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Effect of a Method for Introducing Palladium into Al2O3 Granules on Catalytic Properties and Activity in the Reaction of Deep Oxidation of Methane. / Shikina, N.; Rudina, N. A.; Boronin, A. et al.

In: Chemistry for Sustainable Development, Vol. 26, No. 6, 2018, p. 693-703.

Research output: Contribution to journal › Article › peer-review

Harvard

Shikina, N, Rudina, NA, Boronin, A, Yashnik, SA, Moroz, AA, Surovoy, EP & Ismagilov, ZR 2018, 'Effect of a Method for Introducing Palladium into Al2O3 Granules on Catalytic Properties and Activity in the Reaction of Deep Oxidation of Methane', Chemistry for Sustainable Development, vol. 26, no. 6, pp. 693-703. https://doi.org/10.15372/CSD820180616

APA

Shikina, N., Rudina, N. A., Boronin, A., Yashnik, S. A., Moroz, A. A., Surovoy, E. P., & Ismagilov, Z. R. (2018). Effect of a Method for Introducing Palladium into Al2O3 Granules on Catalytic Properties and Activity in the Reaction of Deep Oxidation of Methane. Chemistry for Sustainable Development, 26(6), 693-703. https://doi.org/10.15372/CSD820180616

Vancouver

Shikina N, Rudina NA, Boronin A, Yashnik SA, Moroz AA, Surovoy EP et al. Effect of a Method for Introducing Palladium into Al2O3 Granules on Catalytic Properties and Activity in the Reaction of Deep Oxidation of Methane. Chemistry for Sustainable Development. 2018;26(6):693-703. doi: 10.15372/CSD820180616

Author

Shikina, N. ; Rudina, N. A. ; Boronin, A. et al. / Effect of a Method for Introducing Palladium into Al2O3 Granules on Catalytic Properties and Activity in the Reaction of Deep Oxidation of Methane. In: Chemistry for Sustainable Development. 2018 ; Vol. 26, No. 6. pp. 693-703.

BibTeX

@article{668778048e4a406e9603a782173390ef,
title = "Effect of a Method for Introducing Palladium into Al2O3 Granules on Catalytic Properties and Activity in the Reaction of Deep Oxidation of Methane",
abstract = "The effect of techniques for introducing Pd into gamma-Al2O3 from palladium chloride solutions on physicochemical and catalytic properties of PdO(Pd)/Al2O3 catalysts was examined. A series of catalysts were investigated by SEM, XPA, BET, XPS, and H-2-TPR. As shown, the use of various methods for introducing Pd into alumina granules enables control of active component distribution along the Al2O3 granule section. The localization of Pd in a catalyst grain determines the nature of the reduction in H 2-TPR and activity in the reaction of deep oxidation of methane, which is connected with a varying degree of the interaction of the active component with the support. The active component is demonstrated to be formed on the granule surface mainly as PdO when using the adsorption-deposition method followed by calcination at a temperature of 1000 degrees C ensuring high reactivity in the methane oxidation reaction.",
keywords = "Pd catalysts, sol-gel, impregnation, adsorption, deposition, methane oxidation",
author = "N. Shikina and Rudina, {N. A.} and A. Boronin and Yashnik, {S. A.} and Moroz, {A. A.} and Surovoy, {E. P.} and Ismagilov, {Z. R.}",
year = "2018",
doi = "10.15372/CSD820180616",
language = "English",
volume = "26",
pages = "693--703",
journal = "Chemistry for Sustainable Development",
issn = "1817-1818",
publisher = "ФГУП {"}Издательство СО РАН{"}",
number = "6",

}

RIS

TY - JOUR

T1 - Effect of a Method for Introducing Palladium into Al2O3 Granules on Catalytic Properties and Activity in the Reaction of Deep Oxidation of Methane

AU - Shikina, N.

AU - Rudina, N. A.

AU - Boronin, A.

AU - Yashnik, S. A.

AU - Moroz, A. A.

AU - Surovoy, E. P.

AU - Ismagilov, Z. R.

PY - 2018

Y1 - 2018

N2 - The effect of techniques for introducing Pd into gamma-Al2O3 from palladium chloride solutions on physicochemical and catalytic properties of PdO(Pd)/Al2O3 catalysts was examined. A series of catalysts were investigated by SEM, XPA, BET, XPS, and H-2-TPR. As shown, the use of various methods for introducing Pd into alumina granules enables control of active component distribution along the Al2O3 granule section. The localization of Pd in a catalyst grain determines the nature of the reduction in H 2-TPR and activity in the reaction of deep oxidation of methane, which is connected with a varying degree of the interaction of the active component with the support. The active component is demonstrated to be formed on the granule surface mainly as PdO when using the adsorption-deposition method followed by calcination at a temperature of 1000 degrees C ensuring high reactivity in the methane oxidation reaction.

AB - The effect of techniques for introducing Pd into gamma-Al2O3 from palladium chloride solutions on physicochemical and catalytic properties of PdO(Pd)/Al2O3 catalysts was examined. A series of catalysts were investigated by SEM, XPA, BET, XPS, and H-2-TPR. As shown, the use of various methods for introducing Pd into alumina granules enables control of active component distribution along the Al2O3 granule section. The localization of Pd in a catalyst grain determines the nature of the reduction in H 2-TPR and activity in the reaction of deep oxidation of methane, which is connected with a varying degree of the interaction of the active component with the support. The active component is demonstrated to be formed on the granule surface mainly as PdO when using the adsorption-deposition method followed by calcination at a temperature of 1000 degrees C ensuring high reactivity in the methane oxidation reaction.

KW - Pd catalysts

KW - sol-gel

KW - impregnation

KW - adsorption

KW - deposition

KW - methane oxidation

UR - https://www.elibrary.ru/item.asp?id=42621076

U2 - 10.15372/CSD820180616

DO - 10.15372/CSD820180616

M3 - Article

VL - 26

SP - 693

EP - 703

JO - Chemistry for Sustainable Development

JF - Chemistry for Sustainable Development

SN - 1817-1818

IS - 6

ER -

ID: 25417658