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Distribution of D2O Molecules of First and Second Types in Hydrothermally Grown Beryl Crystals. / Belyanchikov, M. A.; Abramov, P. A.; Ragozin, A. L. et al.

In: Crystal Growth and Design, Vol. 21, No. 4, 07.04.2021, p. 2283-2291.

Research output: Contribution to journal › Article › peer-review

Harvard

Belyanchikov, MA, Abramov, PA, Ragozin, AL, Fursenko, DA, Gorshunov, BP & Thomas, VG 2021, 'Distribution of D2O Molecules of First and Second Types in Hydrothermally Grown Beryl Crystals', Crystal Growth and Design, vol. 21, no. 4, pp. 2283-2291. https://doi.org/10.1021/acs.cgd.0c01702

APA

Belyanchikov, M. A., Abramov, P. A., Ragozin, A. L., Fursenko, D. A., Gorshunov, B. P., & Thomas, V. G. (2021). Distribution of D2O Molecules of First and Second Types in Hydrothermally Grown Beryl Crystals. Crystal Growth and Design, 21(4), 2283-2291. https://doi.org/10.1021/acs.cgd.0c01702

Vancouver

Belyanchikov MA, Abramov PA, Ragozin AL, Fursenko DA, Gorshunov BP, Thomas VG. Distribution of D2O Molecules of First and Second Types in Hydrothermally Grown Beryl Crystals. Crystal Growth and Design. 2021 Apr 7;21(4):2283-2291. doi: 10.1021/acs.cgd.0c01702

Author

Belyanchikov, M. A. ; Abramov, P. A. ; Ragozin, A. L. et al. / Distribution of D2O Molecules of First and Second Types in Hydrothermally Grown Beryl Crystals. In: Crystal Growth and Design. 2021 ; Vol. 21, No. 4. pp. 2283-2291.

BibTeX

@article{01cd9e05b91e4a008ef703808fc3e71c,
title = "Distribution of D2O Molecules of First and Second Types in Hydrothermally Grown Beryl Crystals",
abstract = "This article reports on the uneven distribution of water molecules of first (D2O-I) and second (D2O-II) types in a D2O-containing beryl crystal grown hydrothermally on a non-singularly oriented flat seed {5.5.10¯.6}, as identified by infrared spectroscopic studies of crystal fragments. The distribution of D2O-II molecules is very heterogeneous, and their maximal concentrations are at the boundaries of the growth sectors of micro-faces, which protrude from the surface growth front {5.5.10¯.6}. We attribute this increase in the D2O-II content to the tensions and the resulting increased internal pressure at the boundaries of the growth sectors of micro-faces. Specifically, the increased internal pressure shifts the isomorphic substitution equation in beryl SiT14+ → AlT13+ + LiR″+ to the right (T1 and R″ denote the crystal's chemical positions of cations), which triggers the D2O-I → D2O-II transformation. The number of growth sector boundaries goes down as the growth front moves, reducing the number of areas with increased internal pressure and the proportion of D2O-II/D2O-I. ",
author = "Belyanchikov, {M. A.} and Abramov, {P. A.} and Ragozin, {A. L.} and Fursenko, {D. A.} and Gorshunov, {B. P.} and Thomas, {V. G.}",
note = "Funding Information: The research was carried out in accordance with the state assignment of IGM SB RAS and supported by Program 5–100 of Russian Ministry of Science and Higher Education. The technical and financial assistance for growing the DO-containing beryl crystal were provided by Tairus LLC (Novosibirsk, Russia). The authors express their gratitude to O. A. Kozmenko (IGM, Novosibirsk, Russia) for participating in the discussion of the work and E. Poslavskaya (Tomas), and for the thorough work on proof-reading and editing of the manuscript. 2 a Publisher Copyright: {\textcopyright} 2021 American Chemical Society.",
year = "2021",
month = apr,
day = "7",
doi = "10.1021/acs.cgd.0c01702",
language = "English",
volume = "21",
pages = "2283--2291",
journal = "Crystal Growth and Design",
issn = "1528-7483",
publisher = "American Chemical Society",
number = "4",

}

RIS

TY - JOUR

T1 - Distribution of D2O Molecules of First and Second Types in Hydrothermally Grown Beryl Crystals

AU - Belyanchikov, M. A.

AU - Abramov, P. A.

AU - Ragozin, A. L.

AU - Fursenko, D. A.

AU - Gorshunov, B. P.

AU - Thomas, V. G.

N1 - Funding Information: The research was carried out in accordance with the state assignment of IGM SB RAS and supported by Program 5–100 of Russian Ministry of Science and Higher Education. The technical and financial assistance for growing the DO-containing beryl crystal were provided by Tairus LLC (Novosibirsk, Russia). The authors express their gratitude to O. A. Kozmenko (IGM, Novosibirsk, Russia) for participating in the discussion of the work and E. Poslavskaya (Tomas), and for the thorough work on proof-reading and editing of the manuscript. 2 a Publisher Copyright: © 2021 American Chemical Society.

PY - 2021/4/7

Y1 - 2021/4/7

N2 - This article reports on the uneven distribution of water molecules of first (D2O-I) and second (D2O-II) types in a D2O-containing beryl crystal grown hydrothermally on a non-singularly oriented flat seed {5.5.10¯.6}, as identified by infrared spectroscopic studies of crystal fragments. The distribution of D2O-II molecules is very heterogeneous, and their maximal concentrations are at the boundaries of the growth sectors of micro-faces, which protrude from the surface growth front {5.5.10¯.6}. We attribute this increase in the D2O-II content to the tensions and the resulting increased internal pressure at the boundaries of the growth sectors of micro-faces. Specifically, the increased internal pressure shifts the isomorphic substitution equation in beryl SiT14+ → AlT13+ + LiR″+ to the right (T1 and R″ denote the crystal's chemical positions of cations), which triggers the D2O-I → D2O-II transformation. The number of growth sector boundaries goes down as the growth front moves, reducing the number of areas with increased internal pressure and the proportion of D2O-II/D2O-I.

AB - This article reports on the uneven distribution of water molecules of first (D2O-I) and second (D2O-II) types in a D2O-containing beryl crystal grown hydrothermally on a non-singularly oriented flat seed {5.5.10¯.6}, as identified by infrared spectroscopic studies of crystal fragments. The distribution of D2O-II molecules is very heterogeneous, and their maximal concentrations are at the boundaries of the growth sectors of micro-faces, which protrude from the surface growth front {5.5.10¯.6}. We attribute this increase in the D2O-II content to the tensions and the resulting increased internal pressure at the boundaries of the growth sectors of micro-faces. Specifically, the increased internal pressure shifts the isomorphic substitution equation in beryl SiT14+ → AlT13+ + LiR″+ to the right (T1 and R″ denote the crystal's chemical positions of cations), which triggers the D2O-I → D2O-II transformation. The number of growth sector boundaries goes down as the growth front moves, reducing the number of areas with increased internal pressure and the proportion of D2O-II/D2O-I.

UR - http://www.scopus.com/inward/record.url?scp=85103375381&partnerID=8YFLogxK

U2 - 10.1021/acs.cgd.0c01702

DO - 10.1021/acs.cgd.0c01702

M3 - Article

AN - SCOPUS:85103375381

VL - 21

SP - 2283

EP - 2291

JO - Crystal Growth and Design

JF - Crystal Growth and Design

SN - 1528-7483

IS - 4

ER -

ID: 34174323