Research output: Contribution to journal › Article › peer-review
Crystals of the (Y1–xEux)2O3 Solid Solution: Growth and Crystal Structure. / Nikolaev, R. E.; Yakovleva, A. M.; Tarasenko, M. S. et al.
In: Journal of Structural Chemistry, Vol. 64, No. 7, 07.2023, p. 1206-1211.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Crystals of the (Y1–xEux)2O3 Solid Solution: Growth and Crystal Structure
AU - Nikolaev, R. E.
AU - Yakovleva, A. M.
AU - Tarasenko, M. S.
AU - Sukhikh, A. S.
AU - Trifonov, V. A.
AU - Naumov, N. G.
N1 - The work was supported by the Russian Science Foundation (project No. 22-43-02079). Публикация для корректировки.
PY - 2023/7
Y1 - 2023/7
N2 - Single crystals of a solid solution of the (Y1–xEux)2O3 compound with the bixbyite-type structure and different europium contents, which are suitable for the structural analysis, are grown by the flux method. The structural data show that the Y/Eu occupation of independent sites is uniform in the crystal; europium has no preferred site occupancy. The average R–O distance is also typical of the rare-earth metal atoms located at different crystallographic sites and increases monotonically as the europium content increases in the crystal. The europium distribution coefficient from the flux is noticeably less than unity, which enriches the crystal with yttrium compared to the flux.
AB - Single crystals of a solid solution of the (Y1–xEux)2O3 compound with the bixbyite-type structure and different europium contents, which are suitable for the structural analysis, are grown by the flux method. The structural data show that the Y/Eu occupation of independent sites is uniform in the crystal; europium has no preferred site occupancy. The average R–O distance is also typical of the rare-earth metal atoms located at different crystallographic sites and increases monotonically as the europium content increases in the crystal. The europium distribution coefficient from the flux is noticeably less than unity, which enriches the crystal with yttrium compared to the flux.
KW - crystal structure
KW - europium
KW - solid solution
KW - yttrium
UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85166220634&origin=inward&txGid=a7ecb8d10c5efdf980b004ce673b8c8e
UR - https://www.mendeley.com/catalogue/005ae8b2-181b-3833-994d-caf515729fc5/
U2 - 10.1134/S0022476623070041
DO - 10.1134/S0022476623070041
M3 - Article
VL - 64
SP - 1206
EP - 1211
JO - Journal of Structural Chemistry
JF - Journal of Structural Chemistry
SN - 0022-4766
IS - 7
ER -
ID: 59578732