Research output: Contribution to journal › Article › peer-review
Crystal structures of cis-diiododiammine platinum and trans-diazidodiammine platinum. / Vasilchenko, D. B.; Zadesenets, A. V.; Baidina, I. A. et al.
In: Journal of Structural Chemistry, Vol. 58, No. 8, 01.12.2017, p. 1689-1692.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Crystal structures of cis-diiododiammine platinum and trans-diazidodiammine platinum
AU - Vasilchenko, D. B.
AU - Zadesenets, A. V.
AU - Baidina, I. A.
AU - Piryazev, D. A.
AU - Romanenko, G. V.
PY - 2017/12/1
Y1 - 2017/12/1
N2 - Platinum(II) complexes cis-[Pt(NH3)2I2] (1) and trans-[Pt(NH3)2(N3)2] (2) are structurally characterized separately for the first time. The crystallographic data are as follows: for 1, a = 7.0065(6) Å, b = 6.8714(6) Å, c = 7.4106(8) Å, β = 108.432(7)°, space group P21/m, Z = 2, ρcalc = 4.739 g/cm3; for 2, a = 8.1337(5) Å, b = 11.5821(7) Å, c = 6.9705(5) Å, β = 107.256(2)°, space group P21/c, Z = 4, ρcalc = 3.318 g/cm3. Platinum atoms have a square planar environment; the main structure-forming factor is the presence of intermolecular hydrogen bonds forming chain motifs in the structure of 1 and a threedimensional framework in the structure of 2.
AB - Platinum(II) complexes cis-[Pt(NH3)2I2] (1) and trans-[Pt(NH3)2(N3)2] (2) are structurally characterized separately for the first time. The crystallographic data are as follows: for 1, a = 7.0065(6) Å, b = 6.8714(6) Å, c = 7.4106(8) Å, β = 108.432(7)°, space group P21/m, Z = 2, ρcalc = 4.739 g/cm3; for 2, a = 8.1337(5) Å, b = 11.5821(7) Å, c = 6.9705(5) Å, β = 107.256(2)°, space group P21/c, Z = 4, ρcalc = 3.318 g/cm3. Platinum atoms have a square planar environment; the main structure-forming factor is the presence of intermolecular hydrogen bonds forming chain motifs in the structure of 1 and a threedimensional framework in the structure of 2.
KW - ammonia
KW - azide
KW - iodide
KW - platinum
KW - VISIBLE-LIGHT
KW - COMPLEX
KW - CISPLATIN
UR - http://www.scopus.com/inward/record.url?scp=85041577022&partnerID=8YFLogxK
U2 - 10.1134/S0022476617080315
DO - 10.1134/S0022476617080315
M3 - Article
AN - SCOPUS:85041577022
VL - 58
SP - 1689
EP - 1692
JO - Journal of Structural Chemistry
JF - Journal of Structural Chemistry
SN - 0022-4766
IS - 8
ER -
ID: 9639889