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Directed synthesis of fluorine containing 2,3-dihydrobenzo[b][1,4]oxathiine derivatives from polyfluoroarenes. / Politanskaya, Larisa; Tretyakov, Evgeny.

In: Journal of Fluorine Chemistry, Vol. 236, 109592, 01.08.2020.

Research output: Contribution to journal › Article › peer-review

Harvard

Politanskaya, L & Tretyakov, E 2020, 'Directed synthesis of fluorine containing 2,3-dihydrobenzo[b][1,4]oxathiine derivatives from polyfluoroarenes', Journal of Fluorine Chemistry, vol. 236, 109592. https://doi.org/10.1016/j.jfluchem.2020.109592

APA

Politanskaya, L., & Tretyakov, E. (2020). Directed synthesis of fluorine containing 2,3-dihydrobenzo[b][1,4]oxathiine derivatives from polyfluoroarenes. Journal of Fluorine Chemistry, 236, [109592]. https://doi.org/10.1016/j.jfluchem.2020.109592

Vancouver

Politanskaya L, Tretyakov E. Directed synthesis of fluorine containing 2,3-dihydrobenzo[b][1,4]oxathiine derivatives from polyfluoroarenes. Journal of Fluorine Chemistry. 2020 Aug 1;236:109592. doi: 10.1016/j.jfluchem.2020.109592

Author

Politanskaya, Larisa ; Tretyakov, Evgeny. / Directed synthesis of fluorine containing 2,3-dihydrobenzo[b][1,4]oxathiine derivatives from polyfluoroarenes. In: Journal of Fluorine Chemistry. 2020 ; Vol. 236.

BibTeX

@article{1bf733f8b1e545979d32ceaabe9c8529,
title = "Directed synthesis of fluorine containing 2,3-dihydrobenzo[b][1,4]oxathiine derivatives from polyfluoroarenes",
abstract = "Polyfluorinated 2,3-dihydrobenzo[b][1,4]oxathiines were synthesized starting from monosubstituted hexafluorobenzenes and 2-mercaptoethanol via aromatic nucleophilic substitution of fluorine atoms in good yields. The reactions take place under mild reaction conditions and require readily available starting materials. The possibility of structural modifications of the obtained heterocycles through interaction with phenylethylamine and potassium methylate was demonstrated.",
keywords = "Aromatic nucleophilic substitution, Fluorinated S,O-heterocycles, Polyfluorinated 2,3-dihydrobenzo[b][1,4]oxathiines, Polyfluorinated 2-(vinylthio)phenol, ANTIOXIDANT ACTIVITY, KETONES, RING, Polyfluorinated 2,3-dihydrobenzo[b][1,4] oxathiines, CYTOTOXICITY EVALUATION, EFFICIENT SYNTHESIS, SULFONES",
author = "Larisa Politanskaya and Evgeny Tretyakov",
note = "Funding Information: This work was supported by the Russian Foundation for Basic Research (grant No. 19-53-53003 ). The authors would like to acknowledge the Multi-Access Chemical Research Center SB RAS for spectral and analytical measurements. Publisher Copyright: {\textcopyright} 2020 Elsevier B.V.",
year = "2020",
month = aug,
day = "1",
doi = "10.1016/j.jfluchem.2020.109592",
language = "English",
volume = "236",
journal = "Journal of Fluorine Chemistry",
issn = "0022-1139",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Directed synthesis of fluorine containing 2,3-dihydrobenzo[b][1,4]oxathiine derivatives from polyfluoroarenes

AU - Politanskaya, Larisa

AU - Tretyakov, Evgeny

N1 - Funding Information: This work was supported by the Russian Foundation for Basic Research (grant No. 19-53-53003 ). The authors would like to acknowledge the Multi-Access Chemical Research Center SB RAS for spectral and analytical measurements. Publisher Copyright: © 2020 Elsevier B.V.

PY - 2020/8/1

Y1 - 2020/8/1

N2 - Polyfluorinated 2,3-dihydrobenzo[b][1,4]oxathiines were synthesized starting from monosubstituted hexafluorobenzenes and 2-mercaptoethanol via aromatic nucleophilic substitution of fluorine atoms in good yields. The reactions take place under mild reaction conditions and require readily available starting materials. The possibility of structural modifications of the obtained heterocycles through interaction with phenylethylamine and potassium methylate was demonstrated.

AB - Polyfluorinated 2,3-dihydrobenzo[b][1,4]oxathiines were synthesized starting from monosubstituted hexafluorobenzenes and 2-mercaptoethanol via aromatic nucleophilic substitution of fluorine atoms in good yields. The reactions take place under mild reaction conditions and require readily available starting materials. The possibility of structural modifications of the obtained heterocycles through interaction with phenylethylamine and potassium methylate was demonstrated.

KW - Aromatic nucleophilic substitution

KW - Fluorinated S,O-heterocycles

KW - Polyfluorinated 2,3-dihydrobenzo[b][1,4]oxathiines

KW - Polyfluorinated 2-(vinylthio)phenol

KW - ANTIOXIDANT ACTIVITY

KW - KETONES

KW - RING

KW - Polyfluorinated 2,3-dihydrobenzo[b][1,4] oxathiines

KW - CYTOTOXICITY EVALUATION

KW - EFFICIENT SYNTHESIS

KW - SULFONES

UR - http://www.scopus.com/inward/record.url?scp=85086775287&partnerID=8YFLogxK

U2 - 10.1016/j.jfluchem.2020.109592

DO - 10.1016/j.jfluchem.2020.109592

M3 - Article

AN - SCOPUS:85086775287

VL - 236

JO - Journal of Fluorine Chemistry

JF - Journal of Fluorine Chemistry

SN - 0022-1139

M1 - 109592

ER -

ID: 24568077