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Diverse Hydrogen-Bonded Structural Motifs in 1,4-Diazabicyclo[2.2.2]octane N,N’-Dioxide Salts with Oxoanions. / Abasheeva, Ksenia D.; Demakov, Pavel A.; Fedin, Vladimir P.

In: MolBank, Vol. 2022, No. 4, M1508, 01.12.2022.

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@article{e4527bfe381445d4bc815bf10d01bfa4,
title = "Diverse Hydrogen-Bonded Structural Motifs in 1,4-Diazabicyclo[2.2.2]octane N,N{\textquoteright}-Dioxide Salts with Oxoanions",
abstract = "Four new hybrid inorganic–organic salts of 1,4-diazabicyclo[2.2.2]octane N,N{\textquoteright}-dioxide (odabco) with the formulae odabco·2HNO3 (1), odabco·HClO4 (2), odabco·H2SO4 (3) and odabco·2H2SO4 (4) were synthesized and characterized by single-crystal x-ray diffraction (XRD), powder XRD and infrared spectroscopy. Compound 1 is based on the isolated (H2odabco)2+ fragments, representing 0D structure. 2 is based on cationic 1D {Hodabco}nn+ hydrogen-bonded chains. Compound 3 comprising a strongly coordinated sulfate anion consists of two-component hydrogen-bonded {-H2odabco-SO4−} fragments forming uncharged 1D helical chains. 4 contains both {-HSO4-}nn– and {-HSO4-H2odabco-HSO4−} hydrogen bonding motifs, resulting in a 3D polymeric network. A comparative structural analysis of both the obtained and the previously reported cognate structures was performed to rationalize the impact of the degree of odabco protonation and the anion donor ability on the structural features and dimensionalities of odabco-based hydrogen-bonded lattices.",
keywords = "HOFs, crystal structure, dabco N,N{\textquoteright}-dioxide, hydrogen bond, nitrate, perchlorate, salts, sulfate",
author = "Abasheeva, {Ksenia D.} and Demakov, {Pavel A.} and Fedin, {Vladimir P.}",
note = "Funding: The research was supported by the Russian Science Foundation, project № 22-23-20179, https://rscf.ru/project/22-23-20179/, and the Government of Novosibirsk region, project № p-22.",
year = "2022",
month = dec,
day = "1",
doi = "10.3390/M1508",
language = "English",
volume = "2022",
journal = "MolBank",
issn = "1422-8599",
publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",
number = "4",

}

RIS

TY - JOUR

T1 - Diverse Hydrogen-Bonded Structural Motifs in 1,4-Diazabicyclo[2.2.2]octane N,N’-Dioxide Salts with Oxoanions

AU - Abasheeva, Ksenia D.

AU - Demakov, Pavel A.

AU - Fedin, Vladimir P.

N1 - Funding: The research was supported by the Russian Science Foundation, project № 22-23-20179, https://rscf.ru/project/22-23-20179/, and the Government of Novosibirsk region, project № p-22.

PY - 2022/12/1

Y1 - 2022/12/1

N2 - Four new hybrid inorganic–organic salts of 1,4-diazabicyclo[2.2.2]octane N,N’-dioxide (odabco) with the formulae odabco·2HNO3 (1), odabco·HClO4 (2), odabco·H2SO4 (3) and odabco·2H2SO4 (4) were synthesized and characterized by single-crystal x-ray diffraction (XRD), powder XRD and infrared spectroscopy. Compound 1 is based on the isolated (H2odabco)2+ fragments, representing 0D structure. 2 is based on cationic 1D {Hodabco}nn+ hydrogen-bonded chains. Compound 3 comprising a strongly coordinated sulfate anion consists of two-component hydrogen-bonded {-H2odabco-SO4−} fragments forming uncharged 1D helical chains. 4 contains both {-HSO4-}nn– and {-HSO4-H2odabco-HSO4−} hydrogen bonding motifs, resulting in a 3D polymeric network. A comparative structural analysis of both the obtained and the previously reported cognate structures was performed to rationalize the impact of the degree of odabco protonation and the anion donor ability on the structural features and dimensionalities of odabco-based hydrogen-bonded lattices.

AB - Four new hybrid inorganic–organic salts of 1,4-diazabicyclo[2.2.2]octane N,N’-dioxide (odabco) with the formulae odabco·2HNO3 (1), odabco·HClO4 (2), odabco·H2SO4 (3) and odabco·2H2SO4 (4) were synthesized and characterized by single-crystal x-ray diffraction (XRD), powder XRD and infrared spectroscopy. Compound 1 is based on the isolated (H2odabco)2+ fragments, representing 0D structure. 2 is based on cationic 1D {Hodabco}nn+ hydrogen-bonded chains. Compound 3 comprising a strongly coordinated sulfate anion consists of two-component hydrogen-bonded {-H2odabco-SO4−} fragments forming uncharged 1D helical chains. 4 contains both {-HSO4-}nn– and {-HSO4-H2odabco-HSO4−} hydrogen bonding motifs, resulting in a 3D polymeric network. A comparative structural analysis of both the obtained and the previously reported cognate structures was performed to rationalize the impact of the degree of odabco protonation and the anion donor ability on the structural features and dimensionalities of odabco-based hydrogen-bonded lattices.

KW - HOFs

KW - crystal structure

KW - dabco N,N’-dioxide

KW - hydrogen bond

KW - nitrate

KW - perchlorate

KW - salts

KW - sulfate

UR - https://www.scopus.com/inward/record.url?eid=2-s2.0-85144705174&partnerID=40&md5=9db643b3bf230d911977f241de83308e

UR - https://www.mendeley.com/catalogue/b33cc4c7-1f2e-3ea0-a882-32146c03fbde/

U2 - 10.3390/M1508

DO - 10.3390/M1508

M3 - Article

VL - 2022

JO - MolBank

JF - MolBank

SN - 1422-8599

IS - 4

M1 - M1508

ER -

ID: 44673959