Research output: Contribution to journal › Article › peer-review
Design and performance of asymmetric supported membranes for oxygen and hydrogen separation. / Sadykov, Vladislav A.; Eremeev, Nikita F.; Fedorova, Yulia E. et al.
In: International Journal of Hydrogen Energy, Vol. 46, No. 38, 03.06.2021, p. 20222-20239.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Design and performance of asymmetric supported membranes for oxygen and hydrogen separation
AU - Sadykov, Vladislav A.
AU - Eremeev, Nikita F.
AU - Fedorova, Yulia E.
AU - Krasnov, Alexey V.
AU - Bobrova, Ludmilla N.
AU - Bespalko, Yulia N.
AU - Lukashevich, Anton I.
AU - Skriabin, Pavel I.
AU - Smorygo, Oleg L.
AU - Van Veen, Andre C.
N1 - Publisher Copyright: © 2020 Hydrogen Energy Publications LLC Copyright: Copyright 2021 Elsevier B.V., All rights reserved.
PY - 2021/6/3
Y1 - 2021/6/3
N2 - Producing syngas and hydrogen from biofuels is a promising technology in the modern energy. In this work results of authors’ research aimed at design of supported membranes for oxygen and hydrogen separation are reviewed. Nanocomposites were deposited as thin layers on Ni–Al foam substrates. Oxygen separation membranes were tested in CH4 selective oxidation/oxi-dry reforming. The hydrogen separation membranes were tested in C2H5OH steam reforming. High oxygen/hydrogen fluxes were demonstrated. For oxygen separation membranes syngas yield and methane conversion increase with temperature and contact time. For reactor with hydrogen separation membrane a good performance in ethanol steam reforming was obtained. Hydrogen permeation increases with ethanol inlet concentration, then a slight decrease is observed. The results of tests demonstrated the oxygen/hydrogen permeability promising for the practical application, high catalytic performance and a good thermochemical stability.
AB - Producing syngas and hydrogen from biofuels is a promising technology in the modern energy. In this work results of authors’ research aimed at design of supported membranes for oxygen and hydrogen separation are reviewed. Nanocomposites were deposited as thin layers on Ni–Al foam substrates. Oxygen separation membranes were tested in CH4 selective oxidation/oxi-dry reforming. The hydrogen separation membranes were tested in C2H5OH steam reforming. High oxygen/hydrogen fluxes were demonstrated. For oxygen separation membranes syngas yield and methane conversion increase with temperature and contact time. For reactor with hydrogen separation membrane a good performance in ethanol steam reforming was obtained. Hydrogen permeation increases with ethanol inlet concentration, then a slight decrease is observed. The results of tests demonstrated the oxygen/hydrogen permeability promising for the practical application, high catalytic performance and a good thermochemical stability.
KW - Asymmetric supported membranes
KW - Methane and ethanol reforming
KW - Nanocomposites
KW - Oxygen and hydrogen separation
KW - Process parameters
UR - http://www.scopus.com/inward/record.url?scp=85079281326&partnerID=8YFLogxK
U2 - 10.1016/j.ijhydene.2020.01.106
DO - 10.1016/j.ijhydene.2020.01.106
M3 - Article
AN - SCOPUS:85079281326
VL - 46
SP - 20222
EP - 20239
JO - International Journal of Hydrogen Energy
JF - International Journal of Hydrogen Energy
SN - 0360-3199
IS - 38
ER -
ID: 23429201