Research output: Contribution to journal › Article › peer-review
Cs2Mo5O16 and Cs2Mo7O22: crystallization, structural and thermal properties. / Григорьева, Вероника Дмитриевна; Бондарева, Анастасия Фёдоровна; Артемьева, Марина Андреевна et al.
In: Журнал структурной химии, Vol. 66, No. 4, 142914, 2025.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Cs2Mo5O16 and Cs2Mo7O22: crystallization, structural and thermal properties
AU - Григорьева, Вероника Дмитриевна
AU - Бондарева, Анастасия Фёдоровна
AU - Артемьева, Марина Андреевна
AU - Bazanova, E. D.
AU - Елисеев, Александр Павлович
AU - Рядун, Алексей Андреевич
AU - Кузнецов, Артем Борисович
N1 - Cs2Mo5O16 and Cs2Mo7O22: crystallization, structural and thermal properties / V. D. Grigorieva, A. F. Bondareva, M. A. Artemyeva [et al.] // Журнал структурной химии. – 2025. – Vol. 66, No. 4. – P. 142914. – DOI 10.26902/JSC_id142914. – EDN DICNHE.
PY - 2025
Y1 - 2025
N2 - Needle-like Cs2Mo7O22 (7×1×1 mm3) and plated Cs2Mo5O16 (4×3×2 mm3) crystals were obtained by spontaneous crystallization method from Cs2Mo5O16 + 2%Cs2O and Cs2Mo7O22 ++ 2%Cs2O melts. Peritectic nature of Cs2Mo5O16 and Cs2Mo7O22 compounds was confirmed by differential scanning calorimetry and thermogravimetric analysis. Cs2Mo5O16 and Cs2Mo7O22 crystal structures were constructed based on X-ray diffraction data. Unit cell parameters of Cs2Mo5O16 and Cs2Mo7O22 crystal samples were measured in 0-450 °C temperature range and thermal expansion vectors were calculated. Photoluminescence was registered on both Cs2Mo5O16 and Cs2Mo7O22 samples at 80 K.
AB - Needle-like Cs2Mo7O22 (7×1×1 mm3) and plated Cs2Mo5O16 (4×3×2 mm3) crystals were obtained by spontaneous crystallization method from Cs2Mo5O16 + 2%Cs2O and Cs2Mo7O22 ++ 2%Cs2O melts. Peritectic nature of Cs2Mo5O16 and Cs2Mo7O22 compounds was confirmed by differential scanning calorimetry and thermogravimetric analysis. Cs2Mo5O16 and Cs2Mo7O22 crystal structures were constructed based on X-ray diffraction data. Unit cell parameters of Cs2Mo5O16 and Cs2Mo7O22 crystal samples were measured in 0-450 °C temperature range and thermal expansion vectors were calculated. Photoluminescence was registered on both Cs2Mo5O16 and Cs2Mo7O22 samples at 80 K.
KW - CS2O-MOO3
KW - PHASE DIAGRAM
KW - THERMOXRD
KW - CS2MO5O16
KW - CS2MO7O22
UR - https://www.elibrary.ru/item.asp?id=81023691
UR - https://jsc.niic.nsc.ru/article/142914/
U2 - 10.26902/JSC_id142914
DO - 10.26902/JSC_id142914
M3 - статья
VL - 66
JO - Журнал структурной химии
JF - Журнал структурной химии
SN - 0136-7463
IS - 4
M1 - 142914
ER -
ID: 74085182