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Directed synthesis of isomeric polyfluorinated dinitrotetraoxacalixarenes and bicyclooxacalixarenes. / Han, Huizhe; Kovtonyuk, Vladimir N.; Gatilov, Yurii V. et al.

In: Journal of Fluorine Chemistry, Vol. 261-262, 110022, 09.2022.

Research output: Contribution to journal › Article › peer-review

Harvard

Han, H, Kovtonyuk, VN, Gatilov, YV & Andreev, RV 2022, 'Directed synthesis of isomeric polyfluorinated dinitrotetraoxacalixarenes and bicyclooxacalixarenes', Journal of Fluorine Chemistry, vol. 261-262, 110022. https://doi.org/10.1016/j.jfluchem.2022.110022

APA

Han, H., Kovtonyuk, V. N., Gatilov, Y. V., & Andreev, R. V. (2022). Directed synthesis of isomeric polyfluorinated dinitrotetraoxacalixarenes and bicyclooxacalixarenes. Journal of Fluorine Chemistry, 261-262, [110022]. https://doi.org/10.1016/j.jfluchem.2022.110022

Vancouver

Han H, Kovtonyuk VN, Gatilov YV, Andreev RV. Directed synthesis of isomeric polyfluorinated dinitrotetraoxacalixarenes and bicyclooxacalixarenes. Journal of Fluorine Chemistry. 2022 Sept;261-262:110022. doi: 10.1016/j.jfluchem.2022.110022

Author

Han, Huizhe ; Kovtonyuk, Vladimir N. ; Gatilov, Yurii V. et al. / Directed synthesis of isomeric polyfluorinated dinitrotetraoxacalixarenes and bicyclooxacalixarenes. In: Journal of Fluorine Chemistry. 2022 ; Vol. 261-262.

BibTeX

@article{2d3a6713f5604068b04a9cb68dc2b684,
title = "Directed synthesis of isomeric polyfluorinated dinitrotetraoxacalixarenes and bicyclooxacalixarenes",
abstract = "The direction of interaction of pentafluoronitrobenzene with resorcinol and orcinol largely depends on the polarity of the solvent and the nature of the base, which made it possible to carry out the directed synthesis of fluorinated tetraoxacalixarenes with the arrangement of nitro groups either in the outer or inner rim of the macrocycle. Polyfluorinated tetraoxacalix[4]arene with nitro groups located in the inner rim of the macrocycle exists in the solvent as an equilibrium mixture of two stable conformers, and the equilibrium position depends largely on the polarity of the solvent.",
keywords = "Bicycloxacalixarenes, Conformational equilibrium, Orcinol, Pentafluoronitrobenzene, Polyfluorinated tetraoxacalixarenes, Resorcinol, X-ray diffraction",
author = "Huizhe Han and Kovtonyuk, {Vladimir N.} and Gatilov, {Yurii V.} and Andreev, {Rodion V.}",
note = "Funding Information: The investigation was carried out with the financial support of the Ministry of Education and Science of Russia. Huizhe Han thanks the China Scholarship Council for financial support. Authors would like to acknowledge the Multi-Access Chemical Research Center SB RAS for spectral and analytical measurements. Funding Information: Huizhe Han reports financial support was provided by China Scholarship Council. Publisher Copyright: {\textcopyright} 2022",
year = "2022",
month = sep,
doi = "10.1016/j.jfluchem.2022.110022",
language = "English",
volume = "261-262",
journal = "Journal of Fluorine Chemistry",
issn = "0022-1139",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Directed synthesis of isomeric polyfluorinated dinitrotetraoxacalixarenes and bicyclooxacalixarenes

AU - Han, Huizhe

AU - Kovtonyuk, Vladimir N.

AU - Gatilov, Yurii V.

AU - Andreev, Rodion V.

N1 - Funding Information: The investigation was carried out with the financial support of the Ministry of Education and Science of Russia. Huizhe Han thanks the China Scholarship Council for financial support. Authors would like to acknowledge the Multi-Access Chemical Research Center SB RAS for spectral and analytical measurements. Funding Information: Huizhe Han reports financial support was provided by China Scholarship Council. Publisher Copyright: © 2022

PY - 2022/9

Y1 - 2022/9

N2 - The direction of interaction of pentafluoronitrobenzene with resorcinol and orcinol largely depends on the polarity of the solvent and the nature of the base, which made it possible to carry out the directed synthesis of fluorinated tetraoxacalixarenes with the arrangement of nitro groups either in the outer or inner rim of the macrocycle. Polyfluorinated tetraoxacalix[4]arene with nitro groups located in the inner rim of the macrocycle exists in the solvent as an equilibrium mixture of two stable conformers, and the equilibrium position depends largely on the polarity of the solvent.

AB - The direction of interaction of pentafluoronitrobenzene with resorcinol and orcinol largely depends on the polarity of the solvent and the nature of the base, which made it possible to carry out the directed synthesis of fluorinated tetraoxacalixarenes with the arrangement of nitro groups either in the outer or inner rim of the macrocycle. Polyfluorinated tetraoxacalix[4]arene with nitro groups located in the inner rim of the macrocycle exists in the solvent as an equilibrium mixture of two stable conformers, and the equilibrium position depends largely on the polarity of the solvent.

KW - Bicycloxacalixarenes

KW - Conformational equilibrium

KW - Orcinol

KW - Pentafluoronitrobenzene

KW - Polyfluorinated tetraoxacalixarenes

KW - Resorcinol

KW - X-ray diffraction

UR - http://www.scopus.com/inward/record.url?scp=85134686593&partnerID=8YFLogxK

U2 - 10.1016/j.jfluchem.2022.110022

DO - 10.1016/j.jfluchem.2022.110022

M3 - Article

AN - SCOPUS:85134686593

VL - 261-262

JO - Journal of Fluorine Chemistry

JF - Journal of Fluorine Chemistry

SN - 0022-1139

M1 - 110022

ER -

ID: 36745147