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Crystal Structures of New 2D Heteroligand Nd(III), Ho(III), and Yb(III) Coordination Polymers with 2-Iodoterephthalate Linkers. / Zaguzin, A. S.; Bondarenko, M. A.; Korobeinikov, N. A. et al.

In: Journal of Structural Chemistry, Vol. 66, No. 4, 07.05.2025, p. 778-787.

Research output: Contribution to journal › Article › peer-review

Harvard

Zaguzin, AS, Bondarenko, MA, Korobeinikov, NA, Zaitsev, AV & Adonin, SA 2025, 'Crystal Structures of New 2D Heteroligand Nd(III), Ho(III), and Yb(III) Coordination Polymers with 2-Iodoterephthalate Linkers', Journal of Structural Chemistry, vol. 66, no. 4, pp. 778-787. https://doi.org/10.1134/S0022476625040134

APA

Zaguzin, A. S., Bondarenko, M. A., Korobeinikov, N. A., Zaitsev, A. V., & Adonin, S. A. (2025). Crystal Structures of New 2D Heteroligand Nd(III), Ho(III), and Yb(III) Coordination Polymers with 2-Iodoterephthalate Linkers. Journal of Structural Chemistry, 66(4), 778-787. https://doi.org/10.1134/S0022476625040134

Vancouver

Zaguzin AS, Bondarenko MA, Korobeinikov NA, Zaitsev AV, Adonin SA. Crystal Structures of New 2D Heteroligand Nd(III), Ho(III), and Yb(III) Coordination Polymers with 2-Iodoterephthalate Linkers. Journal of Structural Chemistry. 2025 May 7;66(4):778-787. doi: 10.1134/S0022476625040134

Author

Zaguzin, A. S. ; Bondarenko, M. A. ; Korobeinikov, N. A. et al. / Crystal Structures of New 2D Heteroligand Nd(III), Ho(III), and Yb(III) Coordination Polymers with 2-Iodoterephthalate Linkers. In: Journal of Structural Chemistry. 2025 ; Vol. 66, No. 4. pp. 778-787.

BibTeX

@article{4ad4a493b9a044b39a287dcdb747851e,
title = "Crystal Structures of New 2D Heteroligand Nd(III), Ho(III), and Yb(III) Coordination Polymers with 2-Iodoterephthalate Linkers",
abstract = "Abstract: Novel Ln3+ and 2-iodoterephthalate based metal-organic frameworks [Nd2(2-I-bdc)3(DMF)4]·3.5DMF (1), [Ho2(2-I-bdc)3(DMF)4]·2.7DMF (2), [Yb2(2-I-bdc)3(DMF)4]·4.3DMF (3) (2-I-bdc - 2-iodoterephthalate, DMF - N,N-dimethylformamide) are prepared; their structure is determined by XRD. All three isostructural compounds contain a [Ln2(2-I-bdc)3(DMF)4] binuclear unit (Ln = Nd, Ho, Yb). The 2-I-bdc dianions exhibit two different types of coordination. In the first type, one carboxylate group is connected with one Ln(III) ion by two oxygen atoms and the other one is connected with two metal ions. One oxygen atom of the second carboxylate group is connected with only one metal center of the binuclear fragment, while the second oxygen is a bridging atom.",
keywords = "carboxylates, holmium, lanthanides, metal-organic frameworks, neodymium, ytterbium",
author = "Zaguzin, {A. S.} and Bondarenko, {M. A.} and Korobeinikov, {N. A.} and Zaitsev, {A. V.} and Adonin, {S. A.}",
note = "This work was funded by the Russian Science Foundation (project No. 21-73-20019) and partially by the Ministry of Science and Higher Education of the Russian Federation (structural characterization of samples, 121031700313-8, synthesis of ligands, 720000F.99.1.BZ85AA13000). Crystal Structures of New 2D Heteroligand Nd(III), Ho(III), and Yb(III) Coordination Polymers with 2-Iodoterephthalate Linkers / A. S. Zaguzin, M. A. Bondarenko, N. A. Korobeinikov [et al.] // Journal of Structural Chemistry. – 2025. – Vol. 66, No. 4. – P. 778-787. – DOI 10.1134/S0022476625040134.",
year = "2025",
month = may,
day = "7",
doi = "10.1134/S0022476625040134",
language = "English",
volume = "66",
pages = "778--787",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer",
number = "4",

