Research output: Contribution to journal › Conference article › peer-review
Development of layered anode structures supported over apatite-type solid electrolytes. / Pandis, P.; Kharlamova, T.; Sadykov, V. et al.
In: MATEC Web of Conferences, Vol. 41, 04001, 01.02.2016.Research output: Contribution to journal › Conference article › peer-review
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TY - JOUR
T1 - Development of layered anode structures supported over apatite-type solid electrolytes
AU - Pandis, P.
AU - Kharlamova, T.
AU - Sadykov, V.
AU - Stathopoulos, V. N.
PY - 2016/2/1
Y1 - 2016/2/1
N2 - Apatite-type lanthanum silicates (ATLS) materials have attracted interest in recent literature as solid electrolytes for SOFCs. The fabrication of an ATLS based fuel cell with the state-of-art electrodes (NiO/YSZ as anode and LSCF or LSM as cathode) can show degradation after long operation hours due to Si diffusion mainly towards the anode. In this work, we report a "layer-by-layer anodic electrodes" fabrication by means of spin coating and physical spraying. The overall aim of this work is the successful fabrication of such a layered structure including suitable blocking layers towards the inhibition of Si interdiffusion from the apatite electrolyte to the anode. The results showed that the deposition of 3 layers of LFSO/GDC (3μm), NiO/GDC (4μm) and the final NiO/YSZ anode layer provided a stable half-cell, with no solid state reaction occurring among the electrodes and no Si diffusion observed towards the anode after thermal treatment at 800oC for 120h.
AB - Apatite-type lanthanum silicates (ATLS) materials have attracted interest in recent literature as solid electrolytes for SOFCs. The fabrication of an ATLS based fuel cell with the state-of-art electrodes (NiO/YSZ as anode and LSCF or LSM as cathode) can show degradation after long operation hours due to Si diffusion mainly towards the anode. In this work, we report a "layer-by-layer anodic electrodes" fabrication by means of spin coating and physical spraying. The overall aim of this work is the successful fabrication of such a layered structure including suitable blocking layers towards the inhibition of Si interdiffusion from the apatite electrolyte to the anode. The results showed that the deposition of 3 layers of LFSO/GDC (3μm), NiO/GDC (4μm) and the final NiO/YSZ anode layer provided a stable half-cell, with no solid state reaction occurring among the electrodes and no Si diffusion observed towards the anode after thermal treatment at 800oC for 120h.
UR - http://www.scopus.com/inward/record.url?scp=84969780656&partnerID=8YFLogxK
U2 - 10.1051/mateccont/20164104001
DO - 10.1051/mateccont/20164104001
M3 - Conference article
AN - SCOPUS:84969780656
VL - 41
JO - MATEC Web of Conferences
JF - MATEC Web of Conferences
SN - 2261-236X
M1 - 04001
T2 - 1st Mini Conference on Emerging Engineering Applications, MCEEA 2015
Y2 - 26 November 2015 through 27 November 2015
ER -
ID: 25395328