrangements in the crystals of heterospin complexes Cu(hfac)2 with nitroxide radicals LR (hfac is hexafluoroacetylacetonate, LR is 2-(1-R-1H-pyrazol-4-yl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-3-oxide-1-oxyl, R is Et or Allyl) induced by increasing pressure from 10−4 to ∼1 GPa in the pressure-transmitting medium. An increase in the external pressure to only ∼0.03 GPa leads to the disappearance of the temperature-induced magnetic anomaly observed for these heterospin crystals under ambient conditions.
AB - The study is concerned with structural rearrangements in the crystals of heterospin complexes Cu(hfac)2 with nitroxide radicals LR (hfac is hexafluoroacetylacetonate, LR is 2-(1-R-1H-pyrazol-4-yl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-3-oxide-1-oxyl, R is Et or Allyl) induced by increasing pressure from 10−4 to ∼1 GPa in the pressure-transmitting medium. An increase in the external pressure to only ∼0.03 GPa leads to the disappearance of the temperature-induced magnetic anomaly observed for these heterospin crystals under ambient conditions.
KW - copper
KW - crystal structure
KW - hexafluoroacetylacetonate
KW - magnetic properties
KW - nitronyl nitroxide radicals
KW - pressure
KW - CELL
UR - http://www.scopus.com/inward/record.url?scp=85091164948&partnerID=8YFLogxK
U2 - 10.1007/s11172-020-2932-2
DO - 10.1007/s11172-020-2932-2
M3 - Article
AN - SCOPUS:85091164948
VL - 69
SP - 1530
EP - 1536
JO - Russian Chemical Bulletin
JF - Russian Chemical Bulletin
SN - 1066-5285
IS - 8
ER -
ID: 25313003