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Crystal Structures and Properties of Metal-Organic Coordination Polymers [Zn2(bdc)x(bdc-I)(2–x)dabco]. / Zaguzin, A. S.; Zaitsev, Ya. A.; Zaitsev, A. V. et al.

In: Russian Journal of Inorganic Chemistry, Vol. 70, No. 8, 30.09.2025, p. 1125-1131.

Research output: Contribution to journal › Article › peer-review

Harvard

Zaguzin, AS, Zaitsev, YA, Zaitsev, AV, Korobeynikov, NA, Bondarenko, MA, Maksimovskii, EA, Fedin, VP & Adonin, SA 2025, 'Crystal Structures and Properties of Metal-Organic Coordination Polymers [Zn2(bdc)x(bdc-I)(2–x)dabco]', Russian Journal of Inorganic Chemistry, vol. 70, no. 8, pp. 1125-1131. https://doi.org/10.1134/s0036023625601436

APA

Zaguzin, A. S., Zaitsev, Y. A., Zaitsev, A. V., Korobeynikov, N. A., Bondarenko, M. A., Maksimovskii, E. A., Fedin, V. P., & Adonin, S. A. (2025). Crystal Structures and Properties of Metal-Organic Coordination Polymers [Zn2(bdc)x(bdc-I)(2–x)dabco]. Russian Journal of Inorganic Chemistry, 70(8), 1125-1131. https://doi.org/10.1134/s0036023625601436

Vancouver

Zaguzin AS, Zaitsev YA, Zaitsev AV, Korobeynikov NA, Bondarenko MA, Maksimovskii EA et al. Crystal Structures and Properties of Metal-Organic Coordination Polymers [Zn2(bdc)x(bdc-I)(2–x)dabco]. Russian Journal of Inorganic Chemistry. 2025 Sept 30;70(8):1125-1131. doi: 10.1134/s0036023625601436

Author

Zaguzin, A. S. ; Zaitsev, Ya. A. ; Zaitsev, A. V. et al. / Crystal Structures and Properties of Metal-Organic Coordination Polymers [Zn2(bdc)x(bdc-I)(2–x)dabco]. In: Russian Journal of Inorganic Chemistry. 2025 ; Vol. 70, No. 8. pp. 1125-1131.

BibTeX

@article{08b76ebe4b284e57ad59a8eb416dbedb,
title = "Crystal Structures and Properties of Metal-Organic Coordination Polymers [Zn2(bdc)x(bdc-I)(2–x)dabco]",
abstract = "New mixed-ligand organometallic frameworks based on zinc terephthalate (bdc), 2‑iodoterephthalate (bdc-I), and 1,4-diazabicyclo[2.2.2]octane (dabco) were obtained: [Zn2(bdc)1.67(bdc-I)0.33dabco] (I), [Zn2(bdc)1.46(bdc-I)0.54dabco] (II), [Zn2(bdc)1.12(bdc-I)0.88dabco] (III), [Zn2(bdc)0.80(bdc-I)1.2dabco] (IV), [Zn2(bdc)0.46(bdc-I)1.54dabco] (V). Their structures and composition were determined by single-crystal and powder X-ray diffraction, as well as elemental analysis. Compounds I–V are isostructural with [Zn2(bdc)2(dabco)], but not with [Zn2(bdc-I)2(dabco)], which we have not described previously, which is confirmed by X-ray powder diffraction data. Experiments on the sorption of diiodine vapors are consistent with the idea that the presence of a larger amount of 2-iodoterephthalate in the MOF should lead to a decrease in pore volume: the greatest amount of I2 is absorbed by I, and the smallest by is absorbed V.",
author = "Zaguzin, {A. S.} and Zaitsev, {Ya. A.} and Zaitsev, {A. V.} and Korobeynikov, {N. A.} and Bondarenko, {M. A.} and Maksimovskii, {E. A.} and Fedin, {V. P.} and Adonin, {S. A.}",
note = "This work was supported by the Russian Science Foundation, grant no. 24-73-00130. Crystal Structures and Properties of Metal-Organic Coordination Polymers [Zn2(bdc)x(bdc-I)(2–x)dabco] / A. S. Zaguzin, Ya. A. Zaitsev, A. V. Zaitsev [et al.] // Russian Journal of Inorganic Chemistry. – 2025. – Vol. 70, No. 8. – P. 1125-1131. – DOI 10.1134/S0036023625601436.",
year = "2025",
month = sep,
day = "30",
doi = "10.1134/s0036023625601436",
language = "English",
volume = "70",
pages = "1125--1131",
journal = "Russian Journal of Inorganic Chemistry",
issn = "0036-0236",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "8",

}

RIS

TY - JOUR

T1 - Crystal Structures and Properties of Metal-Organic Coordination Polymers [Zn2(bdc)x(bdc-I)(2–x)dabco]

AU - Zaguzin, A. S.

