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Direct observation of x-ray excited optical luminescence from a Re6metal cluster in true aqueous solution : The missing link between material characterization and in vivo applications. / Stass, Dmitri V.; Vorotnikova, Natalya A.; Shestopalov, Michael A.

In: Journal of Applied Physics, Vol. 129, No. 18, 183102, 14.05.2021.

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@article{67bb8e79a6444b3cba8104ec5c76ff68,
title = "Direct observation of x-ray excited optical luminescence from a Re6metal cluster in true aqueous solution: The missing link between material characterization and in vivo applications",
abstract = "Phosphorescent octahedral metal cluster complexes are highly attractive in terms of biomedical applications, particularly in the area of luminescent diagnostics and photodynamic therapy (PDT). The ability of clusters to be excited by x-radiation followed by red/near infrared emission makes them a new promising class of photosensitizers for deep-PDT. This work demonstrates a direct observation of x-ray-excited optical luminescence of hexanuclear clusters, by example of rhenium cluster complex Na4[{Re6Se8}(CN)6], in a true aqueous solution. The article also describes point-by-point the details and pitfalls of studying cluster radioluminescence in aqueous solution.",
author = "Stass, {Dmitri V.} and Vorotnikova, {Natalya A.} and Shestopalov, {Michael A.}",
note = "Funding Information: This work was supported by the Russian Science Foundation (Grant No. 19-73-00223). Also, D.V.S. is grateful to Dr. A. I. Kruppa and Dr. I. M. Magin, ICKC SB RAS, for assistance in sample preparation. Publisher Copyright: {\textcopyright} 2021 Author(s). Copyright: Copyright 2021 Elsevier B.V., All rights reserved.",
year = "2021",
month = may,
day = "14",
doi = "10.1063/5.0049769",
language = "English",
volume = "129",
journal = "Journal of Applied Physics",
issn = "0021-8979",
publisher = "AMER INST PHYSICS",
number = "18",

}

RIS

TY - JOUR

T1 - Direct observation of x-ray excited optical luminescence from a Re6metal cluster in true aqueous solution

T2 - The missing link between material characterization and in vivo applications

AU - Stass, Dmitri V.

AU - Vorotnikova, Natalya A.

AU - Shestopalov, Michael A.

N1 - Funding Information: This work was supported by the Russian Science Foundation (Grant No. 19-73-00223). Also, D.V.S. is grateful to Dr. A. I. Kruppa and Dr. I. M. Magin, ICKC SB RAS, for assistance in sample preparation. Publisher Copyright: © 2021 Author(s). Copyright: Copyright 2021 Elsevier B.V., All rights reserved.

PY - 2021/5/14

Y1 - 2021/5/14

N2 - Phosphorescent octahedral metal cluster complexes are highly attractive in terms of biomedical applications, particularly in the area of luminescent diagnostics and photodynamic therapy (PDT). The ability of clusters to be excited by x-radiation followed by red/near infrared emission makes them a new promising class of photosensitizers for deep-PDT. This work demonstrates a direct observation of x-ray-excited optical luminescence of hexanuclear clusters, by example of rhenium cluster complex Na4[{Re6Se8}(CN)6], in a true aqueous solution. The article also describes point-by-point the details and pitfalls of studying cluster radioluminescence in aqueous solution.

AB - Phosphorescent octahedral metal cluster complexes are highly attractive in terms of biomedical applications, particularly in the area of luminescent diagnostics and photodynamic therapy (PDT). The ability of clusters to be excited by x-radiation followed by red/near infrared emission makes them a new promising class of photosensitizers for deep-PDT. This work demonstrates a direct observation of x-ray-excited optical luminescence of hexanuclear clusters, by example of rhenium cluster complex Na4[{Re6Se8}(CN)6], in a true aqueous solution. The article also describes point-by-point the details and pitfalls of studying cluster radioluminescence in aqueous solution.

UR - http://www.scopus.com/inward/record.url?scp=85105872320&partnerID=8YFLogxK

U2 - 10.1063/5.0049769

DO - 10.1063/5.0049769

M3 - Article

AN - SCOPUS:85105872320

VL - 129

JO - Journal of Applied Physics

JF - Journal of Applied Physics

SN - 0021-8979

IS - 18

M1 - 183102

ER -

ID: 28599305