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Cyanide Complexes Based on {Mo6I8}4+ and {W6I8}4+ Cluster Cores. / Pronin, Aleksei S.; Yarovoy, Spartak S.; Gayfulin, Yakov M. et al.

In: Molecules (Basel, Switzerland), Vol. 25, No. 24, 5796, 08.12.2020.

Research output: Contribution to journal › Article › peer-review

Harvard

Pronin, AS, Yarovoy, SS, Gayfulin, YM, Ryadun, AA, Brylev, KA, Samsonenko, DG, Eltsov, IV & Mironov, YV 2020, 'Cyanide Complexes Based on {Mo6I8}4+ and {W6I8}4+ Cluster Cores', Molecules (Basel, Switzerland), vol. 25, no. 24, 5796. https://doi.org/10.3390/molecules25245796

APA

Pronin, A. S., Yarovoy, S. S., Gayfulin, Y. M., Ryadun, A. A., Brylev, K. A., Samsonenko, D. G., Eltsov, I. V., & Mironov, Y. V. (2020). Cyanide Complexes Based on {Mo6I8}4+ and {W6I8}4+ Cluster Cores. Molecules (Basel, Switzerland), 25(24), [5796]. https://doi.org/10.3390/molecules25245796

Vancouver

Pronin AS, Yarovoy SS, Gayfulin YM, Ryadun AA, Brylev KA, Samsonenko DG et al. Cyanide Complexes Based on {Mo6I8}4+ and {W6I8}4+ Cluster Cores. Molecules (Basel, Switzerland). 2020 Dec 8;25(24):5796. doi: 10.3390/molecules25245796

Author

Pronin, Aleksei S. ; Yarovoy, Spartak S. ; Gayfulin, Yakov M. et al. / Cyanide Complexes Based on {Mo6I8}4+ and {W6I8}4+ Cluster Cores. In: Molecules (Basel, Switzerland). 2020 ; Vol. 25, No. 24.

BibTeX

@article{f50679cdd6e8445ca530db212d67b6c5,
title = "Cyanide Complexes Based on {Mo6I8}4+ and {W6I8}4+ Cluster Cores",
abstract = "Compounds based on new cyanide cluster anions [{Mo6I8}(CN)6]2-, trans-[{Mo6I8}(CN)4(MeO)2]2- and trans-[{W6I8}(CN)2(MeO)4]2- were synthesized using mechanochemical or solvothermal synthesis. The crystal and electronic structures as well as spectroscopic properties of the anions were investigated. It was found that the new compounds exhibit red luminescence upon excitation by UV light in the solid state and solutions, as other cluster complexes based on {Mo6I8}4+ and {W6I8}4+ cores do. The compounds can be recrystallized from aqueous methanol solutions; besides this, it was shown using NMR and UV-Vis spectroscopy that anions did not undergo hydrolysis in the solutions for a long time. These facts indicate that hydrolytic stabilization of {Mo6I8} and {W6I8} cluster cores can be achieved by coordination of cyanide ligands.",
keywords = "cluster compounds, crystal structure, cyanide ligand, hydrolytic stability, luminescence, molybdenum, tungsten, ONE-POT SYNTHESIS, CRYSTAL-STRUCTURE, LUMINESCENCE PROPERTIES, VIBRATIONAL-SPECTRA, BR, IODIDE CLUSTER, HEXANUCLEAR MOLYBDENUM, SILICA NANOPARTICLES, NORMAL-COORDINATE ANALYSIS, ELECTRONIC-STRUCTURE",
author = "Pronin, {Aleksei S.} and Yarovoy, {Spartak S.} and Gayfulin, {Yakov M.} and Ryadun, {Aleksey A.} and Brylev, {Konstantin A.} and Samsonenko, {Denis G.} and Eltsov, {Ilia V.} and Mironov, {Yuri V.}",
note = "Publisher Copyright: {\textcopyright} 2020 by the authors. Licensee MDPI, Basel, Switzerland.",
year = "2020",
month = dec,
day = "8",
doi = "10.3390/molecules25245796",
language = "English",
volume = "25",
journal = "Molecules",
issn = "1420-3049",
publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",
number = "24",

}

RIS

TY - JOUR

T1 - Cyanide Complexes Based on {Mo6I8}4+ and {W6I8}4+ Cluster Cores

AU - Pronin, Aleksei S.

AU - Yarovoy, Spartak S.

AU - Gayfulin, Yakov M.

AU - Ryadun, Aleksey A.

AU - Brylev, Konstantin A.

AU - Samsonenko, Denis G.

AU - Eltsov, Ilia V.

AU - Mironov, Yuri V.

N1 - Publisher Copyright: © 2020 by the authors. Licensee MDPI, Basel, Switzerland.

PY - 2020/12/8

Y1 - 2020/12/8

N2 - Compounds based on new cyanide cluster anions [{Mo6I8}(CN)6]2-, trans-[{Mo6I8}(CN)4(MeO)2]2- and trans-[{W6I8}(CN)2(MeO)4]2- were synthesized using mechanochemical or solvothermal synthesis. The crystal and electronic structures as well as spectroscopic properties of the anions were investigated. It was found that the new compounds exhibit red luminescence upon excitation by UV light in the solid state and solutions, as other cluster complexes based on {Mo6I8}4+ and {W6I8}4+ cores do. The compounds can be recrystallized from aqueous methanol solutions; besides this, it was shown using NMR and UV-Vis spectroscopy that anions did not undergo hydrolysis in the solutions for a long time. These facts indicate that hydrolytic stabilization of {Mo6I8} and {W6I8} cluster cores can be achieved by coordination of cyanide ligands.

AB - Compounds based on new cyanide cluster anions [{Mo6I8}(CN)6]2-, trans-[{Mo6I8}(CN)4(MeO)2]2- and trans-[{W6I8}(CN)2(MeO)4]2- were synthesized using mechanochemical or solvothermal synthesis. The crystal and electronic structures as well as spectroscopic properties of the anions were investigated. It was found that the new compounds exhibit red luminescence upon excitation by UV light in the solid state and solutions, as other cluster complexes based on {Mo6I8}4+ and {W6I8}4+ cores do. The compounds can be recrystallized from aqueous methanol solutions; besides this, it was shown using NMR and UV-Vis spectroscopy that anions did not undergo hydrolysis in the solutions for a long time. These facts indicate that hydrolytic stabilization of {Mo6I8} and {W6I8} cluster cores can be achieved by coordination of cyanide ligands.

KW - cluster compounds

KW - crystal structure

KW - cyanide ligand

KW - hydrolytic stability

KW - luminescence

KW - molybdenum

KW - tungsten

KW - ONE-POT SYNTHESIS

KW - CRYSTAL-STRUCTURE

KW - LUMINESCENCE PROPERTIES

KW - VIBRATIONAL-SPECTRA

KW - BR

KW - IODIDE CLUSTER

KW - HEXANUCLEAR MOLYBDENUM

KW - SILICA NANOPARTICLES

KW - NORMAL-COORDINATE ANALYSIS

KW - ELECTRONIC-STRUCTURE

UR - http://www.scopus.com/inward/record.url?scp=85098035730&partnerID=8YFLogxK

U2 - 10.3390/molecules25245796

DO - 10.3390/molecules25245796

M3 - Article

C2 - 33302595

AN - SCOPUS:85098035730

VL - 25

JO - Molecules

JF - Molecules

SN - 1420-3049

IS - 24

M1 - 5796

ER -

ID: 27330853