AU - Zaitsev, Ya. A.

AU - Zaitsev, A. V.

AU - Korobeynikov, N. A.

AU - Bondarenko, M. A.

AU - Maksimovskii, E. A.

AU - Fedin, V. P.

AU - Adonin, S. A.

N1 - This work was supported by the Russian Science Foundation, grant no. 24-73-00130. Crystal Structures and Properties of Metal-Organic Coordination Polymers [Zn2(bdc)x(bdc-I)(2–x)dabco] / A. S. Zaguzin, Ya. A. Zaitsev, A. V. Zaitsev [et al.] // Russian Journal of Inorganic Chemistry. – 2025. – Vol. 70, No. 8. – P. 1125-1131. – DOI 10.1134/S0036023625601436.

PY - 2025/9/30

Y1 - 2025/9/30

N2 - New mixed-ligand organometallic frameworks based on zinc terephthalate (bdc), 2‑iodoterephthalate (bdc-I), and 1,4-diazabicyclo[2.2.2]octane (dabco) were obtained: [Zn2(bdc)1.67(bdc-I)0.33dabco] (I), [Zn2(bdc)1.46(bdc-I)0.54dabco] (II), [Zn2(bdc)1.12(bdc-I)0.88dabco] (III), [Zn2(bdc)0.80(bdc-I)1.2dabco] (IV), [Zn2(bdc)0.46(bdc-I)1.54dabco] (V). Their structures and composition were determined by single-crystal and powder X-ray diffraction, as well as elemental analysis. Compounds I–V are isostructural with [Zn2(bdc)2(dabco)], but not with [Zn2(bdc-I)2(dabco)], which we have not described previously, which is confirmed by X-ray powder diffraction data. Experiments on the sorption of diiodine vapors are consistent with the idea that the presence of a larger amount of 2-iodoterephthalate in the MOF should lead to a decrease in pore volume: the greatest amount of I2 is absorbed by I, and the smallest by is absorbed V.

AB - New mixed-ligand organometallic frameworks based on zinc terephthalate (bdc), 2‑iodoterephthalate (bdc-I), and 1,4-diazabicyclo[2.2.2]octane (dabco) were obtained: [Zn2(bdc)1.67(bdc-I)0.33dabco] (I), [Zn2(bdc)1.46(bdc-I)0.54dabco] (II), [Zn2(bdc)1.12(bdc-I)0.88dabco] (III), [Zn2(bdc)0.80(bdc-I)1.2dabco] (IV), [Zn2(bdc)0.46(bdc-I)1.54dabco] (V). Their structures and composition were determined by single-crystal and powder X-ray diffraction, as well as elemental analysis. Compounds I–V are isostructural with [Zn2(bdc)2(dabco)], but not with [Zn2(bdc-I)2(dabco)], which we have not described previously, which is confirmed by X-ray powder diffraction data. Experiments on the sorption of diiodine vapors are consistent with the idea that the presence of a larger amount of 2-iodoterephthalate in the MOF should lead to a decrease in pore volume: the greatest amount of I2 is absorbed by I, and the smallest by is absorbed V.

UR - https://www.mendeley.com/catalogue/02b4fab4-c9ae-3554-9965-50c597cded9c/

UR - https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=105018326814&origin=inward

UR - https://elibrary.ru/item.asp?id=82944515

U2 - 10.1134/s0036023625601436

DO - 10.1134/s0036023625601436

M3 - Article

VL - 70

SP - 1125

EP - 1131

JO - Russian Journal of Inorganic Chemistry

JF - Russian Journal of Inorganic Chemistry

SN - 0036-0236

IS - 8

ER -

ID: 70824321