}

RIS

TY - JOUR

T1 - Crystal Structures of New 2D Heteroligand Nd(III), Ho(III), and Yb(III) Coordination Polymers with 2-Iodoterephthalate Linkers

AU - Zaguzin, A. S.

AU - Bondarenko, M. A.

AU - Korobeinikov, N. A.

AU - Zaitsev, A. V.

AU - Adonin, S. A.

N1 - This work was funded by the Russian Science Foundation (project No. 21-73-20019) and partially by the Ministry of Science and Higher Education of the Russian Federation (structural characterization of samples, 121031700313-8, synthesis of ligands, 720000F.99.1.BZ85AA13000). Crystal Structures of New 2D Heteroligand Nd(III), Ho(III), and Yb(III) Coordination Polymers with 2-Iodoterephthalate Linkers / A. S. Zaguzin, M. A. Bondarenko, N. A. Korobeinikov [et al.] // Journal of Structural Chemistry. – 2025. – Vol. 66, No. 4. – P. 778-787. – DOI 10.1134/S0022476625040134.

PY - 2025/5/7

Y1 - 2025/5/7

N2 - Abstract: Novel Ln3+ and 2-iodoterephthalate based metal-organic frameworks [Nd2(2-I-bdc)3(DMF)4]·3.5DMF (1), [Ho2(2-I-bdc)3(DMF)4]·2.7DMF (2), [Yb2(2-I-bdc)3(DMF)4]·4.3DMF (3) (2-I-bdc - 2-iodoterephthalate, DMF - N,N-dimethylformamide) are prepared; their structure is determined by XRD. All three isostructural compounds contain a [Ln2(2-I-bdc)3(DMF)4] binuclear unit (Ln = Nd, Ho, Yb). The 2-I-bdc dianions exhibit two different types of coordination. In the first type, one carboxylate group is connected with one Ln(III) ion by two oxygen atoms and the other one is connected with two metal ions. One oxygen atom of the second carboxylate group is connected with only one metal center of the binuclear fragment, while the second oxygen is a bridging atom.

AB - Abstract: Novel Ln3+ and 2-iodoterephthalate based metal-organic frameworks [Nd2(2-I-bdc)3(DMF)4]·3.5DMF (1), [Ho2(2-I-bdc)3(DMF)4]·2.7DMF (2), [Yb2(2-I-bdc)3(DMF)4]·4.3DMF (3) (2-I-bdc - 2-iodoterephthalate, DMF - N,N-dimethylformamide) are prepared; their structure is determined by XRD. All three isostructural compounds contain a [Ln2(2-I-bdc)3(DMF)4] binuclear unit (Ln = Nd, Ho, Yb). The 2-I-bdc dianions exhibit two different types of coordination. In the first type, one carboxylate group is connected with one Ln(III) ion by two oxygen atoms and the other one is connected with two metal ions. One oxygen atom of the second carboxylate group is connected with only one metal center of the binuclear fragment, while the second oxygen is a bridging atom.

KW - carboxylates

KW - holmium

KW - lanthanides

KW - metal-organic frameworks

KW - neodymium

KW - ytterbium

UR - https://www.mendeley.com/catalogue/ca5a8d4c-27b9-3fd8-946e-d898272fe8dd/

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-105004452410&origin=inward&txGid=b502489a8ed592f25d425807076eb12c

UR - https://elibrary.ru/item.asp?id=82272591

U2 - 10.1134/S0022476625040134

DO - 10.1134/S0022476625040134

M3 - Article

VL - 66

SP - 778

EP - 787

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 4

ER -

ID: 66251740