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Easy ligand activation in the coordination sphere of Ru inside the [PW11O39]7– backbone. / Mukhacheva, Anna A.; Gushchin, Artem L.; Yanshole, Vadim V. et al.

In: Molecules, Vol. 25, No. 8, 1859, 17.04.2020.

Research output: Contribution to journal › Article › peer-review

Harvard

Mukhacheva, AA, Gushchin, AL, Yanshole, VV, Abramov, PA & Sokolov, MN 2020, 'Easy ligand activation in the coordination sphere of Ru inside the [PW11O39]7– backbone', Molecules, vol. 25, no. 8, 1859. https://doi.org/10.3390/molecules25081859

APA

Mukhacheva, A. A., Gushchin, A. L., Yanshole, V. V., Abramov, P. A., & Sokolov, M. N. (2020). Easy ligand activation in the coordination sphere of Ru inside the [PW11O39]7– backbone. Molecules, 25(8), [1859]. https://doi.org/10.3390/molecules25081859

Vancouver

Mukhacheva AA, Gushchin AL, Yanshole VV, Abramov PA, Sokolov MN. Easy ligand activation in the coordination sphere of Ru inside the [PW11O39]7– backbone. Molecules. 2020 Apr 17;25(8):1859. doi: 10.3390/molecules25081859

Author

Mukhacheva, Anna A. ; Gushchin, Artem L. ; Yanshole, Vadim V. et al. / Easy ligand activation in the coordination sphere of Ru inside the [PW11O39]7– backbone. In: Molecules. 2020 ; Vol. 25, No. 8.

BibTeX

@article{ae3902a4f3dd4626823ced26e70e4cd3,
title = "Easy ligand activation in the coordination sphere of Ru inside the [PW11O39]7– backbone",
abstract = "Irradiation of the Keggin-type [PW11O39{Ru(NO)}]4– (Ru-NO) polyoxometalate in CH3CN results in rapid NO ligand elimination with the formation of [PW11O39{RuIII(CH3CN)}]4– (RuCH3CN). This complex offers an easy entry into the Ru-based chemistry of the {PW11Ru} complex. Attempts to substitute N3– for CH3CN in the presence of an NaN3 excess lead a variety of products: (i) [PW11O39{RuIII(N3)}]4– (Ru-N3); (ii) [PW11O39{RuIII(N4HC-CH3)}]4– (Ru-Tz) as a click-reaction product; and (iii) [PW11O39{RuII(N2)}]5– (Ru-N2). UV-VIS, CV, and HR-ESI-MS techniques were used for the reaction monitoring and characterization of the products.",
keywords = "Azide, CV, HR-ESI-MS, Polyoxometalate, Ruthenium, KEGGIN STRUCTURE, REACTIVITY, STRUCTURAL-CHARACTERIZATION, RUTHENIUM, NOBLE-METALS, AQUEOUS-SOLUTION, ruthenium, CYCLOADDITION, ELECTROCHEMICAL-BEHAVIOR, CATALYTIC-ACTIVITY, CARBON-DIOXIDE, azide, polyoxometalate",
author = "Mukhacheva, {Anna A.} and Gushchin, {Artem L.} and Yanshole, {Vadim V.} and Abramov, {Pavel A.} and Sokolov, {Maksim N.}",
year = "2020",
month = apr,
day = "17",
doi = "10.3390/molecules25081859",
language = "English",
volume = "25",
journal = "Molecules",
issn = "1420-3049",
publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",
number = "8",

}

RIS

TY - JOUR

T1 - Easy ligand activation in the coordination sphere of Ru inside the [PW11O39]7– backbone

AU - Mukhacheva, Anna A.

AU - Gushchin, Artem L.

AU - Yanshole, Vadim V.

AU - Abramov, Pavel A.

AU - Sokolov, Maksim N.

PY - 2020/4/17

Y1 - 2020/4/17

N2 - Irradiation of the Keggin-type [PW11O39{Ru(NO)}]4– (Ru-NO) polyoxometalate in CH3CN results in rapid NO ligand elimination with the formation of [PW11O39{RuIII(CH3CN)}]4– (RuCH3CN). This complex offers an easy entry into the Ru-based chemistry of the {PW11Ru} complex. Attempts to substitute N3– for CH3CN in the presence of an NaN3 excess lead a variety of products: (i) [PW11O39{RuIII(N3)}]4– (Ru-N3); (ii) [PW11O39{RuIII(N4HC-CH3)}]4– (Ru-Tz) as a click-reaction product; and (iii) [PW11O39{RuII(N2)}]5– (Ru-N2). UV-VIS, CV, and HR-ESI-MS techniques were used for the reaction monitoring and characterization of the products.

AB - Irradiation of the Keggin-type [PW11O39{Ru(NO)}]4– (Ru-NO) polyoxometalate in CH3CN results in rapid NO ligand elimination with the formation of [PW11O39{RuIII(CH3CN)}]4– (RuCH3CN). This complex offers an easy entry into the Ru-based chemistry of the {PW11Ru} complex. Attempts to substitute N3– for CH3CN in the presence of an NaN3 excess lead a variety of products: (i) [PW11O39{RuIII(N3)}]4– (Ru-N3); (ii) [PW11O39{RuIII(N4HC-CH3)}]4– (Ru-Tz) as a click-reaction product; and (iii) [PW11O39{RuII(N2)}]5– (Ru-N2). UV-VIS, CV, and HR-ESI-MS techniques were used for the reaction monitoring and characterization of the products.

KW - Azide

KW - CV

KW - HR-ESI-MS

KW - Polyoxometalate

KW - Ruthenium

KW - KEGGIN STRUCTURE

KW - REACTIVITY

KW - STRUCTURAL-CHARACTERIZATION

KW - RUTHENIUM

KW - NOBLE-METALS

KW - AQUEOUS-SOLUTION

KW - ruthenium

KW - CYCLOADDITION

KW - ELECTROCHEMICAL-BEHAVIOR

KW - CATALYTIC-ACTIVITY

KW - CARBON-DIOXIDE

KW - azide

KW - polyoxometalate

UR - http://www.scopus.com/inward/record.url?scp=85083589406&partnerID=8YFLogxK

U2 - 10.3390/molecules25081859

DO - 10.3390/molecules25081859

M3 - Article

C2 - 32316614

AN - SCOPUS:85083589406

VL - 25

JO - Molecules

JF - Molecules

SN - 1420-3049

IS - 8

M1 - 1859

ER -

ID: 24068228