Standard

Direct conversion of methane to zeolite-templated carbons, light hydrocarbons, and hydrogen. / Liu, Yujie; Osta, Elisabet Huertas; Poryvaev, Artem S. et al.

In: Carbon, Vol. 201, 05.01.2023, p. 535-541.

Research output: Contribution to journal › Article › peer-review

Harvard

Liu, Y, Osta, EH, Poryvaev, AS, Fedin, MV, Longo, A, Nefedov, A & Kosinov, N 2023, 'Direct conversion of methane to zeolite-templated carbons, light hydrocarbons, and hydrogen', Carbon, vol. 201, pp. 535-541. https://doi.org/10.1016/j.carbon.2022.09.050

APA

Liu, Y., Osta, E. H., Poryvaev, A. S., Fedin, M. V., Longo, A., Nefedov, A., & Kosinov, N. (2023). Direct conversion of methane to zeolite-templated carbons, light hydrocarbons, and hydrogen. Carbon, 201, 535-541. https://doi.org/10.1016/j.carbon.2022.09.050

Vancouver

Liu Y, Osta EH, Poryvaev AS, Fedin MV, Longo A, Nefedov A et al. Direct conversion of methane to zeolite-templated carbons, light hydrocarbons, and hydrogen. Carbon. 2023 Jan 5;201:535-541. doi: 10.1016/j.carbon.2022.09.050

Author

Liu, Yujie ; Osta, Elisabet Huertas ; Poryvaev, Artem S. et al. / Direct conversion of methane to zeolite-templated carbons, light hydrocarbons, and hydrogen. In: Carbon. 2023 ; Vol. 201. pp. 535-541.

BibTeX

@article{3cfee1030ac944f2bd2466a0f7243efb,
title = "Direct conversion of methane to zeolite-templated carbons, light hydrocarbons, and hydrogen",
abstract = "Efficient direct valorization of methane to value-added chemicals and materials remains an unsolved challenge for modern chemistry and materials science. In this work, we explored direct non-oxidative conversion of methane to hydrogen, hydrocarbons, and valuable zeolite-templated carbon materials. First, using a set of spectroscopy and microscopy characterization tools, we investigated how the reaction conditions influence the process of carbon formation inside the typical zeolite-based catalyst Mo/ZSM-5. Then, we explored the effect of the zeolite topology on the growth of carbon materials from methane decomposition over Mo/MFI, Mo/MOR, Mo/BEA, and Mo/FAU templates. Finally, we applied the obtained insights to prepare high-quality zeolite-templated carbons directly from methane using Fe/BEA and Fe/FAU templates. Altogether, our results represent a carbon-economic method of methane conversion to COx-free hydrogen gas, a mixture of light aliphatic and aromatic hydrocarbons, and valuable carbon materials.",
keywords = "Light hydrocarbons, Methane conversion, Mo/ZSM-5, Zeolite topology, Zeolite-templated carbons",
author = "Yujie Liu and Osta, {Elisabet Huertas} and Poryvaev, {Artem S.} and Fedin, {Matvey V.} and Alessandro Longo and Alexei Nefedov and Nikolay Kosinov",
note = "Funding Information: Financial support from China Scholarship Council ( 201806930028 ) is gratefully acknowledged. This publication is part of the project OCENW.XS21.3.019 which is financed by the Dutch Research Council (NWO) . We acknowledge the European Synchrotron Radiation Facility for provision of synchrotron radiation facilities. The Helmholtz Zentrum Berlin is gratefully acknowledged for beamtime allocation. Publisher Copyright: {\textcopyright} 2022 The Authors",
year = "2023",
month = jan,
day = "5",
doi = "10.1016/j.carbon.2022.09.050",
language = "English",
volume = "201",
pages = "535--541",
journal = "Carbon",
issn = "0008-6223",
publisher = "Elsevier Ltd",

}

RIS

TY - JOUR

T1 - Direct conversion of methane to zeolite-templated carbons, light hydrocarbons, and hydrogen

AU - Liu, Yujie

AU - Osta, Elisabet Huertas

AU - Poryvaev, Artem S.

AU - Fedin, Matvey V.

AU - Longo, Alessandro

AU - Nefedov, Alexei

AU - Kosinov, Nikolay

N1 - Funding Information: Financial support from China Scholarship Council ( 201806930028 ) is gratefully acknowledged. This publication is part of the project OCENW.XS21.3.019 which is financed by the Dutch Research Council (NWO) . We acknowledge the European Synchrotron Radiation Facility for provision of synchrotron radiation facilities. The Helmholtz Zentrum Berlin is gratefully acknowledged for beamtime allocation. Publisher Copyright: © 2022 The Authors

PY - 2023/1/5

Y1 - 2023/1/5

N2 - Efficient direct valorization of methane to value-added chemicals and materials remains an unsolved challenge for modern chemistry and materials science. In this work, we explored direct non-oxidative conversion of methane to hydrogen, hydrocarbons, and valuable zeolite-templated carbon materials. First, using a set of spectroscopy and microscopy characterization tools, we investigated how the reaction conditions influence the process of carbon formation inside the typical zeolite-based catalyst Mo/ZSM-5. Then, we explored the effect of the zeolite topology on the growth of carbon materials from methane decomposition over Mo/MFI, Mo/MOR, Mo/BEA, and Mo/FAU templates. Finally, we applied the obtained insights to prepare high-quality zeolite-templated carbons directly from methane using Fe/BEA and Fe/FAU templates. Altogether, our results represent a carbon-economic method of methane conversion to COx-free hydrogen gas, a mixture of light aliphatic and aromatic hydrocarbons, and valuable carbon materials.

AB - Efficient direct valorization of methane to value-added chemicals and materials remains an unsolved challenge for modern chemistry and materials science. In this work, we explored direct non-oxidative conversion of methane to hydrogen, hydrocarbons, and valuable zeolite-templated carbon materials. First, using a set of spectroscopy and microscopy characterization tools, we investigated how the reaction conditions influence the process of carbon formation inside the typical zeolite-based catalyst Mo/ZSM-5. Then, we explored the effect of the zeolite topology on the growth of carbon materials from methane decomposition over Mo/MFI, Mo/MOR, Mo/BEA, and Mo/FAU templates. Finally, we applied the obtained insights to prepare high-quality zeolite-templated carbons directly from methane using Fe/BEA and Fe/FAU templates. Altogether, our results represent a carbon-economic method of methane conversion to COx-free hydrogen gas, a mixture of light aliphatic and aromatic hydrocarbons, and valuable carbon materials.

KW - Light hydrocarbons

KW - Methane conversion

KW - Mo/ZSM-5

KW - Zeolite topology

KW - Zeolite-templated carbons

UR - http://www.scopus.com/inward/record.url?scp=85138444923&partnerID=8YFLogxK

U2 - 10.1016/j.carbon.2022.09.050

DO - 10.1016/j.carbon.2022.09.050

M3 - Article

AN - SCOPUS:85138444923

VL - 201

SP - 535

EP - 541

JO - Carbon

JF - Carbon

SN - 0008-6223

ER -

ID: 38844321